# US 2014/0154196 A1 · Cosmetic composition based on a supramolecular polymer and a silicone compound

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- Number: US 2014/0154196 A1
- Document ID: US20140154196A1
- Status: Published application
- Kind: A1
- Application number: 13/691,134
- Filed: 2012-11-30
- Published: 2014-06-05
- Earliest claimed: 2012-11-30
- Assignees: L'oreal
- Applicants: L'oreal
- Inventors: Roberto CAVAZZUTI; Nathalie GEFFROY; Claudia BARBA
- Web page: https://patentgrep.com/patent/US20140154196A1

## CPC

- A61K 8/37: Esters of carboxylic acids
- A61K 8/8111: {Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers}
- A61K 8/8194: {Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds; Compositions of derivatives of such polymers}
- A61K 8/891: saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
- A61Q 1/02: Preparations containing skin colorants, e.g. pigments (preparations in powder form A61Q1/12)
- A61Q 1/06: Lipsticks
- A61Q 1/04: for lips
- A61Q 1/08: for cheeks, e.g. rouge
- A61Q 1/10: for eyes, e.g. eyeliner, mascara
- A61K: PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES (devices or methods specially adapted for bringing pharmaceutical products into particular physical or administering forms A61J3/00; chemical aspects of, or use of materials for deodorisation of air, for disinfection or sterilisation, or for bandages, dressings, absorbent pads or surgical articles A61L; soap compositions C11D)
- A61Q: SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS

## Abstract

The present invention relates to a process for making up and/or caring for the skin and/or the lips, comprising the application to the skin and/or the lips of a cosmetic composition and in particular a composition for making up and/or caring for the skin and/or the lips, comprising at least one supramolecular polymer and a silicone compound with a viscosity of less than 10 000 000 cSt at 25° C.

## Claims

### Claim 1

Cosmetic process for making up and/or caring for the skin and/or the lips, comprising at least the application to the said skin and/or the said lips of a composition comprising, in a physiologically acceptable medium:
at least 2.5% by weight relative to the total weight of the composition of at least one supramolecular polymer based on functionalized polyalkene of formula HO—P—OH in which P represents a homopolymer or a copolymer that may be obtained by polymerization of one or more linear, cyclic and/or branched polyunsaturated C2-C10 and preferably C2-C4 alkenes, which may be derived from the reaction, especially the condensation, of the said functionalized polyalkene polymer with at least one junction group functionalized with at least one reactive group capable of reacting with the reactive group(s) of the functionalized polyalkene polymer, the said junction group being capable of forming at least 3H (hydrogen) bonds, preferably at least 4H bonds, preferentially 4H bonds,
and at least one silicone compound with a viscosity of less than 10 000 000 cSt at 25° C.

### Claim 2 (depends on 1)

Process according to claim 1, in which the functionalized polyalkene of formula HO—P—OH is hydrogenated.

### Claim 3 (depends on 1)

Process according to claim 1, in which P represents a homo- or copolymer that may be obtained by polymerization of one or more linear or branched C2-C4 diunsaturated alkenes.

### Claim 4 (depends on 1)

Process according to claim 1, in which P represents a polybutylene, a polybutadiene, a polyisoprene, a poly(1,3-pentadiene) or a polyisobutylene, and copolymers thereof, and preferably a poly(ethylene/butylene).

### Claim 5 (depends on 1)

Process according to claim 1, in which the functionalized junction group is of formula:
in which L represents a saturated or unsaturated C1-C20 divalent carbon-based group, chosen in particular from a linear or branched C1-C20 alkylene; a C5-C20 (alkyl)cycloalkylene, an alkylene-biscycloalkylene and a C6-C20 (alkyl)arylene, preferably an isophorone group.

### Claim 6 (depends on 1)

Process according to claim 1, in which the supramolecular polymer corresponds to the formula:
in which:
L′ and L″ are, independently of each other, as defined for L in the preceding claim;
X, X′═O and P is as defined in one of the preceding claims.

### Claim 7 (depends on 6)

Process according to claim 6, in which:
L′ and L″ are both isophorone groups,
X and X′═O and P represents a polybutylene, a polybutadiene, a polyisoprene, a poly(1,3-pentadiene) or a polyisobutylene, and copolymers thereof, and preferably a poly(ethylene/butylene).

### Claim 8 (depends on 1)

Process according to claim 1, comprising from 3% to 60% by weight, preferably from 3.5% to 50% by weight or even from 4% to 40% by weight of supramolecular polymer(s) relative to the total weight of the said composition.

### Claim 9 (depends on 8)

Process according to claim 8, comprising from 0.1% to 70% by weight, preferably from 0.2% to 40% by weight or even from 0.3% to 30% by weight of silicone compound(s) with a viscosity of less than 10 000 000 cSt at 25° C. relative to the total weight of the said composition.

### Claim 10 (depends on 1)

Process according to claim 1, in which the said silicone compound with a viscosity of less than 10 000 000 cSt at 25° C. and the said supramolecular polymer are present in a silicone compound(s) according to the invention/polymer(s) weight ratio of between 0.01 and 20, preferably between 0.1 and 15, or even between 0.4 and 10 and better still between 1 and 8.

### Claim 11 (depends on 1)

Process according to claim 1, in which the said silicone compound with a viscosity of less than 10 000 000 cSt at 25° C. is chosen from silicone gums and volatile and non-volatile silicone oils.

### Claim 12 (depends on 1)

Process according to claim 1, in which the said silicone compound with a viscosity of less than 10 000 000 cSt at 25° C. is at least one volatile or non-volatile silicone oil chosen from linear silicone oils and phenyl silicone oils, and especially has a viscosity of less than 800 000 cSt at 25° C.

### Claim 13 (depends on 12)

Process according to claim 12, in which the said phenyl silicone oil is chosen from phenyl trimethicones, phenyl dimethicones, phenyltrimethylsiloxydiphenylsiloxanes, diphenyl dimethicones, diphenylmethyldiphenyltrisiloxanes, 2-phenylethyl trimethylsiloxysilicates and dimethicones or phenyl trimethicone with a viscosity of less than or equal to 100 cSt.

### Claim 14 (depends on 1)

Process according to claim 1, in which the said silicone compound with a viscosity of less than 10 000 000 cSt at 25° C. is at least one silicone gum, especially whose viscosity is greater than 800 000 cSt at 25° C.

### Claim 15 (depends on 1)

Process according to claim 1, in which the said composition also comprises at least one additional liquid fatty phase and especially at least one non-silicone oil.

### Claim 16 (depends on 1)

Process according to claim 1, in which the said composition is in the form of a complexion product such as a foundation, a face powder or an eyeshadow; a lip product such as a lipstick or a lipcare product, which is especially solid; a concealer product; a blusher; an eyeliner; a lipstick pencil or eye pencil; a body makeup product or a gloss (lip gloss).

### Claim 17 (depends on 1)

Composition for making up and/or caring for the skin and/or the lips, comprising, in a physiologically acceptable medium, at least one supramolecular polymer as defined in claim 1, and at least one silicone compound with a viscosity of less than 10 000 000 cSt at 25° C., the said composition being free of cyclopentasiloxane.

### Claim 18 (depends on 1)

Composition for making up and/or caring for the skin and/or the lips, comprising, in a physiologically acceptable medium, at least one supramolecular polymer as defined in claim 1, and at least 15% by weight of silicone compound(s) with a viscosity of less than 10 000 000 cSt at 25° C.

### Claim 19 (depends on 1)

Composition for making up and/or caring for the skin and/or the lips, comprising, in a physiologically acceptable medium, at least one supramolecular polymer as defined in claim 1, at least one silicone compound with a viscosity of less than 10 000 000 cSt at 25° C., and at least one pigment other than a nacre.

### Claim 20 (depends on 17)

Composition according to claim 17, in which the said silicone compound with a viscosity of less than 10 000 000 cSt at 25° C.