# US 2014/0154165 A1 · Method for preparing graphene by using two-dimensional confined space between the layers of inorganic layered materials

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- Number: US 2014/0154165 A1
- Document ID: US20140154165A1
- Status: Published application
- Kind: A1
- Application number: 13/980,715
- Filed: 2012-03-27
- Published: 2014-06-05
- Earliest claimed: 2012-02-17
- Assignees: Beijing University of Chemical Technology
- Inventors: Wensheng Yang; Jie Sun; Haimei Liu; Xu Chen; Xue Duan
- Web page: https://patentgrep.com/patent/US20140154165A1

## CPC

- C01B 32/192: starting from graphitic oxides
- C01B 32/22: Intercalation
- Y10S 977/789: in array format
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y10S: TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS

## Abstract

The present invention relates to a method for preparing graphene using the two-dimensional confined space between the layers of inorganic layered materials. Such method comprises the following steps: mix a soluble salt of a divalent metal ion M2+, a soluble salt of a trivalent metal ion M′3+, a soluble salt of a chain alkyl anion A− and a carbon source molecule C and dissolve them in deionized and CO2-eliminated water to prepare a mixed salt solution; mix the mixed salt solution with an alkali solution under nitrogen protection and subject them to reaction and crystallization under nitrogen, and filter the suspension obtained thereafter and wash the filter cake with deionized water until the pH of the filtrate is 7 to 7.5, and then dry the filter cake to obtain layered double hydroxides with an intercalated structure; under an inert atmosphere or a reducing atmosphere, calcinate the layered double hydroxides with an intercalated structure to provide a calcinated product; add the calcinated product into a hydrochloric acid solution for ultrasonic treatment, and separate the solution by centrifugation and wash the precipitate obtained by centrifugation with deionized water until the pH of the filtrate is 6.5 to 7 to obtain the graphene.

## Claims

### Claim 1

A preparation method for graphene, comprising the following steps:
(1) mix a soluble salt of a divalent metal ion M2+, a soluble salt of a trivalent metal ion M′3+, a soluble salt of a chain alkyl anion A− and a carbon source molecule C and dissolve them in deionized and CO2-eliminated water to prepare a mixed salt solution;
mix the mixed salt solution with an alkali solution under nitrogen protection and subject them to reaction and crystallization at 60° C. to 80° C. for 6 to 10 hours under nitrogen, filter the suspension obtained thereafter and wash the filter cake with deionized water until the pH of the filtrate is 7 to 7.5, and then dry the filter cake at 50° C. to 60° C. for 6 to 12 hours to obtain layered double hydroxides with an intercalated structure having a general chemical structure of:
[M2+1-xM′3+x(OH)2]x+A−x.αC.βH2O
wherein, x is 0.2-0.33, α is 0.2-6.6, and β is 0.3-3;
(2) under an inert atmosphere or a reducing atmosphere, calcinate the layered double hydroxides with an intercalated structure to provide a calcinated product at a calcination temperature of 700° C. to 950° C. for a period of time of 0.5 to 3 hours;
(3) add the calcinated product into a hydrochloric acid solution with a concentration of 5 wt % for ultrasonic treatment, and separate the solution by centrifugation and wash the precipitate obtained by centrifugation with deionized water until the pH of the filtrate is 6.5 to 7 to obtain the graphene.

### Claim 2 (depends on 1)

The preparation method according to claim 1, wherein, in step (1), the soluble salt of the divalent metal ion M2+ is one or more of a nitrate, a sulfate, an oxalate or a chloride of Mg or Zn; and the soluble salt of the trivalent metal ion M′3+ is one or more of a nitrate, a sulfate, an oxalate or a chloride of Al.

### Claim 3 (depends on 1)

The preparation method according to claim 1, wherein, the molar ratio between the divalent metal ion M2+ and the trivalent metal ion M′3+ is 2 to 4:1.

### Claim 4 (depends on 1)

The preparation method according to claim 1, wherein, in the mixed salt solution, the overall concentration of the divalent metal ion M2+ and the trivalent metal ion M′3+ is 0.2 to 0.5 mol/L.

### Claim 5 (depends on 1)

The preparation method according to claim 1, wherein, in step (1), the soluble salt of the chain alkyl anion A− is one or more of sodium dodecyl sulfate, sodium dodecyl sulfonate, sodium dodecyl benzene sulfonate, potassium dodecyl sulfate, potassium dodecyl sulfonate and potassium dodecyl benzene sulfonate.

### Claim 6 (depends on 1)

The preparation method according to claim 1, wherein, in the mixed salt solution in step (1), the number of moles of the chain alkyl anion A− is equivalent to the number of moles of the trivalent metal ion M′3+.

### Claim 7 (depends on 1)

The preparation method according to claim 1, wherein, in step (1), the carbon source molecule C is one or more of methyl methacrylate, n-pentane, benzene, toluene, xylene, and styrene.

### Claim 8 (depends on 1)

The preparation method according to claim 1, wherein, in the mixed salt solution, the number of moles of the carbon source molecule C is 1 to 20 times of the number of moles of the trivalent metal ion M′3+.

### Claim 9 (depends on 1)

The preparation method according to claim 1, wherein, in step (1), the alkali solution is a solution prepared by dissolving sodium hydroxide or potassium hydroxide into deionized and CO2-eliminated water with a concentration of 2 to 5 mol/L.

### Claim 10 (depends on 1)

The preparation method according to claim 1, wherein, the number of moles of the alkali in the alkali solution is twice of the total number of moles of the divalent metal ion M2+ and the trivalent metal ion M′3+.

### Claim 11 (depends on 1)

The preparation method according to claim 1, wherein, in step (2), the inert atmosphere is a nitrogen atmosphere or an argon atmosphere, and the reducing atmosphere is a hydrogen atmosphere.

### Claim 12 (depends on 1)

The preparation method according to claim 1, wherein, in step (3), the solid to liquid ratio between the calcinated product and the HCl solution is 2 to 7 g/L.

### Claim 13 (depends on 1)

The preparation method according to claim 1, wherein, in step (3), the duration of the ultrasonic treatment is 0.5 to 2 hours.

### Claim 14 (depends on 1)

The preparation method according to claim 1, wherein, in step (3), the revolution rate for the centrifugation is 5000 to 9000 rpm.

### Claim 15 (depends on 2)

The preparation method according to claim 2, wherein the molar ratio between the divalent metal ion M2+ and the trivalent metal ion M′3+ is 2 to 4:1.

### Claim 16 (depends on 2)

The preparation method according to claim 2, wherein, in the mixed salt solution, the overall concentration of the divalent metal ion M2+ and the trivalent metal ion M′3+ is 0.2 to 0.5 mol/L.

### Claim 17 (depends on 5)

The preparation method according to claim 5, wherein, in the mixed salt solution in step (1), the number of moles of the chain alkyl anion A− is equivalent to the number of moles of the trivalent metal ion M′3+.

### Claim 18 (depends on 7)

The preparation method according to claim 7, wherein, in the mixed salt solution, the number of moles of the carbon source molecule C is 1 to 20 times of the number of moles of the trivalent metal ion M′3+.

### Claim 19 (depends on 4)

The preparation method according to claim 4, wherein, the number of moles of the alkali in the alkali solution is twice of the total number of moles of the divalent metal ion M2+ and the trivalent metal ion M′3+.

### Claim 20 (depends on 9)

The preparation method according to claim 9, wherein, the number of moles of the alkali in the alkali solution is twice of the total number of moles of the divalent metal ion M2+ and the trivalent metal ion M′3+.