# US 2014/0151997 A1 · Luminescent borates, luminescent materials and articles incorporating such borates

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- Number: US 2014/0151997 A1
- Document ID: US20140151997A1
- Status: Published application
- Kind: A1
- Application number: 13/803,052
- Filed: 2013-03-14
- Published: 2014-06-05
- Earliest claimed: 2012-11-30
- Assignees: Honeywell International Inc.
- Applicants: Honeywell International Inc.
- Inventors: James Kane; Carsten Lau; William Ross Rapoport
- Web page: https://patentgrep.com/patent/US20140151997A1

## CPC

- B42D 25/373: Metallic materials
- B42D 25/00: Information-bearing cards or sheet-like structures characterised by identification or security features; Manufacture thereof (printing processes to produce identification or security features B41M3/14)
- B42D 25/21: for multiple purposes
- B42D 25/23: Identity cards
- B42D 25/24: Passports
- B42D 25/29: Securities; Bank notes
- B42D 25/36: comprising special materials
- B42D 25/378: Special inks
- C09D 5/22: Luminous paints {(luminescent compositions C09K11/00)}
- C09K 11/778: {Borates}
- B42D 2033/14
- B42D 2033/20
- Y10T 428/24802: Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]
- Y10T 428/24893: including particulate material
- Y10T 428/2982: Particulate matter [e.g., sphere, flake, etc.]
- B42D: BOOKS; BOOK COVERS; LOOSE LEAVES; PRINTED MATTER CHARACTERISED BY IDENTIFICATION OR SECURITY FEATURES; PRINTED MATTER OF SPECIAL FORMAT OR STYLE NOT OTHERWISE PROVIDED FOR; DEVICES FOR USE THEREWITH AND NOT OTHERWISE PROVIDED FOR; MOVABLE-STRIP WRITING OR READING APPARATUS
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Luminescent borates, luminescent materials, and articles incorporating such borates are provided herein. An embodiment of a luminescent borate includes a host borate that has a B9O16-comprising crystal lattice. Neodymium and/or ytterbium are present within the host borate, and one or more substitutable elements are optionally present along with the neodymium and/or ytterbium within the host borate. The one or more substitutable elements are different from neodymium and ytterbium.

## Claims

### Claim 1

A luminescent borate comprising:
a host borate having a B9O16-comprising crystal lattice;
neodymium and ytterbium present within the host borate; and
optionally, one or more substitutable elements present within the host borate, the one or more substitutable elements being different from neodymium and ytterbium.

### Claim 2 (depends on 1)

The luminescent borate of claim 1, having a density of less than or equal to 4 grams per cubic centimeter.

### Claim 3 (depends on 1)

The luminescent borate of claim 1, having a formula MeXB9O16 wherein
Me is selected from the group consisting of strontium, barium, or a mixture thereof; and
X is a mixture of neodymium and ytterbium, optionally including the one or more substitutable elements.

### Claim 4 (depends on 3)

The luminescent borate of claim 3, wherein Me is barium.

### Claim 5 (depends on 4)

The luminescent borate of claim 4, wherein the one or more substitutable elements are present in the luminescent borate and include lanthanum.

### Claim 6 (depends on 3)

The luminescent borate of claim 3, wherein the one or more substitutable elements are absent therefrom.

### Claim 7 (depends on 1)

The luminescent borate of claim 1, wherein the one or more substitutable elements are substituted by neodymium at a first substitution percentage of at least about 20 percent, and wherein the one or more substitutable elements is substituted by ytterbium at a second substitution percentage.

### Claim 8 (depends on 7)

The luminescent borate of claim 7, wherein the first substitution percentage is in a range of about 50 to about 95 percent, and the second substitution percentage is in a range of about 50 to about 5 percent.

### Claim 9 (depends on 8)

The luminescent borate of claim 8, wherein the first substitution percentage is in a range of about 85 to about 95 percent, and the second substitution percentage is in a range of about 15 to about 5 percent.

### Claim 10 (depends on 1)

The luminescent borate of claim 1, wherein the luminescent borate is in a form of particles with an average particle size of less than 200 microns.

### Claim 11

A luminescent material comprising:
a medium; and
particles of a luminescent borate dispersed in the medium, the luminescent borate comprising:
a host borate having a B9O16-comprising crystal lattice;
neodymium and/or ytterbium present within the host borate; and
optionally, one or more substitutable elements present within the host borate, the one or more substitutable elements being different from neodymium and ytterbium.

### Claim 12 (depends on 11)

The luminescent material of claim 11, wherein the particles have an average particle size of less than 200 microns.

### Claim 13 (depends on 12)

The luminescent material of claim 12, wherein the medium is chosen from the group of an ink, an ink additive, a glue, a liquid, a gel, a polymer, a slurry, a plastic, plastic base resin, a glass, a ceramic, a metal, a textile, wood, fiber, paper pulp, paper, and mixtures thereof.

### Claim 14 (depends on 13)

The luminescent material of claim 13, wherein the medium is ink or ink additive.

### Claim 15 (depends on 14)

The luminescent material of claim 14, wherein the ink or the ink additive comprises colored dye.

### Claim 16 (depends on 11)

The luminescent material of claim 11, wherein the luminescent borate has neodymium and ytterbium present within the host borate.

### Claim 17 (depends on 11)

The luminescent material of claim 11, wherein the luminescent borate has a formula BaXB9O16, where Ba is barium; and X is neodymium, ytterbium, or a mixture thereof, optionally including the one or more substitutable elements.

### Claim 18

An article comprising:
a security feature that includes
a medium; and
particles of a luminescent borate dispersed in the medium, the luminescent borate comprising:
a host borate having a B9O16-comprising crystal lattice;
neodymium and/or ytterbium present within the host borate; and
optionally, one or more substitutable elements present within the host borate, the one or more substitutable elements being different from neodymium and ytterbium.

### Claim 19 (depends on 18)

The article of claim 18, further comprising a substrate, wherein the medium is an ink that is printed on a surface of the substrate.

### Claim 20 (depends on 18)

The article of claim 18, wherein the article is selected from a group consisting of an identification card, a driver's license, a passport, identity papers, a banknote, a check, a document, a paper, a stock certificate, a packaging component, a credit card, a bank card, a label, a seal, a postage stamp, a token, a liquid, a human, an animal, and a biological sample.
