# US 2014/0151686 A1 · Semiconductor device and method for manufacturing the same

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- Number: US 2014/0151686 A1
- Document ID: US20140151686A1
- Status: Published application
- Kind: A1
- Application number: 14/090,244
- Filed: 2013-11-26
- Published: 2014-06-05
- Earliest claimed: 2012-11-30
- Assignees: Semiconductor Energy Laboratory Co., Ltd.
- Applicants: Semiconductor Energy Laboratory Co., Ltd.
- Inventors: Shunpei YAMAZAKI; Yasutaka NAKAZAWA; Masami JINTYOU; Junichi KOEZUKA; Kenichi OKAZAKI; Takuya HIROHASHI; Shunsuke ADACHI
- Web page: https://patentgrep.com/patent/US20140151686A1

## CPC

- H10D 30/6757: {characterised by the structure of the channel, e.g. transverse or longitudinal shape or doping profile (TFTs having channel structures for preventing kink or snapback effects H10D30/6708; TFTs having lightly-doped source or drain extensions H10D30/6715)}
- H10D 30/6713: {characterised by the properties of the source or drain regions, e.g. compositions or sectional shapes}
- H10D 30/6755: {Oxide semiconductors, e.g. zinc oxide, copper aluminium oxide or cadmium stannate}
- H10D 86/423: {comprising semiconductor materials not belonging to the Group IV, e.g. InGaZnO}
- H10D 86/60: wherein the TFTs are in active matrices
- H10D 99/00: Subject matter not provided for in other groups of this subclass
- H10P 14/412: {Deposition of metallic or metal-silicide materials}
- H10P 14/692: composed of oxides, glassy oxides or oxide-based glasses
- H10P 50/00: Etching of wafers, substrates or parts of devices
- H10P 50/28: of insulating materials
- H10K 59/1213: {the pixel elements being TFTs}
- H10D: INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES

## Abstract

A semiconductor device including a transistor having a reduced number of oxygen vacancies in a channel formation region of an oxide semiconductor with stable electrical characteristics or high reliability is provided. A gate insulating film is formed over a gate electrode; an oxide semiconductor layer is formed over the gate insulating film; an oxide layer is formed over the oxide semiconductor layer by a sputtering method to form an stacked-layer oxide film including the oxide semiconductor layer and the oxide layer; the stacked-layer oxide film is processed into a predetermined shape; a conductive film containing Ti as a main component is formed over the stacked-layer oxide film; the conductive film is etched to form source and drain electrodes and a depression portion on a back channel side; and portions of the stacked-layer oxide film in contact with the source and drain electrodes are changed to an n-type by heat treatment.

## Claims

### Claim 1

A semiconductor device comprising:
a gate electrode;
a gate insulating film overlapping with the gate electrode;
a stacked-layer oxide film including a channel formation region and overlapping with the gate electrode with the gate insulating film provided therebetween; and
a source electrode and a drain electrode in contact with the stacked-layer oxide film,
wherein portions of the stacked-layer oxide film which are in contact with the source electrode and the drain electrode have lowest resistance, and a portion of the stacked-layer oxide film has higher resistance as the portion is distanced from the source electrode or the drain electrode in a film thickness direction.

### Claim 2 (depends on 1)

The semiconductor device according to claim 1, wherein an effective channel length is shorter than a distance between the source electrode and the drain electrode.

### Claim 3 (depends on 1)

The semiconductor device according to claim 1,
wherein the stacked-layer oxide film has a stacked-layer structure of a first oxide layer and a second oxide layer over the first oxide layer, and
wherein the first oxide layer and the second oxide layer each contain In, Zn, and a metal other than In and Zn.

### Claim 4 (depends on 1)

The semiconductor device according to claim 1, further comprising an oxide insulating film over the stacked-layer oxide film, the source electrode, and the drain electrode,
wherein the oxide insulating film is in contact with a top surface of the stacked-layer oxide film between the source electrode and the drain electrode.

### Claim 5 (depends on 1)

The semiconductor device according to claim 1,
wherein the portions of the stacked-layer oxide film which are in contact with the source electrode and the drain electrode are n+ regions, and
wherein the n+ regions are formed in such a manner that oxygen in the stacked-layer oxide film is extracted into the source electrode and the drain electrode.

### Claim 6 (depends on 1)

The semiconductor device according to claim 1,
wherein the portions of the stacked-layer oxide film which are in contact with the source electrode and the drain electrode are n+ regions, and
wherein the n+ regions are extended in a region of the stacked-layer oxide film which is between the source electrode and the drain electrode.

### Claim 7

A semiconductor device comprising:
a gate electrode;
a gate insulating film overlapping with the gate electrode;
a stacked-layer oxide film including a channel formation region and overlapping with the gate electrode with the gate insulating film provided therebetween; and
a source electrode and a drain electrode in contact with the stacked-layer oxide film,
wherein the stacked-layer oxide film includes a first oxide layer and a second oxide layer over the first oxide layer,
wherein the second oxide layer comprises:
a depression portion between the source electrode and the drain electrode; and
low-resistance regions in portions in contact with the source electrode and the drain electrode and part of side surfaces of the depression portion, and
wherein a depth of the depression portion is greater than a depth of the low-resistance regions in a film thickness direction.

### Claim 8 (depends on 7)

The semiconductor device according to claim 7,
wherein the low-resistance regions have lowest resistance, and a portion of the stacked-layer oxide film has higher resistance as the portion is distanced from the source electrode or the drain electrode in the film thickness direction.

### Claim 9 (depends on 7)

The semiconductor device according to claim 7,
wherein the first oxide layer and the second oxide layer each contain In, Zn, and a metal other than In and Zn.

### Claim 10 (depends on 7)

The semiconductor device according to claim 7, further comprising an oxide insulating film over the stacked-layer oxide film, the source electrode, and the drain electrode,
wherein the oxide insulating film is in contact with a top surface of the depression portion.

### Claim 11 (depends on 7)

The semiconductor device according to claim 7,
wherein the low-resistance regions are formed in such a manner that oxygen in the second oxide layer is extracted into the source electrode and the drain electrode.

### Claim 12

A method for manufacturing a semiconductor device comprising the steps of:
forming a gate insulating film over a gate electrode;
forming an oxide semiconductor layer over the gate insulating film;
forming an oxide layer over the oxide semiconductor layer to form an stacked-layer oxide film containing the oxide semiconductor layer and the oxide layer;
processing the stacked-layer oxide film into a predetermined shape;
forming a conductive film containing Ti as a main component over and in contact with the stacked-layer oxide film;
etching the conductive film to form a source electrode and a drain electrode, wherein a depression portion is formed in the oxide layer between the source electrode and the drain electrode; and
performing a heat treatment, wherein low-resistance regions are formed in portions of the oxide layer which are in contact with the source electrode and the drain electrode, wherein a depth of the depression portion is greater than a depth of the low-resistance regions in a film thickness direction.

### Claim 13 (depends on 12)

The method for manufacturing a semiconductor device according to claim 12,
wherein the oxide semiconductor layer and the oxide layer are each an oxide containing In, M (Al, Ga, Y, La, Ce, or Nd), and Zn, and
wherein the oxide layer has a proportion of M higher than the oxide semiconductor layer.

### Claim 14 (depends on 12)

The method for manufacturing a semiconductor device according to claim 12,
wherein the heat treatment is not performed between the step of processing the stacked-layer oxide film into the predetermined shape and the step of etching the conductive film.

### Claim 15 (depends on 12)

The method for manufacturing a semiconductor device according to claim 12,
wherein the low-resistance regions are formed in such a manner that oxygen in the oxide layer is extracted into the source electrode and the drain electrode.

### Claim 16 (depends on 12)

The method for manufacturing a semiconductor device according to claim 12, wherein the conductive film is a stack of a first conductive layer containing Ti as a main component and a second conductive layer.

### Claim 17 (depends on 16)

The method for manufacturing a semiconductor device according to claim 16, wherein the second conductive layer is any of a conductive layer containing Cu as a main component, a conductive layer containing Al as a main component, and a stack of a conductive layer containing Al as a main component and a conductive layer containing Ti as a main component.

### Claim 18 (depends on 12)

The method for manufacturing a semiconductor device according to claim 12,
wherein the low-resistance regions have lowest resistance, and a portion of the stacked-layer oxide film has higher resistance as the portion is distanced from the source electrode or the drain electrode in the film thickness direction

### Claim 19 (depends on 12)

The method for manufacturing a semiconductor device according to claim 12, further comprising the step of forming an oxide insulating film over the stacked-layer oxide film, the source electrode, and the drain electrode,
wherein the heat treatment is performed after the formation of the oxide insulating film.

### Claim 20 (depends on 19)

The method for manufacturing a semiconductor device according to claim 19,
wherein the oxide insulating film includes a first film configured to permeate oxygen and a second film containing oxygen at a proportion higher than a proportion of oxygen in the stoichiometric composition over the first film, and
wherein the oxygen is released from the second film and moves to the stacked-layer oxide film through the first film by the heat treatment.
