# US 2014/0151320 A1 · Glass containers with delamination resistance and improved damage tolerance > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2014/0151320 A1 - Document ID: US20140151320A1 - Status: Published application - Kind: A1 - Application number: 14/075,620 - Filed: 2013-11-08 - Published: 2014-06-05 - Earliest claimed: 2012-11-30 - Assignees: Corning Incorporated - Applicants: Corning Incorporated - Inventors: Theresa Chang; Paul Stephen Danielson; Steven Edward DeMartino; Andrei Gennadyevich Fadeev; Robert Michael Morena; Santona Pal; John Stephen Peanasky; Robert Anthony Schaut; Natesan Venkataraman; Ronald Luce Verkleeran - Web page: https://patentgrep.com/patent/US20140151320A1 ## CPC - A61J 1/1468: {Containers characterised by specific material properties} - A61J 1/065: {Rigid ampoules, e.g. glass ampoules} - B32B 17/06: comprising glass as the main or only constituent of a layer, next to another layer of a specific {material} - B65D 1/0207: {characterised by material, e.g. composition, physical features} - B65D 1/0215: {multilayered (B65D81/3837 takes precedence)} - B65D 1/40: Details of walls (other container details B65D23/00, B65D25/00) - B65D 23/02: Linings or internal coatings - B65D 23/0814: {characterised by the composition of the material} - B65D 23/0821: {consisting mainly of polymeric materials (B65D23/0828 takes precedence)} - B65D 25/14: Linings or internal coatings (of containers made by folding or erecting blanks made of paper B65D5/56 {; linings for domestic water storage heaters F24H1/183}) - B65D 25/34: Coverings or external coatings (of containers made by folding or erecting blanks made of paper B65D5/62; covering or external coating for bottles or jars not otherwise provided for B65D23/08; wrappers B65D65/00) - C03B 23/04: Re-forming tubes or rods - C03C 15/02: for making a smooth surface - C03C 17/005: {Coating the outside} - C03C 17/22: with other inorganic material (C03C17/34, C03C17/44 take precedence) - C03C 17/30: with silicon-containing compounds - C03C 17/32: with synthetic or natural resins (C03C17/30 takes precedence) - C03C 17/3405: {with at least two coatings of organic materials (C03C17/36, C03C17/42 take precedence)} - C03C 17/42: at least one coating of an organic material and at least one non-metal coating - C03C 21/002: {to perform ion-exchange between alkali ions (C03C21/005 takes precedence)} - C09D 179/08: Polyimides; Polyester-imides; Polyamide-imides; Polyamide acids or similar polyimide precursors - C03C 2217/78: Coatings specially designed to be durable, e.g. scratch-resistant - C03C 2218/111: by dipping, immersion - Y10T 428/13: Hollow or container type article [e.g., tube, vase, etc.] - Y10T 428/131: Glass, ceramic, or sintered, fused, fired, or calcined metal oxide or metal carbide containing [e.g., porcelain, brick, cement, etc.] - Y10T 428/1317: Multilayer [continuous layer] - Y10T 428/24802: Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.] - Y10T 428/315: Surface modified glass [e.g., tempered, strengthened, etc.] - A61J: CONTAINERS SPECIALLY ADAPTED FOR MEDICAL OR PHARMACEUTICAL PURPOSES; DEVICES OR METHODS SPECIALLY ADAPTED FOR BRINGING PHARMACEUTICAL PRODUCTS INTO PARTICULAR PHYSICAL OR ADMINISTERING FORMS; DEVICES FOR ADMINISTERING FOOD OR MEDICINES ORALLY; BABY COMFORTERS; DEVICES FOR RECEIVING SPITTLE - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM - B65D: CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES - C03B: MANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES - C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS - C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D) - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract The glass containers described herein have at least two performance attributes selected from resistance to delamination, improved strength, and increased damage resistance. In one embodiment, a glass container may include a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. At least the inner surface of the body may have a delamination factor less than or equal to 10. A tenacious inorganic coating may be positioned around at least a portion of the outer surface of the body. The outer surface of the body with the tenacious inorganic coating may have a coefficient of friction less than or equal to 0.7. ## Claims ### Claim 1 A glass container comprising: a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface, wherein at least the inner surface of the body has a delamination factor less than or equal to 10; and a tenacious inorganic coating positioned around at least a portion of the outer surface of the body, wherein the outer surface of the body with the tenacious inorganic coating has a coefficient of friction less than or equal to 0.7. ### Claim 2 (depends on 1) The glass container of claim 1, wherein the tenacious inorganic coating is thermally stable at a temperature of at least about 250° C. for 30 minutes. ### Claim 3 (depends on 2) The glass container of claim 2, wherein the tenacious inorganic coating is thermally stable at a temperature of at least about 280° C. for 30 minutes. ### Claim 4 (depends on 1) The glass container of claim 1, wherein the tenacious inorganic coating is a metal nitride coating, a metal oxide coating, a metal sulfide coating, SiO2, diamond-like carbon, graphenes, or a carbide coating. ### Claim 5 (depends on 4) The glass container of claim 4, wherein the tenacious inorganic coating comprises at least one of TiN, BN, hBN, TiO2, Ta2O5, HfO2, Nb2O5, V2O5, SiO2, MoS2, SiC, SnO, SnO2, ZrO2, Al2O3, BN, ZnO, and BC. ### Claim 6 (depends on 1) The glass container of claim 1, wherein the body has an interior region extending between the inner surface of the body and the outer surface of the body, the interior region having a persistent layer homogeneity. ### Claim 7 (depends on 6) The glass container of claim 6, wherein the interior region has a thickness of at least 100 nm. ### Claim 8 (depends on 1) The glass container of claim 1, wherein the inner surface of the body has a persistent surface homogeneity. ### Claim 9 (depends on 8) The glass container of claim 8, wherein the persistent surface homogeneity extends into the wall thickness of the body to a depth DSR of at least 10 nm from the inner surface of the body. ### Claim 10 (depends on 1) The glass container of claim 1, wherein the inner surface of the body is etched. ### Claim 11 (depends on 1) The glass container of claim 1, wherein the inner surface of the body is acid etched. ### Claim 12 (depends on 1) The glass container of claim 1 wherein the inner surface of the body is a barrier coating. ### Claim 13 (depends on 12) The glass container of claim 12, wherein the barrier coating is an inorganic coating is a metal nitride coating, a metal oxide coating, a metal sulfide coating, SiO2, diamond-like carbon, graphenes, or a carbide coating. ### Claim 14 (depends on 12) The glass container of claim 12, wherein the barrier coating comprises at least one of Al2O3, TiO2, ZrO2, SnO, SnO2, SiO2, Ta2O5, Nb2O5, Cr2O3, V2O5, ZnO or HfO2, or combinations thereof. ### Claim 15 (depends on 12) The glass container of claim 12, wherein the barrier coating comprises at least one of a polybenzimidazoles, polybisoxazoles, polybisthiazoles, polyetherimides, polyquinolines, polythiophenes, phenylene sulfides, polysulfones, polycyanurates, parylenes, fluorinated polyolefins including polytetrafluorethylenes and other fluoro-substituted polyolefins, perfluoroalkoxy polymers, polyether ether ketones (PEEK), polyamides, epoxies, polyphenolics, polyurethane acrylates, cyclic olefin copolymer and cyclic olefin polymers, polyolefins including polyethylenes, oxidized polyethylenes, polypropylenes, polyethylene/propylene copolymers, polyethylene/vinyl acetate copolymers, polyvinylchloride, polyacrylates, polymethacrylates, polystyrenes, polyterpenes, polyanhydrides, polymaleicanhydrides, polyformaldehydes, polyacetals and copolymers of polyacetals, polysiloxanes of dimethyl or diphenyl or methyl/phenyl mixtures, perfluorinated siloxanes and other substituted siloxanes, polyimides, polycarbonates, polyesters, parafins and waxes, or various combinations thereof. ### Claim 16 (depends on 1) The glass container of claim 1, wherein the body has at least a class S3 acid resistance or better according to DIN 12116. ### Claim 17 (depends on 1) The glass container of claim 1, wherein the body has at least a class A2 base resistance or better according to ISO 695. ### Claim 18 (depends on 1) The glass container of claim 1, wherein the body has at least a type HgB2 hydrolytic resistance or better according to ISO 719. ### Claim 19 (depends on 1) The glass container of claim 1, wherein the body has at least a type HgA2 hydrolytic resistance or better according to ISO 720. ### Claim 20 (depends on 1) The glass container of claim 1, wherein the body has a Type 1 chemical durability according to USP <660>. ### Claim 21 (depends on 1) The glass container of claim 1, wherein the body is a mold-formed body. ### Claim 22 (depends on 1) The glass container of claim 1, wherein the body is formed with a glass forming process in which the body is monotonically cooled from a glass melt. ### Claim 23 (depends on 1) The glass container of claim 1, wherein the body is formed from an aluminosilicate glass composition. ### Claim 24 (depends on 1) The glass container of claim 1, wherein the body is formed from an alkali-aluminosilicate glass composition. ### Claim 25 (depends on 24) The glass container of claim 24, wherein the alkali-aluminosilicate glass composition is substantially free from boron and compounds containing boron. ### Claim 26 (depends on 24) The glass container of claim 24, wherein the alkali-aluminosilicate glass composition is substantially free from zinc and compounds containing zinc. ### Claim 27 (depends on 24) The glass container of claim 24, wherein the alkali-aluminosilicate glass composition is substantially free from phosphorous and compounds containing phosphorous. ### Claim 28 (depends on 1) The glass container of claim 1, wherein the body is formed from a glass composition comprising: from about 67 mol. % to about 75 mol. % SiO2; from about 6 mol. % to about 10 mol. % Al2O3; from about 5 mol. % to about 12 mol. % alkali oxide, wherein the alkali oxide comprises from about 2.5 mol. % to about 10 mol % Na2O and greater than about 0 mol. % to about 2.5 mol. % K2O; from about 9 mol. % to about 15 mol. % alkaline earth oxide; and from about 0 mol. % to about 0.5 mol. % SnO2. ### Claim 29 (depends on 28) The glass container of claim 28, wherein the glass composition is substantially free from boron and compounds containing boron. ### Claim 30 (depends on 28) The glass container of claim 28, wherein the glass composition is substantially free from zinc and compounds containing zinc. ### Claim 31 (depends on 28) The glass container of claim 28, wherein the glass composition is substantially free from phosphorous and compounds containing phosphorous. ### Claim 32 (depends on 1) The glass container of claim 1, wherein the body is formed from a Type I, Class B glass according to ASTM Standard E438-92. ### Claim 33 (depends on 32) The glass container of claim 32, wherein the Type I, Class B glass according to ASTM Standard E438-92 is substantially free from zinc and compounds containing zinc. ### Claim 34 (depends on 1) The glass container of claim 1, wherein the glass container is a pharmaceutical package. ### Claim 35 A glass container comprising: a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface, wherein at least the inner surface of the body has a delamination factor less than or equal to 10; and an transient coating positioned around at least a portion of the outer surface of the body, wherein the outer surface of the body with the transient coating has a coefficient of friction less than or equal to 0.7. ### Claim 36 (depends on 35) The glass container of claim 35, wherein the transient coating pyrolizes at temperatures less than or equal to 300° C. in less than or equal to 1 hour. ### Claim 37 (depends on 35) The glass container of claim 35, wherein the transient coating comprises a mixture of polyoxyethylene glycol, methacrylate resin, melamine formaldehyde resin, and polyvinyl alcohol. ### Claim 38 (depends on 35) The glass container of claim 35, wherein the transient coating comprises one or more polysaccharides. ### Claim 39 (depends on 35) The glass container of claim 35, wherein the transient coating comprises polyacrylic acid or a derivative of polyacrylic acid. ### Claim 40 (depends on 38) The glass container of claim 38, wherein the transient coating comprises an inorganic salt. ### Claim 41 (depends on 35) The glass container of claim 35, wherein the transient coating comprises at least one of: poly(ethylene oxides), poly(propylene oxides), ethylene oxide-propylene oxide copolymers, polyvinyl-pyrrolidinones, polyethyleneimines, poly(methyl vinyl ethers), polyacrylamides, polymethacrylamides, polyurethanes, poly(vinylacetates), polyvinyl formal, polyformaldehydes including polyacetals and acetal copolymers, poly(alkyl methacrylates), methyl celluloses, ethyl celluloses, hydroxyethyl celluloses, hydroxypropyl celluloses, sodium carboxymethyl celluloses, methyl hydroxypropyl celluloses, poly(acrylic acids) and salts thereof, poly(methacrylic acids) and salts thereof, ethylene-maleic anhydride copolymers, ethylene-vinyl alcohol copolymers, ethylene-acrylic acid copolymers, vinyl acetate-vinyl alcohol copolymers, methyl vinyl ether-maleic anhydride copolymers, emulsifiable polyurethanes, polyoxyethylene stearates, and polyolefins including polyethylenes, polypropylenes and copolymers thereof, starches and modified starches, hydrocolloids, polyacryloamide, vegetable and animal fats, wax, tallow, soap, stearine-paraffin emulsions, polysiloxanes of dimethyl or diphenyl or methyl/phenyl mixtures, perfluorinated siloxanes and other substituted siloxanes, alkylsilanes, aromatic silanes, and oxidized polyethylene. ### Claim 42 (depends on 35) The glass container of claim 35, wherein the body has an interior region extending between the inner surface of the body and the outer surface of the body, the interior region having a persistent layer homogeneity. ### Claim 43 (depends on 42) The glass container of claim 42, wherein the interior region has a thickness of at least 100 nm. ### Claim 44 (depends on 35) The glass container of claim 35, wherein the inner surface of the body has a persistent surface homogeneity. ### Claim 45 (depends on 44) The glass container of claim 44, wherein the persistent surface homogeneity extends into the wall thickness of the body to a depth DSR of at least 10 nm from the inner surface of the body. ### Claim 46 (depends on 44) The glass container of claim 44, wherein the inner surface of the body is etched. ### Claim 47 (depends on 44) The glass container of claim 44, wherein the inner surface of the body is acid etched. ### Claim 48 (depends on 35) The glass container of claim 35, wherein the inner surface of the body is a barrier coating. ### Claim 49 (depends on 48) The glass container of claim 48, wherein the barrier coating is a metal nitride coating, a metal oxide coating, a metal sulfide coating, SiO2, diamond-like carbon, graphenes, or a carbide coating. ### Claim 50 (depends on 48) The glass container of claim 48, wherein the barrier coating comprises at least one of Al2O3, TiO2, ZrO2, SnO, SnO2, SiO2, Ta2O5, Nb2O5, Cr2O3, V2O5, ZnO or HfO2, or combinations thereof. ### Claim 51 (depends on 48) The glass container of claim 48, wherein the barrier coating comprises at least one of a polybenzimidazoles, polybisoxazoles, polybisthiazoles, polyetherimides, polyquinolines, polythiophenes, phenylene sulfides, polysulfones, polycyanurates, parylenes, fluorinated polyolefins including polytetrafluorethylenes and other fluoro-substituted polyolefins, perfluoroalkoxy polymers, polyether ether ketones (PEEK), polyamides, epoxies, polyphenolics, polyurethane acrylates, cyclic olefin copolymer and cyclic olefin polymers, polyolefins including polyethylenes, oxidized polyethylenes, polypropylenes, polyethylene/propylene copolymers, polyethylene/vinyl acetate copolymers, polyvinylchloride, polyacrylates, polymethacrylates, polystyrenes, polyterpenes, polyanhydrides, polymaleicanhydrides, polyformaldehydes, polyacetals and copolymers of polyacetals, polysiloxanes of dimethyl or diphenyl or methyl/phenyl mixtures, perfluorinated siloxanes and other substituted siloxanes, polyimides, polycarbonates, polyesters, parafins and waxes, or various combinations thereof. ### Claim 52 (depends on 35) The glass container of claim 35, wherein the body has at least a class S3 acid resistance or better according to DIN 12116. ### Claim 53 (depends on 35) The glass container of claim 35, wherein the body has at least a class A2 base resistance or better according to ISO 695. ### Claim 54 (depends on 35) The glass container of claim 35, wherein the body has at least a type HgB2 hydrolytic resistance or better according to ISO 719. ### Claim 55 (depends on 35) The glass container of claim 35, wherein the body has at least a type HgA2 hydrolytic resistance or better according to ISO 720. ### Claim 56 (depends on 35) The glass container of claim 35, wherein the body has a Type 1 chemical durability according to USP <660>. ### Claim 57 (depends on 35) The glass container of claim 35, wherein the body is formed with a glass forming process in which the body is monotonically cooled from a glass melt. ### Claim 58 (depends on 35) The glass container of claim 35, wherein the body is formed from an aluminosilicate glass composition. ### Claim 59 (depends on 35) The glass container of claim 35, wherein the body is formed from an alkali-aluminosilicate glass composition. ### Claim 60 (depends on 35) The glass container of claim 35, wherein the alkali-aluminosilicate glass composition is substantially free from boron and compounds containing boron. ### Claim 61 (depends on 35) The glass container of claim 35, wherein the alkali-aluminosilicate glass composition is substantially free from zinc and compounds containing zinc. ### Claim 62 (depends on 35) The glass container of claim 35, wherein the alkali-aluminosilicate glass composition is substantially free from phosphorous and compounds containing phosphorous. ### Claim 63 (depends on 35) The glass container of claim 35, wherein the body is formed from a glass composition comprising: from about 67 mol. % to about 75 mol. % SiO2; from about 6 mol. % to about 10 mol. % Al2O3; from about 5 mol. % to about 12 mol. % alkali oxide, wherein the alkali oxide comprises from about 2.5 mol. % to about 10 mol % Na2O and greater than about 0 mol. % to about 2.5 mol. % K2O; from about 9 mol. % to about 15 mol. % alkaline earth oxide; and from about 0 mol. % to about 0.5 mol. % SnO2. ### Claim 64 (depends on 63) The glass container of claim 63, wherein the glass composition comprises from about 0 mol. % to about 3 mol. % B2O3. ### Claim 65 (depends on 63) The glass container of claim 63, wherein the glass composition is substantially free from boron and compounds containing boron. ### Claim 66 (depends on 63) The glass container of claim 63, wherein the glass composition is substantially free from zinc and compounds containing zinc. ### Claim 67 (depends on 63) The glass container of claim 63, wherein the glass composition is substantially free from phosphorous and compounds containing phosphorous. ### Claim 68 (depends on 38) The glass container of claim 38, wherein the body is formed from a Type I, Class B glass according to ASTM Standard E438-92. ### Claim 69 (depends on 68) The glass container of claim 68, wherein the Type I, Class B glass according to ASTM Standard E438-92 is free from zinc and compounds containing zinc. ### Claim 70 (depends on 35) The glass container of claim 35, wherein the glass container is formed from a glass composition which comprises greater than about 75 mol. % SiO2 and is substantially free from boron, alkali oxides, and alkaline oxides. ### Claim 71 (depends on 35) The glass container of claim 35, wherein the glass container is a pharmaceutical package. ### Claim 72 A glass container comprising: a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface, wherein at least the inner surface of the body has a delamination factor less than or equal to 10; and a tenacious organic coating positioned around at least a portion of the outer surface of the body, wherein the outer surface of the body with the tenacious organic coating has a coefficient of friction less than or equal to 0.7. ### Claim 73 (depends on 72) The glass container of claim 72, wherein the tenacious organic coating is thermally stable at a temperature of at least about 250° C. for 30 minutes. ### Claim 74 (depends on 72) The glass container of claim 72, wherein the tenacious organic coating is thermally stable at a temperature of at least about 280° C. for 30 minutes. ### Claim 75 (depends on 72) The glass container of claim 72, wherein a light transmission through the glass container is greater than or equal to about 55% of a light transmission through an uncoated glass article for wavelengths from about 400 nm to about 700 nm. ### Claim 76 (depends on 72) The glass container of claim 72, wherein the tenacious organic coating has a mass loss of less than about 5% of its mass when heated from a temperature of 150° C. to 350° C. at a ramp rate of about 10° C./minute. ### Claim 77 (depends on 72) The glass container of claim 72, wherein the tenacious organic coating comprises a polymer chemical composition. ### Claim 78 (depends on 77) The glass container of claim 77, wherein the tenacious organic coating further comprises a coupling agent. ### Claim 79 (depends on 72) The glass container of claim 72, wherein the body has an interior region extending between the inner surface of the body and the outer surface of the body, the interior region having a persistent layer homogeneity. ### Claim 80 (depends on 79) The glass container of claim 79, wherein the interior region has a thickness of at least 100 nm. ### Claim 81 (depends on 72) The glass container of claim 72, wherein the inner surface of the body has a persistent surface homogeneity. ### Claim 82 (depends on 81) The glass container of claim 81, wherein the persistent surface homogeneity extends into the wall thickness of the body to a depth DSR of at least 10 nm from the inner surface of the body. ### Claim 83 (depends on 72) The glass container of claim 72, wherein the inner surface of the body is etched. ### Claim 84 (depends on 72) The glass container of claim 72, wherin the inner surface of the body is acid etched. ### Claim 85 (depends on 72) The glass container of claim 72, wherein the inner surface of the body is a barrier coating. ### Claim 86 (depends on 85) The glass container of claim 85, wherein the barrier coating is a metal nitride coating, a metal oxide coating, a metal sulfide coating, SiO2, diamond-like carbon, graphenes, or a carbide coating. ### Claim 87 (depends on 85) The glass container of claim 85, wherein the barrier coating comprises at least one of Al2O3, TiO2, ZrO2, SnO, SnO2, SiO2, Ta2O5, Nb2O5, Cr2O3, V2O5, ZnO or HfO2 or combinations thereof. ### Claim 88 (depends on 85) The glass container of claim 85, wherein the barrier coating comprises at least one of a polybenzimidazoles, polybisoxazoles, polybisthiazoles, polyetherimides, polyquinolines, polythiophenes, phenylene sulfides, polysulfones, polycyanurates, parylenes, fluorinated polyolefins including polytetrafluorethylenes and other fluoro-substituted polyolefins, perfluoroalkoxy polymers, polyether ether ketones (PEEK), polyamides, epoxies, polyphenolics, polyurethane acrylates, cyclic olefin copolymer and cyclic olefin polymers, polyolefins including polyethylenes, oxidized polyethylenes, polypropylenes, polyethylene/propylene copolymers, polyethylene/vinyl acetate copolymers, polyvinylchloride, polyacrylates, polymethacrylates, polystyrenes, polyterpenes, polyanhydrides, polymaleicanhydrides, polyformaldehydes, polyacetals and copolymers of polyacetals, polysiloxanes of dimethyl or diphenyl or methyl/phenyl mixtures, perfluorinated siloxanes and other substituted siloxanes, polyimides, polycarbonates, polyesters, parafins and waxes, or various combinations thereof. ### Claim 89 (depends on 72) The glass container of claim 72, wherein the body has at least a class S3 acid resistance or better according to DIN 12116. ### Claim 90 (depends on 72) The glass container of claim 72, wherein the body has at least a class A2 base resistance or better according to ISO 695. ### Claim 91 (depends on 72) The glass container of claim 72, wherein the body has at least a type HgB2 hydrolytic resistance or better according to ISO 719. ### Claim 92 (depends on 72) The glass container of claim 72, wherein the body has at least a type HgA2 hydrolytic resistance or better according to ISO 720. ### Claim 93 (depends on 72) The glass container of claim 72, wherein the body has a Type 1 chemical durability according to USP <660>. ### Claim 94 (depends on 72) The glass container of claim 72, wherein the body is a mold-formed body. ### Claim 95 (depends on 94) The glass container of claim 94, wherein the body is formed with a glass forming process in which the body is monotonically cooled from a glass melt. ### Claim 96 (depends on 72) The glass container of claim 72, wherein the body is formed from an aluminosilicate glass composition. ### Claim 97 (depends on 72) The glass container of claim 72, wherein the body is formed from an alkali-aluminosilicate glass composition. ### Claim 98 (depends on 97) The glass container of claim 97, wherein the alkali-aluminosilicate glass composition is substantially free from boron and compounds containing boron. ### Claim 99 (depends on 97) The glass container of claim 97, wherein the alkali-aluminosilicate glass composition is substantially free from zinc and compounds containing zinc. ### Claim 100 (depends on 97) The glass container of claim 97, wherein the alkali-aluminosilicate glass composition is substantially free from phosphorous and compounds containing phosphorous. ### Claim 101 (depends on 72) The glass container of claim 72, wherein the body is formed from a glass composition comprising: from about 67 mol. % to about 75 mol. % SiO2; from about 6 mol. % to about 10 mol. % Al2O3; from about 5 mol. % to about 12 mol. % alkali oxide, wherein the alkali oxide comprises from about 2.5 mol. % to about 10 mol % Na2O and greater than about 0 mol. % to about 2.5 mol. % K2O; from about 9 mol. % to about 15 mol. % alkaline earth oxide; and from about 0 mol. % to about 0.5 mol. % SnO2. ### Claim 102 (depends on 101) The glass container of claim 101, wherein the glass composition is substantially free from boron and compounds containing boron. ### Claim 103 (depends on 101) The glass container of claim 101, wherein the glass composition is substantially free from zinc and compounds containing zinc. ### Claim 104 (depends on 101) The glass container of claim 101, wherein the glass composition is substantially free from phosphorous and compounds containing phosphorous. ### Claim 105 (depends on 72) The glass container of claim 72, wherein the body is formed from a Type I, Class B glass according to ASTM Standard E438-92. ### Claim 106 (depends on 105) The glass container of claim 105, wherein the Type I, Class B glass according to ASTM Standard E438-92 is substantially free from zinc and compounds containing zinc. ### Claim 107 (depends on 72) The glass container of claim 72, wherein the glass container is formed from a glass composition which comprises greater than about 75 mol. % SiO2 and is substantially free from boron, alkali oxides and alkali oxides. ### Claim 108 (depends on 72) The glass container of claim 72, wherein the glass container is a pharmaceutical package. ### Claim 109 A glass container comprising: a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface, wherein the body is formed from a Type I, Class B glass according to ASTM Standard E438-92; a barrier coating positioned on the inner surface of the body such that a composition contained in the glass container does not contact the inner surface of the body; and a lubricous coating positioned around at least a portion of the outer surface of the body, wherein the outer surface of the body with the lubricous coating has a coefficient of friction less than or equal to 0.7. ### Claim 110 (depends on 109) The glass container of claim 109, wherein the body with the barrier coating has a delamination factor of less than or equal to 10. ### Claim 111 (depends on 109) The glass container of claim 109, wherein the lubricous coating is thermally stable at a temperature of at least about 250° C. for 30 minutes. ### Claim 112 (depends on 111) The glass container of claim 111, wherein the lubricous coating is thermally stable at a temperature of at least about 280° C. for 30 minutes. ### Claim 113 A glass container comprising: a body having an inner surface, an outer surface and a wall thickness extending from the outer surface to the inner surface, wherein the body has a hydrolytic resistance of at least HGB2 or better according to the ISO 719 standard and is formed from a glass composition which is free from constituent components which form species that volatilize significantly at temperatures corresponding to a viscosity in a range from about 200 poise to about 100 kilopoise; and a lubricous coating positioned around at least a portion of the outer surface of the body, wherein the outer surface of the body with the lubricous coating has a coefficient of friction less than or equal to 0.7. ### Claim 114 (depends on 113) The glass container of claim 113, wherein the lubricous coating is thermally stable at a temperature of at least about 250° C. for 30 minutes. ### Claim 115 (depends on 114) The glass container of claim 114, wherein the lubricous coating is thermally stable at a temperature of at least about 280° C. for 30 minutes. ### Claim 116 (depends on 113) The glass container of claim 113, wherein at least the inner surface of the body has a delamination factor less than or equal to 10. ### Claim 117 A glass container comprising: a body having an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface, wherein the body is formed from a Type I, Class B glass according to ASTM Standard E438-92; and a lubricous coating positioned around at least a portion of the outer surface of the body, wherein the outer surface of the body with the lubricous coating has a coefficient of friction less than or equal to 0.7, wherein the body is formed under processing conditions which mitigate the vaporization of volatile species in the glass. ### Claim 118 (depends on 117) The glass container of claim 117, wherein the body is formed at forming temperatures which are less than a lowest vaporization temperature of the volatile species in the glass. ### Claim 119 (depends on 117) The glass container of claim 117, wherein the body is formed at forming speeds which are less than forming speeds at which volatile species in the glass composition vaporize. ### Claim 120 (depends on 117) The glass container of claim 117, wherein the lubricous coating is thermally stable at a temperature of at least about 250° C. for 30 minutes. ### Claim 121 (depends on 120) The glass container of claim 120, wherein the lubricous coating is thermally stable at a temperature of at least about 280° C. for 30 minutes. ### Claim 122 (depends on 117) The glass container of claim 117, wherein at least the inner surface of the body has a delamination factor less than or equal to 10.