Azo compound and ink containing the compound
AssigneeMitsubishi Chemical Corporation
InventorsUtako TAKEDA, Shoko Ichinosawa, Yuki Tanaka, Hiroyuki Aikyo, Mio Ishida
Life of this patent
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Abstract
An object of the present invention is to provide an ink containing an azo compound which is excellent in solubility in a solvent and has a high extinction coefficient. The present invention relates to an ink comprising a solvent having a relative permittivity of 3 or less, as measured at a frequency of 1 kHz and at 22° C. and having a solubility in water of 20 mg/L or less at 25° C. and a specific azo compound.
Claims15
An ink comprising:
- a solvent having a relative permittivity of 3 or less, as measured at a frequency of 1 kHz and at 22° C., and having a solubility in water of 20 mg/L or less at 25° C.;
- and an azo compound, the azo compound being represented by the following general formula (I):
- wherein
- R1, R2, D1, A1, and A2 each independently represent an arbitrary substituent,
- m represents an integer of 1 to 4, and when m is 2 or larger, two or more D1 groups present in one molecule may be the same or different, and
- X represents a nitrogen atom or an optionally substituted methine group.
An azo compound represented by the following general formula (VIII):
- wherein
- R601 and R602 each independently represent an optionally substituted branched alkyl group having 7 to 20 carbon atoms,
- D9 represents a hydrogen atom, a halogen atom, an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted alkoxy group having 1 to 20 carbon atoms, an —NHCOR603 group, or an —NHSO2R608 group,
- R603 and R608 each independently represent an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms,
- a represents an integer of 1 to 4, and when a is 2 or larger, two or more D9 groups present in one molecule may be the same or different,
- A3 represents a halogen atom, a cyano group, an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, an optionally substituted heteroaryl group having 2 to 20 carbon atoms, an optionally substituted alkoxy group having 1 to 20 carbon atoms, or a —COOR604 group,
- R604 represents an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms,
- A4 represents a halogen atom, an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted alkenyl group having 2 to 20 carbon atoms, an optionally substituted alkylcarbonyl group having 2 to 20 carbon atoms, an optionally substituted alkoxycarbonyl group having 2 to 20 carbon atoms, a formyl group, an R605OOC(NC)C═CH— group, or an NC(NC)C═CH— group,
- R605 represents an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms,
- X2 represents a nitrogen atom, or a methine group which may have a halogen atom, a cyano group, or a —COOR607 group as a substituent, and
- R607 represents an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms.
An azo compound represented by the following general formula (IX):
- wherein
- R701 and R702 each independently represent an optionally substituted branched alkyl group having 5 to 20 carbon atoms,
- D11 represents a hydrogen atom, a halogen atom, an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted alkoxy group having 1 to 20 carbon atoms, an —NHCOR703 group, or an —NHSO2R708 group,
- R703 and R708 each independently represent an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms,
- d represents an integer of 1 to 4, and when d is 2 or larger, two or more D11 groups present in one molecule may be the same or different,
- A5 represents a hydrogen atom, a halogen atom, a cyano group, an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, an optionally substituted heteroaryl group having 2 to 20 carbon atoms, an optionally substituted alkoxy group having 1 to 20 carbon atoms, or a —COOR704 group,
- R704 represents an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms,
- D10 represents a hydrogen atom, a halogen atom, a cyano group, an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted alkoxy group having 1 to 20 carbon atoms, a —COOR706 group, a —COR709 group, or an —OCOR710 group,
- b represents an integer of 1 to 5, and when b is 2 or larger, two or more D10 groups present in one molecule may be the same or different,
- R706, R709, and R710 each independently represent an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms,
- X3 represents a nitrogen atom, or a methine group which may have a halogen atom, a cyano group, or a —COOR707 group as a substituent, and
- R707 represents an optionally substituted alkyl group having 1 to 20 carbon atoms, an optionally substituted aryl group having 6 to 20 carbon atoms, or an optionally substituted heteroaryl group having 2 to 20 carbon atoms.
Dependencies are inferred from the claim text.