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US 2014/0005408 A1Published application
Metal complexes, their application and methods of carrying out of metathesis reaction
AssigneeApeiron Synthesis S.A.
InventorsKrzysztof Skowerski, Michal Bieniek
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Abstract
This disclosure relates to new metal complexes, such as compounds of Formula 1, and their application in olefin or alkyne metathesis and to methods of carrying out olefin metathesis reactions.
Claims29
A compound of a formula:
- wherein
- M is ruthenium or osmium;
- X and X1 are independently anionic ligands;
- L is neutral ligand;
- R1 is hydrogen, C1-20 alkyl, or C5-10 aryl;
- is optionally substituted o-phenylene, wherein 2 or more substituents of the o-phenylene may form an optionally substituted fused C4-8 carbocyclic ring an optionally substituted fused aromatic C5-14 ring;
- and
- R6, R7, and R8 are independently H, C1-6 alkyl, optionally substituted C4-10 heterocyclyl, or optionally substituted C5-14 aryl;
- wherein R7 and R8 may be linked together to form a substituted or unsubstituted C4-8 cyclic system.
6 more elements
19-24. (canceled)
Dependencies are inferred from the claim text.