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US 2014/0005245 A1Published application
Insecticidal compounds
AssigneeSyngenta Participations AG
InventorsPierre Joseph Marcel Jung, Ottmar Franz Hueter, Peter Renold, Thomas Pitterna
Life of this patent
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Abstract
The present invention relates to novel triazole derivatives of formula (I) having insecticidal activity, to processes and intermediates for preparing them, to insecticidal, acaricidal, nematicidal or molluscicidal compositions comprising them and to methods of using them to combat and control insect, acarine, nematode or mollusc pests wherein A1, A2, A3, A4, R1, R2, G1, Q1 and Q2 are as defined in claim 1; or salts or N— oxides thereof.
Claims11
A compound of formula (I)
- wherein
- A1, A2, A3 and A4 are each independently C—X or nitrogen, wherein each X may be the same or different;
- R1 is hydrogen, C1-C4alkyl, H2NC(O)—C1-C4alkyl, or C1-C4alkylcarbonyl;
- R2 is hydrogen, halogen, C1-C4alkyl, C1-C6 haloalkyl or cyano;
- G1 is oxygen or sulfur;
- X is hydrogen, halogen, cyano, C1-C4alkyloxy, C1-C4alkyl or C1-C4haloalkyl;
- Q1 is aryl or heterocyclyl, each optionally substituted by one to five substituents R3, which may be the same or different;
- or Q1 is C1-C8alkyl or C1-C8alkyl substituted by one to five R4, C2-C8alkenyl, C2-C8alkenyl substituted by one to five R4, C2-C8alkynyl, C2-C8alkynyl substituted by one to five R4, C3-C10cycloalkyl, C3-C10cycloalkyl substituted by one to five R4 or C1-C8alkyl-(CO)—N—C1-C8alkyl or C1-C8alkyl-(CO)—N—C1-C8alkyl substituted by one to five R4;
- R3 is selected from cyano, amino, nitro, hydroxy, oxo, halogen, C1-C4alkyl, C1-C4haloalkyl,
- C2-C4alkenyl, C2-C4haloalkenyl, C2-C4alkynyl, C2-C4haloalkynyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C3alkoxy, C1-C3haloalkoxy, C1-C3alkylthio, C1-C3haloalkylthio, C1-C3alkylsulfinyl, C1-C3haloalkylsulfinyl, C1-C3alkylsulfonyl, C1-C3haloalkylsulfonyl, C1-C4alkylamino, di-(C1-C4alkyl)amino, C1-C4alkylcarbonyl, C1-C4alkylcarbonyloxy, C1-C4alkoxycarbonyl, C1-C4alkylcarbonylamino and phenyl;
- each R4 is independently halogen, cyano, nitro, hydroxy, C3-C10cycloalkyl, C3-C10cycloalkyl substituted by one to five R3, di(C1-C8alkyl)amino, C1-C8alkanoylamino, C1-C8alkyl, C2-C8alkynyl, C1-C8alkoxy-, C1-C8haloalkoxy-, C1-C8alkylthio-, C1-C8haloalkylthio-, C1-C8alkylsulfinyl-, C1-C8haloalkylsulfinyl-, C1-C8alkylsulfonyl-, C1-C8haloalkylsulfonyl-, C1-C8alkylcarbonyl-, C1-C8alkoxycarbonyl-, aryl or aryl substituted by one to five R3, aryloxy or aryloxy substituted by one to five R3, or heterocyclyl or heterocyclyl substituted by one to five R3;
- Q2 is a moiety of formula (II)
- wherein
- R7 and R6 are independently of each other hydrogen, cyano, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C4alkoxy-C1-C4-alkyl, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkylsulfinyl, C1-C6haloalkylsulfinyl, C1-C6alkylsulfonyl or C1-C6haloalkylsulfonyl;
- R5 is independently hydrogen, hydroxyl, amino, N—C1-C6alkylamino, N,N-di-(C1-C6alkyl)amino, C1-C6alkyl, C3-C6cycloalkyl, C2-C6alkenyl, C2-C6alkynyl, C1-C6alkyl substituted by one to five substituents R9, C3-C6Cycloalkyl substituted by one to five substituents R9, C2-C6alkynyl substituted by one to five substituents R9, C2-C6alkenyl substituted by one to five substituents R9, aryl or aryl substituted by one to five substituents R10, heteroaryl or heteroaryl substituted by one to five substituents R10,
- each R9 is independently cyano, nitro, amino, hydroxy, halogen, N—C1-C6alkylamino, N,N-di-(C1-C6alkyl)amino, C1-C6alkoxy, C1-C6alkylthio, C1-C6alkylsulfinyl, aryl or aryl which is substituted by one to five substituents independently selected from cyano, nitro, hydroxyl, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy or C1-C6haloalkoxy, or heteroaryl or heteroaryl which is substituted by one to five substituents independently selected from cyano, nitro, hydroxy, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C6alkoxy or C1-C6haloalkoxy;
- each R10 is independently cyano, nitro, amino, hydroxy, halogen, C1-C6alkyl, C1-C6haloalkyl, C1-C4alkoxy-C1-C4-alkyl, C2-C6alkenyl, C2-C6haloalkenyl, C2-C6alkynyl, C2-C6haloalkynyl, C3-C6cycloalkyl, C3-C6halocycloalkyl, C1-C6alkoxy, C1-C6haloalkoxy, C1-C4alkoxy-C1-C4-alkoxy, C1-C6alkylthio, C1-C6haloalkylthio, C1-C6alkylsulfinyl, C1-C6haloalkylsulfinyl, C1-C6alkylsulfonyl, C1-C6haloalkylsulfonyl, N—C1-C6alkylamino, N,N-di-(C1-C6alkyl)amino, N,N-di-(C1-C6alkyl)-aminocarbonyl, N,N-di-(C1-C6alkyl)aminosulfonyl, C1-C6alkylcarbonyl, C1-C6alkylcarbonyloxy, C1-C6alkoxycarbonyl, C1-C6alkylcarbonylamino;
- or an agrochemically acceptable salt or N-oxides thereof.
15 more elements
A compound of formula (III) form
- wherein A1, A2, A3, A4, R2 and Q2 are as defined in relation to formula (I);
- or a salt thereof.
A compound of formula (IIIb)
- wherein A1, A2, A3, A4, R2 and Q2 are as defined in relation to formula (I);
- and R is C1-C6 alkyl or a salt thereof.
Dependencies are inferred from the claim text.