Method for preparing a catalyst composition for oligomerization of ethylene and respective catalyst composition pre-formation unit
AssigneeSaudi Basic Industries Corporation
InventorsAnina Wöhl, Wolfgang Müller, Heinz Bölt, Andreas Meiswinkel, Uwe Rosenthal, Bernd Müller, Normen Peulecke, Christian Thaller, Marco Harff, Stephan Peitz, Fuad Mosa, Mohammed H. Al-Hazmi, Shahid Azam
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Abstract
The present invention relates to a method for preparing a catalyst composition for the oligomerization of ethylene and a respective catalyst composition pre-formation unit.
Claims20
A method for preparing a catalyst composition for the oligomerization of ethylene comprising the steps:
- a) preparing in a first solvent, a first solution by mixing of a co-catalyst and a modifier, wherein the co-catalyst is selected from trialkyl aluminum, alkyl aluminum sesquichloride, dialkyl aluminum chloride, alkyl aluminum dichloride, wherein alkyl is preferably methyl, ethyl, isopropyl or isobutyl, methylaluminoxane (MAO) or mixtures thereof, and wherein the modifier is selected from ammonium or phosphonium salts of the type [H4E]X, [H3ER]X, [H2ER2]X, [HER3]X or [ER4]X or HX or RX with E=N or P, X═Cl, Br or I and R=alkyl, cycloalkyl, acyl, aryl, alkenyl, alkynyl or the corresponding bridging di-, tri- or multiunits, or ammonium or phosphonium salts based on cyclic amines;
- and
- b) adding a chromium compound and a ligand to the first solution obtained in step a) to obtain a second solution.
A catalyst composition pre-formation unit for preparing a catalyst composition for the oligomerization of ethylene, the catalyst composition, comprising a chromium compound, a ligand, a modifier and a co-catalyst, wherein the pre-formation unit comprises a first vessel (1) containing a solution of co-catalyst and modifier, a second vessel (2) containing chromium compound and ligand, the first and second vessel (1, 2) being connected via lines, to a mixing unit (3), the mixing unit (3) being connected via a line, to an oligomerization reactor (7).
The catalyst composition pre-formation unit according to claim 11, wherein the mixing unit is a vessel comprising stirring means.
Dependencies are inferred from the claim text.