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US 2014/0004464 A1Published application
Polymer composition, photoresist comprising the polymer composition, and coated article comprising the photoresist
AssigneesRohm and Haas Electronic Materials LLC, Dow Global Technologies LLC
InventorsMatthew D. CHRISTIANSON, Matthew M. MEYER, Owendi Ongayi
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Abstract
A copolymer comprises the polymerized product of a dissolution-rate controlling monomer having the formula (I), an acyclic vinyl ether monomer of the formula (II), and a cyclic vinyl ether monomer of the formula (III): wherein Ra, Rb, Rc, L, X, and Z1 are defined herein. A photoresist composition comprising the copolymer is described, as is an article coated with the photoresist composition, and a method of forming an electronic device using the photoresist composition.
Claims10
A copolymer, comprising the polymerized product of:
- a dissolution-rate controlling monomer having the formula (I), an acyclic vinyl ether monomer of the formula (II), and a cyclic vinyl ether monomer of the formula (III):
- wherein Ra is H, F, C1-10 alkyl, or C1-10 fluoroalkyl, provided Ra is C1-10 fluoroalkyl for at least one instance of the monomer of formula (I),
- X is O or NR wherein R is H, a C1-10 alkyl, or a C6-10 aryl,
- Z1 is a C1-20 alkylene, C3-20 cycloalkylene, C6-20 arylene, or C7-20 aralkylene, wherein Z1 optionally comprises an aromatic or non-aromatic hydroxyl, sulfonate, sulfonic acid, sulfonamide, sulfonimide, carboxylic acid, ester, carbonate, amide, or a combination comprising at least one of the foregoing,
- each Rb is independently H or a C1-20 alkyl, C3-20 cycloalkyl, C6-20 aryl, or C7-20 aralkyl, wherein Rb optionally comprises F, —C(═O)—O—, or a combination comprising at least one of the foregoing,
- Rc is a C1-20 alkyl, C3-20 cycloalkyl, C6-20 aryl, or C7-20 aralkyl, wherein Rc optionally comprises an F, —O—, —S—, NR—, —C(═O)—O—, or —OH, wherein R is H, C1-10 alkyl, C3-10 cycloalkyl, C6-10 aryl, or C6-10 aralkyl, and
- L is a containing C1-20 alkylene, C3-20 cycloalkylene, C6-20 arylene, or C7-20 aralkylene, and L optionally comprises F, —OH, or a combination comprising at least one of the foregoing.
4 more elements
Dependencies are inferred from the claim text.