A method of producing a positive electrode active material for lithium ion batteries, which is formed from LiMPO4 (provided that, M represents one or more kinds selected from a group consisting of Mn, Co, and Ni), by a hydrothermal synthesis method, the production method comprising:
- a step of adding one kind or two kinds selected from a group consisting of ammonia and amine-type compounds to raw material slurry obtained by mixing a Li source, a P source, and an M source (provided that, M represents one or more kinds selected from a group consisting of Mn, Co, and Ni) with a solvent containing water as a main component in such a manner that % by mole of an ammonia group of the ammonia or the amine-type compounds with respect to the M source becomes 1% by mole to 12% by mole to obtain a mixture;
- and
- a step of heating the mixture to a temperature equal to or higher than a boiling point of the raw material slurry.