Resin composition and molded product thereof
AssigneesBASF SE, The Nippon Synthetic Chemical Industry Co., Ltd.
InventorsMitsuo Shibutani, Norihito Sakai, Lars Boerger, Gabriel Skupin
Life of this patent
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Abstract
Provided is a resin composition from which a melt molded product which is excellent in transparency, gas barrier property and flexibility and has biodegradability can be obtained. The present invention relates to a resin composition, which comprises a polyvinyl alcohol-based resin (i) comprising a structural unit represented by the following general formula (1) and an aliphatic-aromatic polyester (ii) comprising a specific component, wherein each of R1, R2 and R3 independently represents a hydrogen atom or an organic group, X represents a single bond or a bonding chain, and each of R4, R5 and R6 independently represents a hydrogen atom or an organic group.
Claims16
A resin composition, which comprises a polyvinyl alcohol-based resin (i) comprising a structural unit represented by the following general formula (1) and an aliphatic-aromatic polyester (ii):
- wherein each of R1, R2 and R3 independently represents a hydrogen atom or an organic group, X represents a single bond or a bonding chain, and each of R4, R5 and R6 independently represents a hydrogen atom or an organic group;
- wherein the aliphatic-aromatic polyester (ii) includes a polyester comprising, as essential components:
- A) an acid component composed of
- a1) 40 to 75 mol % of at least one aliphatic dicarboxylic acid or its/their ester-forming derivatives or mixtures thereof,
- a2) 25 to 60 mol % of at least one aromatic dicarboxylic acid or its/their ester-forming derivative or mixtures thereof, and
- a3) 0 to 5 mol % of a sulfonated compound;
- B) a diol component composed of at least one C2- to C12-alkanediol or mixtures thereof;
- and, if desired, one or more components selected from
- C) a component selected from
- c1) at least one dihydroxy compound comprising ether functions and having the formula I
- [Chem. 2]
- HO—[(CH2)n—O]m—H (I)
- where n represents 2, 3 or 4 and m represents an integer from 2 to 250,
- c2) at least one hydroxy-carboxylic acid of the formula II
- [Chem. 3]
- HO—[C(O)-G-O]p—H (II)
- where p represents an integer from 1 to 1500 and G represents a radical selected from the group consisting of phenylene, o-hydroxyphenylene, —(CH2)q—, where q is an integer from 1 to 5, —C(R)H— and —C(R)HCH2, where R represents methyl or ethyl,
- c3) at least one amino-C2- to C12-alkanol or at least one amino-C5- to C10-cycloalkanol or mixtures thereof,
- c4) at least one diamino-C1- to C8-alkane,
- c5) at least one 2,2′-bisoxazoline of the general formula III
- where R1 represents a single bond, a (CH2)z alkylene group, where z=2, 3 or 4, or a phenylene group,
- c6) at least one amino carboxylic acid selected from the group consisting of natural amino acids, polyamides obtainable by polycondensation of a dicarboxylic acid having 4 to 6 carbon atoms and a diamine having 4 to 10 carbon atoms, compounds of the formula IV
- [Chem. 5]
- HO—[C(O)-T-O]s—H (IV)
- where s represents an integer from 1 to 1500 and T represents a radical selected from the group consisting of phenylene, —(CH2)u—, where u represents an integer from 1 to 12, —C(R2)H— and —C(R2)HCH2, where R2 represents methyl or ethyl,
- or mixtures of c1) to c6);
- and
- D) a component selected from:
- d1) a compound having at least three groups capable of ester formation,
- d2) a di- or polyisocyanate,
- d3) a di- or polyepoxide
- or mixtures of d1) to d3),
- wherein a content ratio (i)/(ii) of the polyvinyl alcohol-based resin (i) to the aliphatic-aromatic polyester (ii) is from 98/2 to 50/50 in terms of weight ratio.
Dependencies are inferred from the claim text.