Injection Stretch Blow Moulded Articles
AssigneeTotal Research & Technology Feluy
InventorsJean-Marie Boissiere, Aurelien Vantomme, Pierre Belloir, Alain Van Sinoy
Life of this patent
Estimating the term…
Abstract
This invention covers injection stretch blow moulded articles prepared from polyethylene resin having a bimodal molecular weight distribution (MWD), defined by the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), of from 2 to 20, comprising two polyethylene fractions A and B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a metallocene-containing catalyst system.
Claims18
An injection stretch blow moulded article prepared from high density polyethylene (HDPE) resin comprising:
- two polyethylene fractions comprising fraction A and fraction B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a metallocene-containing catalyst system;
- wherein the metallocene is selected from at least one of the following formula (I) or (II):
- wherein each R is the same or different and is selected from hydrogen or XR′v in which X is chosen from carbon, silicon, germanium, oxygen or nitrogen, and each R′ is the same or different and is chosen from hydrogen or a hydrocarbyl of from 1 to 20 carbon atoms and v+1 is the valence of X;
- wherein R″ is a structural bridge between the two indenyl or tetrahydrogenated indenyls to impart stereorigidity that comprises a C1-C4 alkylene radical, a dialkyl germanium, silicon or siloxane, or an alkyl phosphine or amine radical;
- wherein Q is a hydrocarbyl radical having from 1 to 20 carbon atoms or a halogen;
- and wherein M is a transition metal Group 4 of the Periodic Table or vanadium;
- wherein the HDPE resin has a bimodal molecular weight distribution (MWD), defined by the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), of from 2 to 20, a density, measured following the method of standard test ASTM 1505 at a temperature of 23° C., of from 0.950 to 0.965 g/cm3, and a melt index MI2, measured following the method of standard test ASTM D 1238 at a temperature of 190° C. and under a load of 2.16 kg, of from 0.5 to 5 g/10 min.
A method comprising preparing an injection stretch blow moulded article from a high density polyethylene (HDPE) resin, wherein the HDPE comprises:
- two polyethylene fractions comprising fraction A and fraction B, fraction A being substantially free of comonomer and having a lower weight average molecular weight and a higher density than fraction B, each fraction prepared in different reactors of two reactors connected in series in the presence of a metallocene-containing catalyst system,
- wherein the metallocene is selected from at least one of the following formula (I) or (II):
- wherein each R is the same or different and is selected from hydrogen or XR′v in which X is chosen from carbon, silicon, germanium, oxygen or nitrogen, and each R′ is the same or different and is chosen from hydrogen or a hydrocarbyl of from 1 to 20 carbon atoms and v+1 is the valence of X;
- wherein R″ is a structural bridge between the two indenyl or tetrahydrogenated indenyls to impart stereorigidity that comprises a C1-C4 alkylene radical, a dialkyl germanium, silicon or siloxane, or an alkyl phosphine or amine radical;
- wherein Q is a hydrocarbyl radical having from 1 to 20 carbon atoms or a halogen;
- and wherein M is a transition metal Group 4 of the Periodic Table or vanadium;
- wherein the HDPE resin has a bimodal molecular weight distribution (MWD), defined by the ratio of the weight average molecular weight (Mw) to the number average molecular weight (Mn), of from 2 to 20, a density, measured following the method of standard test ASTM 1505 at a temperature of 23° C., of from 0.950 to 0.965 g/cm3, and a melt index MI2, measured following the method of standard test ASTM D 1238 at a temperature of 190° C. and under a load of 2.16 kg, of from 0.5 to 5 g/10 min.
The injection stretch blow moulded article of 5, wherein the HDPE resin has a density of from 0.954 to 0.962 g/cm3.
Dependencies are inferred from the claim text.