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US 2014/0000824 A9Published application
Freeness of paper products
AssigneeCatexel Limited
InventorsRonald Hage, Kimberly Soraya Yang
Life of this patent
Estimating the term…
Abstract
The present invention provides for the optimisation of conditions for treating pulp with a catalyst and hydrogen peroxide to produce a Freeness value (SR) in a web produced from the treated pulp such that the energy required in mechanical agitation of the pulp is reduced.
Claims20
A method for the treatment of a cellulose pulp suspension comprising:
- (i) subjecting cellulose pulp fibres to an aqueous solution of a preformed manganese transition metal catalyst and hydrogen peroxide at pH from 6 to 13, wherein the manganese transition metal catalyst is present at a concentration from 0.0001 to 1 kg/tonne oven-dry pulp, and the hydrogen peroxide is present at a concentration from 0.1 to 100 kg/tonne oven-dry pulp;
- (ii) subjecting the cellulose pulp fibres treated by step (i) to a refining process until a Shopper Riegler (SR) value of from 10 to 90° is reached and the resultant pulp is processed into paper, tissue or board;
- and
- wherein the manganese transition metal catalyst is a mononuclear Mn(II), Mn(III), Mn(IV) or dinuclear Mn(II)Mn(II), Mn(II)Mn(III), Mn(III)Mn(III), Mn(III)Mn(IV) or Mn(IV)Mn(IV) transition metal catalyst, having a ligand of formula (I):
- p is 3;
- R is independently selected from the group consisting of:
- hydrogen, C1-C6-alkyl, CH2CH2OH, CH2COOH, and pyridin-2-ylmethyl;
- and
- R1, R2, R3, and R4 are independently selected from the group consisting of:
- H, C1-C4-alkyl, and C1-C4-alkylhydroxy.
7 more elements
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Dependencies are inferred from the claim text.