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US 2013/0296492 A1Published application
Functional diene block elastomer with a low pi and improved cold flow, and rubber composition containing same
AssigneesMichelin Recherche et Technique S.A., Compagnie Generale Des Etablissements Michelin
InventorsMathilde Abad, Margarita Dorato, Jean-Michel Favrot, Nathalie Simon, Jean Marc Marechal, Stéphanie De Landtsheer
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Abstract
The invention relates to a functionalized diene elastomer composed a) of a specific block copolymer functionalized, at the chain end or in the middle of the chain, by a tin functional group, b) of a specific block copolymer star-branched by tin and c) of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a specific non-tin-functional block copolymer.
Claims18
Functionalized diene elastomer composed:
- a) of a block copolymer functionalized, at the chain end or in the middle of the chain, by a tin functional group and corresponding to the following formula:
- [A-BnXB-A]m
- where n and m are integers of greater than or equal to 0 and such that n+m=1 or 2,
- b) of a block copolymer star-branched by tin and corresponding to the following formula:
- [A-BoYB-A]p
- where o and p are integers of greater than or equal to 0 and such that o+p≧3 and o+p≦6,
- c) of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a non-tin-functional block copolymer corresponding to the following formula:
- [A-B]
- where:
- all the A blocks are composed of a polyisoprene or all the A blocks are composed of a polybutadiene,
- the B blocks are composed of a diene elastomer, the molar content of units resulting from conjugated dienes of which is greater than 15%, the B blocks being identical to one another,
- X and Y independently represent a tin-comprising group,
- the number-average molecular weight Mn1 of each A block varies from 2 500 to 20 000 g/mol,
- the number-average molecular weight Mn2 of each B block varies from 80 000 to 350 000 g/mol,
- the content of 1,2 linkages in each A block is between 1 and 20% in the case where A is a polybutadiene block,
- the content of 3,4 linkages in each A block is between 1 and 25% in the case where A is a polyisoprene block,
- the A-B copolymer exhibits a monomodal distribution of molecular weights before optional functionalization or optional star-branching and a polydispersity index before optional functionalization or optional star-branching of less than or equal to 1.3.
14 more elements
Dependencies are inferred from the claim text.