Aromatic compounds bearing at least one phosphonate or phosphinate group, preparation method and uses thereof
OwnerFloryan De Campo, Tao Zhang +1inventors
InventorsFloryan De Campo, Tao Zhang, Changkai Zhou
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Abstract
An aromatic compound bearing at least a phosphonate or phosphinate group on the aromatic ring is described. Further described, is the process by which the aromatic compound is prepared, reacted with a reagent of formula (I) or (II) constituted of a diene backbone and bearing a phosphonate or phosphinate group on one of the double bonds, in the presence of a Lewis acid.
Claims30
A process for the preparation of an aromatic compound, the process comprising reacting an aromatic compound with the formula (III):
- wherein:
- A represents the residue of a cycle forming all or a portion of a monocyclic or polycyclic, aromatic, carbocyclic and/or heterocyclic system;
- R, which may be identical or different, represents substituents on the cycle;
- and
- n represents the number of substituents on the cycle,
- with a reagent of formula (I) or (II) constituted of a diene backbone and bearing a phosphonate or phosphinate group on one of the double bonds, in the presence of a Lewis acid:
- wherein:
- R1 and R2, represent, independently, hydrogen, alkyl, alkenyl, aryl, alkaryl, aralkyl, cycloalkyl, heterocycloalkyl, or alkenyl groups,
- R3 represents an alkyl group or an electron-donating group, and
- R4, R5 and R6 represent independently hydrogen, alkyl, aralkyl, cycloalkyl or metals selected from the group consisting of alkali metal or alkaline earth metal, wherein the resulting aromatic compound bears a phosphonate or phosphinate group on the aromatic ring.
The process as claimed in group 3, wherein the electron-donating group is selected from the group consisting of an alkoxy group containing 1 to 6 carbon atoms, a hydroxy group, an amino group and an alkylamide or arylamide group
Dependencies are inferred from the claim text.