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US 2013/0274355 A1Published application
Catalyst useful in fisher-tropsch synthesis
AssigneeSaudi Basic Industries Corporation
InventorsKhalid Karim, Saleh A. Al-Sayari
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Abstract
The present invention relates to a catalyst composition comprising cobalt manganese oxide which is modified with lanthanum and/or phosphorus and optionally one or more basic elements selected from the group consisting of alkali metal, alkaline earth metal and transition metal. Furthermore, a method for preparing said catalyst composition and a process for producing aliphatic and aromatic hydrocarbons by Fischer-Tropsch synthesis using said catalyst composition is provided.
Claims14
A catalyst composition comprising:
- cobalt;
- manganese;
- and at least one element selected from the group of lanthanum and phosphorus,
- wherein the relative molar ratios of the elements comprised in the composition are represented by the formula
- CoMnaLabPcMdOx
- wherein:
- M is one or more elements selected from the group consisting of alkali metal, alkaline earth metal and transition metal;
- a is about 0.8-1.2;
- b and/or c is greater than 0 to about 0.005;
- d is 0 to about 0.005;
- and
- x is a number determined by the valence requirements of the other elements present.
9 more elements
A process for producing a product stream comprising:
- contacting the catalyst composition with a syngas mixture to produce a mixture of aliphatic and aromatic hydrocarbons;
- wherein the product stream is produced by Fischer-Tropsch synthesis performed at a reaction temperature of about 150-350° C., a space velocity of about 400-5000 h−1 and a pressure of between atmospheric and about 5 MPa;
- wherein the syngas mixture has a hydrogen (H2) to carbon monoxide (CO) molar ratio of about 1-4;
- and
- wherein the catalyst composition comprises
- cobalt;
- manganese;
- and at least one element selected from the group of lanthanum and phosphorus,
- wherein the relative molar ratios of the elements comprised in the composition are represented by the formula
- CoMnaLabPcMdOx
- wherein:
- M is one or more elements selected from the group consisting of alkali metal, alkaline earth metal and transition metal;
- a is about 0.8-1.2;
- b and/or c is greater than 0 to about 0.005;
- d is 0 to about 0.005;
- and
- x is a number determined by the valence requirements of the other elements present.
14 more elements
Dependencies are inferred from the claim text.