Polymer supported reagents and methods or reducing aromatic nitro compounds by using the same
AssigneesIucf-Hyu (Industry-University Cooperation Foundation Hanyang University), LG Chem, Ltd.
InventorsYang-Kyoo Han, Jin Cho, Sang-Mi Lee, Seung-Hoon Shin
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Abstract
The present invention relates to a polymer supported reagent comprising a novel crosslinked mesoporous polymer, enabling a simple and easy production of an azoxy compound or an azo compound from an aromatic nitro compound, and a method of selectively reducing an aromatic nitro compound by using the same. The polymer supported reagent comprises a certain acrylamide mesoporous crosslinked polymer.
Claims22
A polymer supported reagent comprising an acrylamide mesoporous crosslinked polymer including at least one repeating unit of Chemical Formula 1:
- in Chemical Formula 1, n is an integer of 15 to 1800,
- R is hydrogen or methyl,
- R′ is X,
- X is —Z—R″,
- Y is an alkylene of C1 to C10,
- Z is an arylene of C6 to C20, and
- R″ is a linear or branched hydrocarbon of C10 to C20, or a linear or branched perfluorohydrocarbon of C10 to C20.
Dependencies are inferred from the claim text.