# US 2013/0252147 A1 · Electrophotographic photoreceptor, process cartridge, and image forming apparatus

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- Number: US 2013/0252147 A1
- Document ID: US20130252147A1
- Status: Published application
- Kind: A1
- Application number: 13/561,535
- Filed: 2012-07-30
- Published: 2013-09-26
- Earliest claimed: 2012-03-23
- Assignees: Fuji Xerox Co., Ltd.
- Inventors: Satoya SUGIURA; Shigeto HASHIBA; Kazuhiro KOSEKI; Hirofumi NAKAMURA; Kenta IDE; Akihiro NONAKA; Kosuke NARITA; Akihiro KAWASAKI
- Web page: https://patentgrep.com/patent/US20130252147A1

## CPC

- G03G 5/144: {comprising inorganic material}
- G03G 5/0539: {Halogenated polymers}
- G03G 5/0542: {Polyvinylalcohol, polyallylalcohol; Derivatives thereof, e.g. polyvinylesters, polyvinylethers, polyvinylamines}
- G03G 5/0564: {Polycarbonates}
- G03G 5/061473: {plural alkenyl groups linked directly to the same aryl group}
- G03G 5/0696: {Phthalocyanines}
- G03G 5/142: {Inert intermediate layers}
- G03G 5/14708: {comprising organic material}
- G03G 5/14756: {Polycarbonates}
- G03G 15/75: {Details relating to xerographic drum, band or plate, e.g. replacing, testing (electrographic recording members per se G03G5/00)}
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY

## Abstract

An electrophotographic photoreceptor includes a conductive support, and an undercoat layer, a charge generation layer, and a charge transport layer that are provided in this order on the conductive support, wherein the undercoat layer includes at least metallic oxide particles, a reactive acceptor substance including an anthraquinone structure expressed by the following Formula 1, and a binder resin, the charge generation layer includes hydroxygallium phthalocyanine as a charge generation material, and a reflectance of incident light having a wavelength of 780 nm on a surface of the charge generation layer when the charge transport layer is removed is 17% or greater: wherein the anthraquinone structure expressed by Formula 1 is bonded to another structure at a position of *, and thus forms the reactive acceptor substance, and in Formula 1, n1 represents an integer of 1 to 7.

## Claims

### Claim 1

An electrophotographic photoreceptor comprising:
a conductive support; and
an undercoat layer, a charge generation layer, and a charge transport layer that are provided in this order on the conductive support,
wherein the undercoat layer includes at least metallic oxide particles, a reactive acceptor substance including an anthraquinone structure expressed by the following Formula 1, and a binder resin,
the charge generation layer includes hydroxygallium phthalocyanine as a charge generation material, and
a reflectance of incident light having a wavelength of 780 nm on a surface of the charge generation layer when the charge transport layer is removed is 17% or greater:
wherein the anthraquinone structure expressed by Formula 1 is bonded to another structure at a position of *, and thus forms the reactive acceptor substance, and in Formula 1, n1 represents an integer of from 1 to 7.

### Claim 2 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein the reflectance is 20% or greater.

### Claim 3 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein in the Formula 1, n1 is 1 to 4.

### Claim 4 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein in the Formula 1, another structure bonded at the position of * is an alkoxy group.

### Claim 5 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein in the Formula 1, another structure bonded at the position of * is an alkoxy group having from 1 to 8 carbon atoms.

### Claim 6 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein an amount of the reactive acceptor substance added of the Formula 1 is 0.1% by weight to 10% by weight in the undercoat layer.

### Claim 7 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein an amount of the reactive acceptor substance added of the Formula 1 is 0.5% by weight to 5% by weight in the undercoat layer.

### Claim 8 (depends on 1)

The electrophotographic photoreceptor according to claim 1,
wherein the charge transport layer includes a compound that has a charge transport ability and has a butadiene structure expressed by the following Formula 2, and a polycarbonate copolymer including a repeating unit expressed by the following Formula 3 and a repeating unit expressed by the following Formula 4:
wherein in Formula 2, R1, R2, R3, R4, R5, and R6 each may be the same as, or different from each other, and represent a hydrogen atom, an alkyl group, an alkoxy group, a halogen atom, or a substituted or unsubstituted aryl group, and m1 and n2 represent 0 or 1;
wherein in Formulas 3 and 4, R7, R8, R9, and R10 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cycloalkyl group having 5 to 7 carbon atoms, or an aryl group having 6 to 12 carbon atoms, and X represents a phenylene group, a biphenylene group, a naphthylene group, a linear or branched alkylene group, or a cycloalkylene group.

### Claim 9 (depends on 8)

The electrophotographic photoreceptor according to claim 8,
wherein in the Formula 2, m1 and n2 are 1.

### Claim 10 (depends on 8)

The electrophotographic photoreceptor according to claim 8,
wherein in the Formula 4, X is a cycloalkylene group.

### Claim 11 (depends on 1)

A process cartridge comprising:
the electrophotographic photoreceptor according to claim 1; and
at least one selected from the group consisting of a charging unit that charges a surface of the electrophotographic photoreceptor, a developing unit that develops an electrostatic latent image formed on the electrophotographic photoreceptor with a developer to form a toner image, and a toner removing unit that removes a toner remaining on the surface of the electrophotographic photoreceptor.

### Claim 12 (depends on 1)

An image forming apparatus comprising:
the electrophotographic photoreceptor according to claim 1;
a charging unit that charges a surface of the electrophotographic photoreceptor;
an electrostatic latent image forming unit that exposes the charged surface of the electrophotographic photoreceptor to form an electrostatic latent image;
a developing unit that develops the electrostatic latent image with a developer to form a toner image; and
a transfer unit that transfers the toner image onto a transfer medium.

### Claim 13 (depends on 12)

The image forming apparatus according to claim 12,
wherein the charging unit is a contact-type charging unit.

### Claim 14 (depends on 12)

The image forming apparatus according to claim 12,
wherein the charging potential by the contact-type charging unit is 650 V or greater in terms of absolute value.

### Claim 15 (depends on 12)

The image forming apparatus according to claim 12,
wherein the charging potential by the contact-type charging unit is 700 V or greater in terms of absolute value.
