# US 2013/0240451 A1 · Apparatus and Methods for Removing Contaminants from a Liquid

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 2013/0240451 A1
- Document ID: US20130240451A1
- Status: Published application
- Kind: A1
- Application number: 13/780,640
- Filed: 2013-02-28
- Published: 2013-09-19
- Earliest claimed: 2012-02-29
- Assignees: Woods Hole Oceanographic Institution
- Applicants: Woods Hole Oceanographic Institution
- Inventors: Thomas Gray Curtis, JR.; Scott C. Smith
- Web page: https://patentgrep.com/patent/US20130240451A1

## CPC

- B01D 17/0202: {by ab- or adsorption}
- C02F 1/285: {using synthetic organic sorbents}
- C02F 1/40: Devices for separating or removing fatty or oily substances or similar floating material (cleaning or keeping clear the surface of open water from oil or like materials E02B15/04; devices in sewers for separating liquid or solid substances from sewage E03F5/14, e.g. for use in drains leading to the sewer E03F5/16)
- C02F 1/681: {by addition of solid materials for removing an oily layer on water}
- C08J 9/0061: {characterized by the use of several polymeric components}
- C08J 9/06: by a chemical blowing agent
- C08J 9/36: After-treatment (C08J9/22 takes precedence)
- C08J 9/38: Destruction of cell membranes
- C02F 2101/32: Hydrocarbons, e.g. oil
- C08J 2201/03: Extrusion of the foamable blend
- C08J 2205/05: Open cells, i.e. more than 50% of the pores are open
- C08J 2205/052: Closed cells, i.e. more than 50% of the pores are closed
- C08J 2323/08: Copolymers of ethene (C08J2323/16 takes precedence)
- C08J 2423/06: Polyethene
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)
- C08J: WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H (working, e.g. shaping, of plastics B29)

## Abstract

An apparatus for removing a contaminant from a liquid includes a tension element extending along a length of the liquid and may be near a bottom of the liquid. A plurality of buoyant strips having a polymer defining an open-cell foam are attached to the tension element and extend to a surface of the liquid, with at least a portion of the strips floating on the surface. The polymer may include ethylene alkyl acrylate copolymer (e.g., 100% EMA copolymer).

## Claims

### Claim 1

An apparatus for removing a contaminant from a liquid, the apparatus comprising:
a tension element extending along a length of the liquid, proximate a bottom thereof; and
a plurality of buoyant strips attached to the tension element and extending to a surface of the liquid, at least a portion of the strips floating on the surface,
wherein (i) the strips comprise a polymer defining an open cell foam, (ii) the polymer comprises ethylene alkyl acrylate copolymer, and (iii) the foam comprises at least one of: an average cell size greater than 1.4 mm and a ratio of open cells to closed cells greater than 1:1.

### Claim 2 (depends on 1)

The apparatus of claim 1, wherein the ethylene alkyl acrylate comprises ethylene methyl acrylate.

### Claim 3 (depends on 1)

The apparatus of claim 1, wherein the polymer comprises at least 80% ethylene alkyl acrylate, by weight.

### Claim 4 (depends on 1)

The apparatus of claim 1, wherein the foam comprises a tensile strength greater than 14 psi.

### Claim 5 (depends on 1)

The apparatus of claim 1, wherein the foam comprises a density greater than 1 lb/ft3.

### Claim 6 (depends on 1)

The apparatus of claim 1, wherein the polymer further comprises low density polyethylene.

### Claim 7 (depends on 1)

The apparatus of claim 1, wherein the contaminant comprises a petroleum product.

### Claim 8 (depends on 1)

The apparatus of claim 1, wherein the contaminant comprises a nonpolar species.

### Claim 9

A method of removing a contaminant from a liquid, the method comprising the steps of:
placing a tension element along a length of a bottom of the liquid;
attaching a plurality of buoyant strips to the tension element, such that the strips extend to a surface of the liquid with at least a portion of the strips floating on the surface; and
exposing the strips to the contaminant in the liquid,
wherein (i) the strips comprise a polymer defining an open cell foam, (ii) the polymer comprises ethylene alkyl acrylate copolymer, and (iii) the foam comprises at least one of: an average cell size greater than 1.4 mm and a ratio of open cells to closed cells greater than 1:1.

### Claim 10 (depends on 9)

The method of claim 9, wherein the ethylene alkyl acrylate comprises ethylene methyl acrylate.

### Claim 11 (depends on 9)

The method of claim 9, wherein the polymer comprises at least 80% ethylene alkyl acrylate, by weight.

### Claim 12 (depends on 9)

The method of claim 9, wherein the foam comprises a tensile strength greater than 14 psi.

### Claim 13 (depends on 9)

The method of claim 9, wherein the foam comprises a density greater than 1 lb/ft3.

### Claim 14 (depends on 9)

The method of claim 9, wherein the polymer further comprises low density polyethylene.

### Claim 15 (depends on 9)

The method of claim 9, wherein the contaminant comprises a petroleum product.

### Claim 16 (depends on 9)

The method of claim 9, wherein the contaminant comprises a nonpolar species.

### Claim 17 (depends on 9)

The method of claim 9, further comprising adsorbing the contaminant onto the strips.

### Claim 18 (depends on 17)

The method of claim 17, further comprising:
removing the strips from the liquid; and
extracting the contaminant from the strips by mechanical action.

### Claim 19 (depends on 18)

The method of claim 18, further comprising redeploying the strips into the liquid for further contaminant removal.

### Claim 20

A method of manufacturing a contaminant removal apparatus, the method comprising:
mixing a polymer with a foaming agent to produce an open cell foam sheet, the polymer comprising ethylene alkyl acrylate copolymer;
introducing a plurality of substantially parallel slits in the foam sheet, the slits originating at a base portion of the foam sheet and extending to an opposite edge of the foam sheet to define a plurality of strips attached to the base portion; and
attaching the base portion to a tension element,
wherein the foam comprises at least one of: an average cell size greater than 1.4 mm and a ratio of open cells to closed cells greater than 1:1.

### Claim 21 (depends on 20)

The method of claim 20, wherein the ethylene alkyl acrylate comprises ethylene methyl acrylate.

### Claim 22 (depends on 20)

The method of claim 20, wherein the polymer comprises at least 80% ethylene alkyl acrylate, by weight.

### Claim 23 (depends on 20)

The method of claim 20, wherein the foam comprises a tensile strength greater than 14 psi.

### Claim 24 (depends on 20)

The method of claim 20, wherein the foam comprises a density greater than 1 lb/ft3.

### Claim 25 (depends on 20)

The method of claim 20, wherein the polymer further comprises low density polyethylene.

### Claim 26 (depends on 20)

The method of claim 20, wherein the mixing occurs in an extruder.

### Claim 27 (depends on 20)

The method of claim 20, wherein the contaminant comprises a petroleum product.

### Claim 28 (depends on 20)

The method of claim 20, wherein the contaminant comprises a nonpolar species.

### Claim 29

A composition comprising a polymer defining an open cell foam, the polymer comprising ethylene alkyl acrylate copolymer, and the foam comprising at least one of: an average cell size greater than 1.4 mm and a ratio of open cells to closed cells greater than 1:1.
