# US 2013/0239792 A1 · Method For The Production Of Highly Oriented Polyolefin Ribbons, Textiles And Technical Flexible Sheet Materials Produced Therefrom, And The Use Thereof In Protective Bodies For The Protection From Ballistic Projectiles And The Like

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- Number: US 2013/0239792 A1
- Document ID: US20130239792A1
- Status: Published application
- Kind: A1
- Application number: 13/774,997
- Filed: 2013-02-22
- Published: 2013-09-19
- Earliest claimed: 2007-04-12
- Assignees: Nextrusion GMBH
- Applicants: Nextrusion GmbH
- Inventors: Hans-Joachim Bruning; Andreas Fischer; Jan Adolph Dam Backer; Mark James Bonner; Ian McMillan Ward
- Web page: https://patentgrep.com/patent/US20130239792A1

## CPC

- F41H 5/02: Plate construction
- B29C 55/06: parallel with the direction of feed
- B29C 55/065: {in several stretching steps}
- B32B 5/024: {Woven fabric}
- B32B 5/028: {Net structure, e.g. spaced apart filaments bonded at the crossing points}
- B32B 5/12: characterised by the relative arrangement of fibres or filaments of {different layers, e.g. the fibres or filaments being parallel or perpendicular to each other}
- D01D 5/084: Heating filaments, threads or the like, leaving the spinnerettes
- D01F 6/04: from polyolefins
- F41H 5/0485: {all the layers being only fibre- or fabric-reinforced layers}
- B29K 2023/065: {HDPE, i.e. high density polyethylene}
- Y10T 156/10: Methods of surface bonding and/or assembly therefor
- Y10T 442/10: Scrim [e.g., open net or mesh, gauze, loose or open weave or knit, etc.]
- Y10T 442/3041: Woven fabric comprises strips or ribbons only
- F41H: ARMOUR; ARMOURED TURRETS; ARMOURED OR ARMED VEHICLES; MEANS OF ATTACK OR DEFENCE, e.g. CAMOUFLAGE, IN GENERAL
- B29C: SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING (making preforms B29B11/00; making laminated products by combining previously unconnected layers which become one product whose layers will remain together B32B37/00 - B32B41/00)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- D01D: MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01F: CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- B29K: INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR {MOULDS, } REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

The invention relates to a method for the production of high-strength ribbons having a high modulus of elasticity made of a highly molecular polyolefin, wherein the polyolefins, particularly polypropylene and polyethylene, are extruded through a slotted nozzle, are then subjected to a temperature of 85° to 135° C. for a duration of at least one second, the films are then cut into individual ribbons, if necessary, and stretched at temperatures between 90° and 165° C. in one or more steps, are rolled up or further processed directly into textiles or technical flexible sheet materials. The ribbons can be laminated into multi-layer flexible sheet materials by using adhesives or adhesion promoters, the flexible sheet materials being particularly suitable as protection from ballistic projectiles. In this case particularly in the form of plate-shaped or flexible compound bodies.

## Claims

### Claim 1

Method of producing high-strength ribbons having a high modulus of elasticity from polyolefin of high molecular weight, characterised in that the polyolefin is extruded through a slit die as a melt whose temperature is at least 10° C. above the melting point of the polyolefin, the emerging film, which is still in the melted state, is then exposed to a temperature from 85° to 135° C. for a period of at least one second, the film is then cut into individual ribbons if required and is then stretched in one or more stages at temperatures of between 90° C. and 165° C. until a total stretch of 15:1 to 60:1 is reached, and the ribbons are wound into reels or further processed directly into textile or engineering sheet materials.

### Claim 2 (depends on 1)

Method according to claim 1, characterised in that a thickness from 10 μm to 250 μm is set for the ribbons by setting the height of the slot, the feed rate and the total stretch.

### Claim 3 (depends on 2)

Method according to claim 2, characterised in that a thickness from 30 μm to 80 μm is set for the films.

### Claim 4 (depends on 1)

Method according to claim 1, characterised in that the films are cut to a width from 0.6 to 50 mm before being stretched.

### Claim 5 (depends on 4)

Method according to claim 4, characterised in that the ribbons are cut to a width from 5 to 20 mm.

### Claim 6 (depends on 1)

Method according to claim 1, characterised in that the film is perforated by means of a needle roller after being stretched.

### Claim 7 (depends on 1)

Method according to claim 1, characterised in that the film is exposed to a temperature from 85° to 135° C. by passing it over one or more cooling rollers which are at a temperature from 85° to 135° C.

### Claim 8 (depends on 1)

Method according to claim 1, characterised in that the exposure to a temperature from 85° to 135° C. is performed by passing the film through a liquid or a gas, and preferably an inert gas, at a temperature from 85 to 135° C.

### Claim 9 (depends on 1)

Method according to claim 1, characterised in that the polyolefin used contains 0.01 to 5% by weight of calcium carbonate

### Claim 10 (depends on 1)

Method according to claim 1, characterised in that the polyolefin used contains 0.01 to 5% by weight of a UV-stabiliser

### Claim 11 (depends on 1)

Method according to claim 1, characterised in that the polyolefin used contains 0.01 to 5% by weight of an aramide and preferably a polyaramide powder.

### Claim 12 (depends on 1)

Method according to claim 1, characterised in that what is used as a polyolefin of high molecular weight is a polyethylene of high molecular weight having average molecular weights Mw from 80,000 to 500,000 and Mn from 5,000 to 80,000.

### Claim 13 (depends on 1)

Method according to at least one of claims 1 to characterised in that what is used as a polyolefin of high molecular weight is a polypropylene of high molecular weight having average molecular weights Mw from 100,000 to 130,000 and Mn from 25,000 to 33,000.

### Claim 14 (depends on 1)

Method according to claim 1, characterised in that the film, on leaving the slit die and upstream of the tempering zone, is also fed, for a period of at least one second, directly through a heating zone which is at a temperature from 135° C. to a temperature of the melting point of the polymer being extruded.

### Claim 15 (depends on 1)

Method according to claim 1, characterised in that a bimodal polyolefin is used.

### Claim 16 (depends on 1)

Ribbons produced by a method according to claim 1, characterised in that they are of a strength from 500 MPa to 3000 MPa and have a modulus of elasticity from 20 GPa to 180 GPa, the modulus of elasticity being determined from the secant which intersects the stress-strain curve of the ribbon, measured at an ambient temperature of 23° C. and a relative humidity of 65%, at a strain of between 0.5% and 1%.

### Claim 17 (depends on 1)

Method of producing textile or engineering sheet materials which contain fine ribbons according to claim 1, characterised in that the ribbons are provided on one or more sides with an adhesive and/or an adhesion promoter and are then connected by lamination to form sheet materials having two or more layers.

### Claim 18 (depends on 17)

Method of producing the sheet materials according to claim 17, characterised in that the ribbons are processed into the multilayered sheet materials as laid scrims or woven fabrics.

### Claim 19 (depends on 17)

Sheet material according to claim 17, characterised in that the laid scrims or woven fabrics are laminated to one another in such a way that the individual layers of the sheet materials are constructed in such a way that the directions of stretch of the films or ribbons comprising them are at an angle of at least 10° to the directions of stretch of the ribbons in the woven fabrics or laid scrims situated above them or below them.

### Claim 20 (depends on 19)

Use of the laminates according to claim 19 for producing protective bodies for providing protection against ballistic projectiles, characterised in that the laid scrims or woven fabrics are used in plate-like or flexible composite bodies.