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US 2013/0210864 A1Published application
N-benzyl heterocyclic carboxamides
AssigneeBayer Intellectual Property GmbH
InventorsJurgen Benting, Pierre Cristau, Philippe Desbordes, Stephanie Gary, Jorg Greul, Hendrik Helmke
Life of this patent
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Abstract
The present invention relates to N-benzyl heterocyclic carboxamides derivatives or their thiocarboxamides derivatives, their process of preparation, their use as fungicide, particularly in the form of compositions, and methods for the control of phytopathogenic fungi, notably of plants, using these compounds or compositions.
Claims17
A compound of formula (I)
- wherein
- Y represents CR5 or N;
- T represents O or S;
- X1 and X2 which can be the same or different, represent a chlorine or a fluorine atom;
- Z1 represents a hydrogen atom, substituted or non substituted C1-C8-alkyl;
- substituted or non substituted C1-C8-alkoxy;
- substituted or non substituted C2-C8-alkenyl;
- substituted or non substituted C2-C8-alkynyl;
- substituted or non substituted C4-C7-cycloalkyl;
- substituted or non substituted C3-C7-cycloalkyl-C1-C8-alkyl;
- substituted or non substituted 3-oxetanyl;
- or substituted or non substituted 3-thietanyl;
- Z2 and Z3, which can be the same or different, represent a hydrogen atom;
- substituted or non substituted C1-C8-alkyl;
- substituted or non substituted C2-C8-alkenyl;
- substituted or non substituted C2-C8-alkynyl;
- cyano;
- isonitrile;
- nitro;
- a halogen atom;
- substituted or non substituted C1-C8-alkoxy;
- substituted or non substituted C2-C8-alkenyloxy;
- substituted or non substituted C2-C8-alkynyloxy;
- substituted or non substituted C3-C7-cycloalkyl;
- substituted or non substituted C1-C8-alkylsulfanyl;
- substituted or non substituted C1-C8-alkylsulfonyl;
- substituted or non substituted C1-C8-alkylsulfinyl;
- amino;
- substituted or non substituted C1-C8-alkylamino;
- substituted or non substituted di-C1-C8-alkylamino;
- substituted or non substituted C1-C8-alkoxycarbonyl;
- substituted or non substituted C1-C8-alkylcarbamoyl;
- substituted or non substituted di-C1-C8-alkylcarbamoyl;
- or substituted or non substituted N—C1-C8-alkyl-C1-C8-alkoxy-carbamoyl;
- or
- Z3 and R1 together with the consecutive carbon atoms to which they are linked form a substituted or non substituted 5-, 6- or 7-membered, partly saturated, carbo- or hetero-cycle comprising up to 3 heteroatoms and Z2 is as herein described;
- or
- Z2 and Z3 together with the carbon atom to which they are linked form a substituted or non substituted C3-C7 cycloalkyl;
- R1, R2, R3, R4 and R5, which can be the same or different, represent a hydrogen atom;
- a halogen atom;
- nitro;
- cyano;
- isonitrile;
- hydroxyl;
- sulfanyl;
- amino;
- pentafluoro-λ6-sulfanyl;
- substituted or non substituted C1-C8-alkyl;
- C1-C8-halogenoalkyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkylamino;
- substituted or non substituted di-C1-C8-alkylamino;
- substituted or non substituted C1-C8-alkoxy;
- C1-C8-halogenoalkoxy comprising up to 9 halogen atoms which can be the same or different;
- C1-C8-alkoxy-C1-C8-alkyl;
- substituted or non substituted C1-C8-alkylsulfanyl;
- C1-C8-halogenoalkylsulfanyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C2-C8-alkenyl;
- C2-C8-halogenoalkenyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C2-C8-alkynyl;
- C2-C8-halogenoalkynyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C2-C8-alkenyloxy;
- C2-C8-halogenoalkenyloxy comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C2-C8-alkynyloxy;
- C2-C8-halogenoalkynyloxy comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C3-C7-cycloalkyl;
- C3-C7-halogenocycloalkyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C3-C7-cycloalkyl-C1-C8-alkyl;
- substituted or non substituted C3-C7-cycloalkyl-C2-C8-alkenyl;
- substituted or non substituted C3-C7-cycloalkyl-C2-C8-alkynyl;
- substituted or non substituted C3-C7-cycloalkyl-C3-C7-cycloalkyl;
- substituted or non substituted C1-C8-alkyl-C3-C7-cycloalkyl;
- formyl;
- formyloxy;
- formylamino;
- carboxy;
- carbamoyl;
- N-hydroxycarbamoyl;
- carbamate;
- (hydroxyimino)-C1-C8-alkyl;
- substituted or non substituted C1-C8-alkylcarbonyl;
- C1-C8-halogenoalkylcarbonyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkylcarbamoyl;
- substituted or non substituted di-C1-C8-alkylcarbamoyl;
- N-(substituted or non substituted C1-C8-alkyloxy)carbamoyl;
- substituted or non substituted C1-C8-alkoxycarbamoyl;
- N-(substituted or non substituted C1-C8-alkyl)-(substituted or non substituted C1-C8-alkoxy)-carbamoyl;
- substituted or non substituted C1-C8-alkoxycarbonyl;
- C1-C8-halogenoalkoxycarbonyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkylaminocarbonyl;
- di-substituted or non substituted C1-C8-alkylaminocarbonyl;
- substituted or non substituted C1-C8-alkylcarbonyloxy;
- C1-C8-halogenoalkylcarbonyloxy comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkylcarbonylamino;
- C1-C8halogenoalkylcarbonylamino comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkylaminocarbonyloxy;
- substituted or non substituted di-C1-C8-alkylaminocarbonyloxy;
- substituted or non substituted C1-C8-alkyloxycarbonyloxy;
- substituted or non substituted C1-C8-alkylsulfinyl;
- C1-C8-halogenoalkylsulfinyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkylsulfonyl;
- C1-C8-halogenoalkylsulfonyl comprising up to 9 halogen atoms which can be the same or different;
- substituted or non substituted C1-C8-alkoxyimino;
- (C1-C8-alkoxyimino)-C1-C8-alkyl;
- substituted or non substituted (C1-C8-alkenyloxyimino)-C1-C8-alkyl;
- (C1-C8-alkynyloxyimino)-C1-C8-alkyl;
- a (benzyloxyimino)-C1-C8-alkyl;
- tri(substituted or non substituted C1-C8-alkyl)silyl;
- tri(substituted or non substituted C1-C8-alkyl)silyl-C1-C8-alkyl;
- benzyloxy which can be substituted by up to 5 groups Q;
- benzylsulfanyl which can be substituted by up to 5 groups Q;
- benzylamino which can be substituted by up to 5 groups Q;
- aryl which can be substituted by up to 7 groups Q;
- aryloxy which can be substituted by up to 7 groups Q;
- arylamino which can be substituted by up to 7 groups Q;
- arylsulfanyl which can be substituted by up to 7 groups Q;
- aryl-C1-C8-alkyl which can be substituted by up to 7 groups Q;
- aryl-C2-C8-alkenyl which can be substituted by up to 7 groups Q;
- aryl-C2-C8-alkynyl which can be substituted by up to 7 groups Q;
- pyridinyl which can be substituted by up to 4 groups Q;
- pyridinyloxy which can be substituted by up to 4 groups Q;
- aryl-C3-C7-cycloalkyl which can be substituted by up to 7 groups Q;
- or
- Two vicinal substituents R together with the consecutive carbon atoms to which they are linked form a substituted or non substituted 5- or 6-membered, saturated, carbo- or hetero-cycle comprising up to 3 heteroatoms and the other substituents R are as herein-described;
- or
- R1 and Z3 together with the consecutive carbon atoms to which they are linked form a substituted or non substituted 5-, 6- or 7-membered, partly saturated, carbo- or hetero-cycle comprising up to 3 heteroatoms, and R2 to R5 are as herein-described;
- Q, which can be the same or different, represents a halogen atom;
- cyano;
- nitro;
- C1-C8-alkyl;
- C1-C8-alkoxy;
- C1-C8-alkylsulfanyl;
- C1-C8-halogenoalkyl comprising up to 9 halogen atoms which can be the same or different;
- C1-C8-halogenoalkoxy comprising up to 9 halogen atoms which can be the same or different;
- tri(C1-C8)alkylsilyl or tri(C1-C8)alkylsilyl-C1-C8-alkyl;
- as well as salts, N-oxides, metal complexes, metalloid complexes and optically active or geometric isomers thereof.
132 more elements
Dependencies are inferred from the claim text.