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US 2013/0172638 A1Published application
Process for the hydroconversion of a low quality hydrocarbonaceous feedstock
AssigneeTotal Raffinage Marketing
InventorsDidier Borremans, Jean-Pierre Dath, Kai Hortmann
Life of this patent
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Abstract
The invention concerns a process for upgrading lower quality carbonaceous feedstock using a slurry catalyst composition. The use of particular organometallic compounds as precursors for the dispersed active catalyst allows for reduced coke formation.
Claims14
Process for the hydroconversion of a low quality hydrocarbonaceous feedstock using an active slurry catalytic phase, wherein said active slurry catalytic phase is obtained from a precursor composition comprising at least one organometallic coordination compound of formula C1C2MLn (I), where
- M is a transition metal selected from group IIA, IIIB, IVB, VB, VIIB, VIIB, VIII, IB or IIB of the periodic table of elements,
- —C1 and —C2 are monocyclic or polycyclic aryl hydrocarbon ligands that are pi-bonded to M, —C1 and —C2 being the same or different, each of —C1 or —C2 comprising from 0 to 5 substituents R, each substituent R being the same or different, R being selected from:
- a C3-C8 substituted or unsubstituted, monocyclic or polycyclic ring structure that is partially unsaturated, unsaturated or aromatic, fused or not fused to the ligand —C1 or —C2,
- a C3-C8 substituted or unsubstituted, partially unsaturated or unsaturated, linear or branched, alicyclic hydrocarbyl radical,
- a C1-C8, substituted or unsubstituted, linear or branched, saturated hydrocarbyl radical,
- —C1 and —C2 being independent or connected via at least one substituent R,
- -L is a ligand that is sigma-bonded to M, n is an integer equal to 0 to 3, each -L is, independently, a univalent ligand.
4 more elements
Dependencies are inferred from the claim text.