# US 2013/0157036 A1 · Fireproof glazing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 2013/0157036 A1 - Document ID: US20130157036A1 - Status: Published application - Kind: A1 - Application number: 13/820,013 - Filed: 2011-08-31 - Published: 2013-06-20 - Earliest claimed: 2010-09-03 - Assignees: Agc Glass Europe - Inventors: Guillaume Herremans; Thomas Lescot - Web page: https://patentgrep.com/patent/US20130157036A1 ## CPC - C03C 17/23: Oxides (C03C17/02 takes precedence) - B32B 17/069: {of intumescent material (B32B17/10311 takes precedence)} - C09K 21/02: Inorganic materials - E06B 5/165: {Fireproof windows (layered glass panes with expansion layers for fire protection B32B17/10311)} - C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS - B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM - C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE - E06B: FIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES (shades or blinds for greenhouses A01G9/22; curtains A47H; lids for car boots or bonnets B62D25/10; skylights E04B7/18; sunshades, awnings E04F10/00) ## Abstract The invention relates to fireproof glazing comprising at least one intumescent layer of hydrated alkaline silicate having a thickness of no less than 2.5 mm and containing water and optionally compounds partially substituting the water, namely either glycerin or ethylene glycol, said compounds and water combined representing between 25 and 45 wt.-% of the layer, with a molar ratio SiO2/M2O of between 2.5 and 6. The viscosity of the intumescent layer prevents the layer from creeping over time. ## Claims ### Claim 1 Fire-resistant glazing comprising at least one intumescent layer of hydrated alkali silicate, the thickness of which is not less than 2.5 mm, which contains water and possibly hydroxylated compounds that are partly substituted for this, said compounds being either glycerine or ethylene glycol, wherein those with water are present to an amount of 25% to 45% by weight of the layer, and with an SiO2/M2O molar ratio of 2.5 to 6, and the intumescent layer has a viscosity that is not less than 0.8. 109 Pa.s and is preferably not lower than 1.109 Pa.s measured in accordance with standard ASTM C1351M-96. ### Claim 2 Fire-resistant glazing comprising at least one intumescent layer of hydrated alkali silicate, the thickness of which is not less than 2 mm, which contains water and possibly hydroxylated compounds (H) that are partly substituted for this, said compounds being either glycerine or ethylene glycol, wherein the alkali silicate is a mixed silicate constituent of sodium and potassium complying with one of the following combinations of conditions between the Na2O/M2O molar ratio, the content by weight of water and hydroxylated compounds (W+H) and the RM SiO2/M2O molar ratio (M being the sum of Na and K): Na2O/M2O of 67% to 100% and W+H of 40% to 45% RM>3.5 or W+H of 35% to 40% RM>2.75 or W+H of 25% to 35% RM>2.25 Na2O/M2O of 34% to 66% and W+H of 40% to 45% RM>4.25 or W+H of 35% to 40% RM>4.0 or W+H of 30% to 35% RM>3.75 or W+H of 25% to 30% RM>3.5 Na2O/M2O of 0% to 33% and W+H of 40% to 45% RM>4.75 or W+H of 35% to 40% RM>4.5 or W+H of 30% to 35% RM>4.25 or W+H of 25% to 30% RM>4.0. ### Claim 3 (depends on 2) Glazing according to claim 2, in which the intumescent layer has a thickness at least equal to 2.5 mm. ### Claim 4 Glazing according to one of the preceding claims, in which the content of glycerine or ethylene glycol of the intumescent layer is in the range of between 2% and 15% by weight. ### Claim 5 Glazing according to one of the preceding claims, in which at least 20% of the silica present in the intumescent layer comes from colloidal silica used during the preparation of the composition that leads to the intumescent layer. ### Claim 6 Glazing according to one of the preceding claims, in which the intumescent layer is formed from sodium and/or potassium silicate and in addition thereto lithium is present to 10 atom. % at most of all the alkali metals. ### Claim 7 Glazing according to one of the preceding claims, in which the SiO2/M2O molar ratio amounts to 3 to 6. ### Claim 8 Glazing according to one of the preceding claims, in which the intumescent layer also contains additives in proportions by weight that do not exceed 6% of the entire intumescent layer. ### Claim 9 (depends on 8) Glazing according to claim 8, in which included among the additives present in the layer in particular are one or more compounds of the group comprising aminated compounds and organic compounds of silicon. ### Claim 10 (depends on 9) Glazing according to claim 9, in which TMAH is included among the additives with a content that does not exceed 2% by weight of the intumescent layer. ### Claim 11 (depends on 9) Glazing according to claim 9, in which TEOS and/or MTEOS are included among the organic compounds of silicon. ### Claim 12 Process for the production of fire-resistant glazing according to one of the preceding claims, in which to produce the intumescent layer, a starting solution is prepared, in which the initial content of water and glycerine and ethylene glycol is at least equal to 50% by weight of this solution, wherein the solution used to form the intumescent layer is brought to the final values by drying after it has been applied to a support or by dehydration preferably in vacuum conducted on the solution itself. ### Claim 13 (depends on 16) Process according to claim 16?, in which the starting solution is formed at least partially from industrial alkali silicate, wherein the complement results from the reaction of a suspension of colloidal silica and alkali hydroxide.