# US 2013/0156680 A1 · Expandable Graphite Particles and Methods of Making Same

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- Number: US 2013/0156680 A1
- Document ID: US20130156680A1
- Status: Published application
- Kind: A1
- Application number: 13/769,450
- Filed: 2013-02-18
- Published: 2013-06-20
- Earliest claimed: 2011-06-29
- Assignees: W. L. Gore & Associates, Inc.
- Inventors: Mukesh Jain; Dattatreya Panse
- Web page: https://patentgrep.com/patent/US20130156680A1

## CPC

- C01B 32/225: Expansion; Exfoliation
- C01B 32/22: Intercalation
- Y10T 428/2982: Particulate matter [e.g., sphere, flake, etc.]
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Small particle size expandable graphite materials are described which are highly expandable, as well as methods of making such unique graphite materials. In one embodiment, expandable graphite particles are described having a particle size nominally between about 100 and 200 US mesh, a chromium content of less than 5 parts per million (ppm) and an expansion of about 80 cc/g or greater when heated at about 500° C.

## Claims

### Claim 1

A method of making expandable graphite particles, said expandable graphite particles having a bulk density of at least about 0.45 cc/g, a particle size between about 100 and 200 US mesh, a chromium content of less than 100 ppm; and an expansion of about 80 cc/g or greater when heated at about 500° C., said method comprising the sequential steps of:
sieving natural flake graphite to a nominal size between about 100 and 200 US mesh;
intercalating the natural flake graphite with acid in the presence of an oxidizing agent;
washing excess acid with water; and neutralizing the intercalated graphite with dilute sodium hydroxide solution.

### Claim 2

A method of making expandable graphite particles, said expandable graphite particles having a particle size between about 100 and 200 US mesh, a chromium content of less than 100 ppm; and an expansion of about 80 cc/g or greater when heated at about 500° C., said method comprising the sequential steps of:
sieving natural flake graphite bulk density of at least about 0.48 cc/g, to a nominal size between about 100 and 200 US mesh;
intercalating the natural flake graphite with acid in the presence of an oxidizing agent;
washing excess acid with water; and
neutralizing the intercalated graphite with dilute sodium hydroxide solution.

### Claim 3 (depends on 1)

The method of claim 1, wherein said natural flake graphite particles have a bulk density of greater than 0.45 cc/g.

### Claim 4 (depends on 2)

The method of claim 2, wherein said expandable graphite particles, have a bulk density of about 0.45 g/cc or greater.

### Claim 5 (depends on 1)

The method of claim 1, wherein the acid comprises sulfuric acid and the oxidizing agent comprises potassium permanganate.

### Claim 6 (depends on 1)

The method of claim 1, wherein said expandable graphite particles have an expansion of about 100 cc/g or greater when heated at about 500° C.

### Claim 7 (depends on 1)

The method of claim 1, wherein said expandable graphite particles have an expansion of about 120 cc/g or greater when heated at about 500° C.

### Claim 8 (depends on 2)

The method of claim 2, wherein the acid comprises sulfuric acid and the oxidizing agent comprises potassium permanganate.

### Claim 9 (depends on 2)

The method of claim 2, wherein said expandable graphite particles have an expansion of about 100 cc/g or greater when heated at about 500° C.

### Claim 10 (depends on 2)

The method of claim 2, wherein said expandable graphite particles have an expansion of about 120 cc/g or greater when heated at about 500° C.