# US 2013/0155484 A1 · Plasmonic modulator incorporating a solid-state phase change material

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- Number: US 2013/0155484 A1
- Document ID: US20130155484A1
- Status: Published application
- Kind: A1
- Application number: 13/327,298
- Filed: 2011-12-15
- Published: 2013-06-20
- Earliest claimed: 2011-12-15
- Assignees: Northrop Grumman Systems Corporation
- Inventors: LUKE SWEATLOCK; Kenneth Diest; James Ma; Vladan Jankovic; Imogen Pryce; Ryan Briggs; Harry Atwater
- Web page: https://patentgrep.com/patent/US20130155484A1

## CPC

- G02F 1/23: for the control of the colour (G02F1/03 - G02F1/21 take precedence)
- B82Y 20/00: Nanooptics, e.g. quantum optics or photonic crystals
- G02F 1/0147: {based on thermo-optic effects (G02F1/132 takes precedence)}
- G02F 1/065: in an optical waveguide structure
- G02F 2203/10: plasmon
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES

## Abstract

Systems and methods are provided for modulating light of a wavelength of interest. The modulator assembly includes a plasmonic layer that supports surface plasmon polaritons at the wavelength of interest and a layer of solid-state phase change material having a first phase in which it is substantially transparent to light of the wavelength of interest and a second phase in which it is substantially opaque to light of the wavelength of interest. A control mechanism is configured to alter the phase of the solid-state phase change material between the first phase and the second phase. Each of the plasmonic layer and the layer of solid-state phase change material are configured as to provide a plasmonic mode of transmission for light of the wavelength of interest.

## Claims

### Claim 1

A nanoscale plasmonic modulator assembly for modulating light of a wavelength of interest comprising:
a plasmonic layer that supports surface plasmon polaritons at the wavelength of interest;
a layer of solid-state phase change material having a first phase in which it is substantially transparent to light of the wavelength of interest and a second phase in which it is substantially opaque to light of the wavelength of interest; and
a control mechanism configured to alter the phase of the solid-state phase change material between the first phase and the second phase;
wherein each of the plasmonic layer and the layer of solid-state phase change material are configured as to provide a plasmonic mode of transmission for light of the wavelength of interest.

### Claim 2 (depends on 1)

The nanoscale plasmonic modulator assembly of claim 1, further comprising a dielectric layer that is substantially transparent to light of the wavelength of interest.

### Claim 3 (depends on 2)

The nanoscale plasmonic modulator assembly of claim 2, wherein the dielectric layer is a first dielectric layer and the assembly further comprises a second dielectric layer, the layer of solid-state phase change material being positioned between the first dielectric layer and the second dielectric layer.

### Claim 4 (depends on 3)

The nanoscale plasmonic modulator assembly of claim 3, wherein the plasmonic layer is a first plasmonic layer and the assembly further comprises a second plasmonic layer, the first dielectric layer being positioned between the first plasmonic layer and the layer of solid-state phase change material, and the second dielectric layer being positioned between the layer of solid-state phase change material and the second plasmonic layer.

### Claim 5 (depends on 2)

The nanoscale plasmonic modulator assembly of claim 2, wherein the layer of solid-state phase change material is positioned between the plasmonic layer and the dielectric layer.

### Claim 6 (depends on 5)

The nanoscale plasmonic modulator assembly of claim 5, wherein the plasmonic layer is a first plasmonic layer, and the assembly further comprises a second plasmonic layer, each of the layer of solid-state phase change material and the dielectric layer being positioned between the first plasmonic layer and the second plasmonic layer.

### Claim 7 (depends on 1)

The nanoscale plasmonic modulator assembly of claim 1, wherein the layer of solid-state phase change material is a first layer of solid-state phase change material, and the assembly further comprises a second layer of solid-state phase change material, the plasmonic layer being positioned between the first layer of solid-state phase change material and the second layer of solid-state phase change material.

### Claim 8 (depends on 1)

The nanoscale plasmonic modulator assembly of claim 1, wherein the layer of solid-state phase change material comprises a layer of vanadium oxide.

### Claim 9 (depends on 1)

The nanoscale plasmonic modulator assembly of claim 1, wherein the layer of solid-state phase change material comprises a chalcogenide phase change film.

### Claim 10 (depends on 8)

The nanoscale plasmonic modulator assembly of claim 8, wherein the control mechanism comprises circuitry configured to apply an electrical field to the vanadium oxide.

### Claim 11 (depends on 1)

The nanoscale plasmonic modulator assembly of claim 1, wherein the control mechanism comprises an ultrafast optical pumping arrangement.

### Claim 12 (depends on 1)

The nanoscale plasmonic modulator assembly of claim 1, wherein the control mechanism comprises thermal switching, via elements which heat or cool the layer of solid-state phase change material.

### Claim 13

A method for fabricating a nanoscale plasmonic modulator comprising:
depositing a solid-state phase change material on a first substrate;
depositing a first plasmonic layer on the solid-state phase change material, such that the solid-state phase change material is substantially covered by the first plasmonic layer;
depositing a second plasmonic layer on a second substrate;
bonding the first substrate to the second substrate, such that the first plasmonic layer is joined to the second plasmonic layer; and
etching substantially all of the first substrate to expose the solid-state phase change material.

### Claim 14 (depends on 13)

The method of claim 13, wherein depositing a solid-state phase change material on a first substrate comprises depositing the solid-state phase change material via pulsed laser deposition.

### Claim 15 (depends on 13)

The method of claim 13, further comprising depositing a third plasmonic layer on the solid-state phase change material, such that the solid-state phase change material is substantially covered by the third plasmonic layer.

### Claim 16 (depends on 13)

The method of claim 13, depositing a second layer of solid-state phase change material on the second substrate prior to depositing the second plasmonic layer, such that the second plasmonic layer substantially covers the second layer of solid-state phase change material.

### Claim 17 (depends on 13)

The method of claim 13, further comprising:
depositing an dielectric layer on the solid-state phase change material, such that the solid-state phase change material is substantially covered by the dielectric layer; and
depositing a third plasmonic layer on the dielectric layer.

### Claim 18 (depends on 13)

The method of claim 13, further comprising weakening the first substrate via ion implantation prior to bonding the first substrate to the second substrate.

### Claim 19

A nanoscale plasmonic modulator assembly for modulating light of a wavelength of interest comprising:
a plasmonic layer that is substantially opaque to light of the wavelength of interest;
a dielectric layer that is substantially transparent to light of the wavelength of interest
a layer of vanadium oxide; and
a control mechanism configured to alter the phase of the vanadium oxide between a metallic phase and an insulator phase;
wherein each of the plasmonic layer, the dielectric layer, and the layer of vanadium oxide are configured as to provide a plasmonic mode of transmission for light of the wavelength of interest.

### Claim 20 (depends on 19)

The nanoscale plasmonic modulator assembly of claim 19, wherein the dielectric layer is formed from sapphire and the plasmonic layer is formed from silver.

### Claim 21 (depends on 19)

The nanoscale plasmonic modulator assembly of claim 19, wherein the dielectric layer is formed from sapphire and the plasmonic layer is formed from gold.

### Claim 22 (depends on 19)

The nanoscale plasmonic modulator assembly of claim 19, wherein the dielectric layer is formed from silicon dioxide and the plasmonic layer is formed from silver.

### Claim 23 (depends on 19)

The nanoscale plasmonic modulator assembly of claim 19, wherein the dielectric layer is formed from silicon dioxide and the plasmonic layer is formed from gold.
