# US 2013/0153777 A1 · Absorption probe for measuring dissolved organic carbon in an aqueous sample

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- Number: US 2013/0153777 A1
- Document ID: US20130153777A1
- Status: Published application
- Kind: A1
- Application number: 13/806,701
- Filed: 2011-06-23
- Published: 2013-06-20
- Earliest claimed: 2010-06-23
- Assignees: Commonwealth Scientific and Industrial Research Organisation
- Inventors: Brett Alexander Sexton; Michael John Best
- Web page: https://patentgrep.com/patent/US20130153777A1

## CPC

- G01N 21/59: Transmissivity (G01N21/25 takes precedence)
- G01N 21/8507: {Probe photometers, i.e. with optical measuring part dipped into fluid sample}
- G01N 33/1886: {using probes, e.g. submersible probes, buoys}
- C02F 2209/21: Dissolved organic carbon [DOC]
- G01N 21/33: using ultraviolet light (G01N21/39 takes precedence)
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)

## Abstract

Some embodiments relate to an absorption probe for measuring an amount of dissolved organic carbon in an aqueous sample, the absorption probe comprising: a housing defining an analysis zone for the containment or passage of an aqueous sample; a light reflector disposed within said housing; an ultraviolet light emitting device disposed within said housing and operable to radiate ultraviolet light along an optical path that passes through the aqueous sample to impinge on said reflector; and a light detector disposed within said housing and operable to detect radiated light reflected from said reflector and to output a received signal from said detected reflected light, said received signal indicative of a measure of an amount of dissolved organic carbon in the aqueous sample.

## Claims

### Claim 1

An absorption probe for measuring an amount of dissolved organic carbon in an aqueous sample, the absorption probe comprising:
a housing defining an analysis zone for the containment or passage of an aqueous sample;
a light reflector disposed within said housing;
an ultraviolet light emitting device disposed within said housing and operable to radiate ultraviolet light along an optical path that passes through the aqueous sample to impinge on said reflector; and
a light detector disposed within said housing and operable to detect radiated light reflected from said reflector and to output a received signal from said detected reflected light, said received signal indicative of a measure of an amount of dissolved organic carbon in the aqueous sample.

### Claim 2 (depends on 1)

An absorption probe according to claim 1, wherein the light reflector is one of a back surface reflector or a front surface reflector.

### Claim 3 (depends on 2)

An absorption probe according to claim 2, wherein the light reflector is a back surface reflector comprising aluminium, silver, a metal with a high UV reflectance, or a dielectric reflector layer deposited on a ultraviolet transmitting quartz disc or a UV transmitting glass.

### Claim 4 (depends on 2)

An absorption probe according to claim 2, wherein the light reflector is a front surface reflector comprising aluminium, silver, a metal with a high UV reflectance or a dielectric reflector layer deposited on a layer of plate glass, common glass or non-ultraviolet transmitting flat substrate.

### Claim 5 (depends on 1)

An absorption probe according to claim 1, wherein the light reflector is a mirror.

### Claim 6 (depends on 3)

An absorption probe according to claim 3, wherein a protective overcoat of silicon dioxide or magnesium fluoride is applied to the deposited aluminium or silver.

### Claim 7 (depends on 1)

An absorption probe according to claim 1, wherein the housing comprises a first member within which is housed the ultraviolet light emitting device and the light detector and a second member within which is housed the light reflector.

### Claim 8 (depends on 7)

An absorption probe according to claim 7, wherein the light reflector and light detector are disposed proximate a first end of the first member, and the first end of the first member is capped with an ultraviolet radiation transparent element.

### Claim 9 (depends on 7)

An absorption probe according to claim 7 further comprising a collimator to collimate the ultraviolet light radiated from the light emitting diode.

### Claim 10 (depends on 7)

An absorption probe according to claim 7, wherein the first member is detachably connectable to the second member.

### Claim 11 (depends on 10)

An absorption probe according to claim 10, wherein an end of the second member slidably or rotationally engages with a surface of said first member to connect the respective members together.

### Claim 12 (depends on 11)

An absorption probe according to claim 11, wherein the first member is provided with a limit means to limit the extent of engagement with the second member.

### Claim 13 (depends on 7)

An absorption probe according to claim 7, wherein the second member has a passageway through it to enable transport of the aqueous sample through the analysis zone.

### Claim 14 (depends on 13)

An absorption probe according to claim 13, wherein a well of the second member has two or more apertures configured to permit circulation of the aqueous sample when at least a portion of the absorption probe is immersed in a body of water.

### Claim 15 (depends on 14)

An absorption probe according to claim 14, wherein a wall of the first or second member surrounding the cavity has engagement means to engage the output of a faucet.

### Claim 16 (depends on 1)

An absorption probe according to claim 1 further comprising a signal processing unit operable to process said received signal to calculate a measure of an amount of dissolved organic carbon in the aqueous sample according to Beer's-Lamberts Law.

### Claim 17 (depends on 16)

An absorption probe according to claim 16, where the signal processing unit is a physically separate unit from the housing and the signal processing unit is in signal communication with the light detector.

### Claim 18 (depends on 17)

An absorption probe according to claim 17, wherein the signal processing unit stores a measure of the transmission Io of ultraviolet light in substantially pure distilled or de-ionised water containing no dissolved organic carbon.

### Claim 19 (depends on 4)

An absorption probe according to claim 4, wherein a protective overcoat of silicon dioxide or magnesium fluoride is applied to the deposited aluminium or silver.

### Claim 20 (depends on 8)

An absorption probe according to claim 8 further comprising a collimator to collimate the ultraviolet light radiated from the light emitting diode.
