# US 2013/0153094 A1 · Method for hot forming a coated metal part and formed part

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- Number: US 2013/0153094 A1
- Document ID: US20130153094A1
- Status: Published application
- Kind: A1
- Application number: 13/818,041
- Filed: 2011-07-19
- Published: 2013-06-20
- Earliest claimed: 2010-08-31
- Assignees: Tata Steel Ijmuiden B.V.
- Inventors: Willem Cornelis Verloop; Marc Jacco van Genderen; Ronald Theodoor van Tol; Guido Cornelis Hensen; Jenny Loiseaux
- Web page: https://patentgrep.com/patent/US20130153094A1

## CPC

- C21D 8/0247: characterised by the heat treatment
- B32B 15/013: {one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium}
- C21D 1/673: for die quenching
- C21D 8/02: during manufacturing of plates or strips (C21D8/12 takes precedence)
- C21D 8/0447: {characterised by the heat treatment}
- C21D 9/46: for sheet metals
- C21D 9/48: deep-drawing sheets
- C22C 18/00: Alloys based on zinc
- C22C 18/04: with aluminium as the next major constituent
- C22C 38/002: {containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60}
- C22C 38/02: containing silicon
- C22C 38/04: containing manganese
- C23C 10/28: using solids, e.g. powders, pastes
- C23C 10/60: After-treatment
- C21D: MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass C23F17/00; unidirectional solidification of eutectic materials or unidirectional demixing of eutectoid materials C30B)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- C22C: ALLOYS (treatment of alloys C21D, C22F)
- C23C: COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL (making metal-coated products by extrusion B21C23/22; covering with metal by connecting pre-existing layers to articles, see the relevant places, e.g. B21D39/00, B23K; metallising of glass C03C; metallising mortars, concrete, artificial stone, ceramics or natural stone C04B41/00; enamelling of, or applying a vitreous layer to, metals C23D; treating metal surfaces or coating of metals by electrolysis or electrophoresis C25D; single-crystal film growth C30B; by metallising textiles D06M11/83; decorating textiles by locally metallising D06Q1/04)

## Abstract

A method for manufacturing a coated part having very high mechanical properties using hot forming techniques. The method includes:—providing an annealed steel strip or blank or pre-shaped part that was coated with a metal or metal alloy before the annealing—if a strip is provided, cutting a blank from the strip before or after the annealing—optionally forming a pre-shaped part from the blank—heating the blank or preshaped part to a temperature of 500° C. at an average heating rate of 16° C./s or more—further heating the blank or pre-shaped part to a temperature between 700 and 1000° C.—hot forming the blank or preshaped part into a hot formed part—hardening the hot formed part. A method for manufacturing a coated steel strip, blank or pre-shaped part, and a coated steel strip, blank or part and a hot formed part.

## Claims

### Claim 1

Method for manufacturing a coated part having very high mechanical properties using hot forming techniques, comprising the following steps:
1. providing an annealed steel strip or blank or pre-shaped part that has been coated with zinc or a zinc alloy before the annealing
2. if a strip is provided, cutting a blank from the strip before or after the annealing
3. optionally forming a pre-shaped part from the blank
4. heating the blank or pre-shaped part to a temperature of 500° C. at an average heating rate of 16° C./s or more
5. further heating the blank or pre-shaped part to a temperature between 700 and 1000° C.
6. hot forming the blank or pre-shaped part into a hot formed part
7. hardening the hot formed part,
wherein before the blank or pre-shaped part is taken out of an oven and put in a hot-forming apparatus, the heating of the blank or pre-shaped part is performed within 3 minutes.

### Claim 2 (depends on 1)

Method for manufacturing a coated part according to claim 1, wherein the blank or pre-shaped part in step 4 is heated to a temperature of 625° C. at an average heating rate of 16° C./s or more.

### Claim 3 (depends on 1)

Method for manufacturing a coated part according to claim 1, wherein the blank or pre-shaped part in step 4 is heated to a temperature of 700° C. at an average heating rate of 16° C./s or more.

### Claim 4 (depends on 1)

Method for manufacturing a coated part according to claim 1, wherein the blank or pre-shaped part in step 4 is heated to a temperature between 700 and 900° C. at an average heating rate of 16° C./s or more.

### Claim 5 (depends on 1)

Method according to claim 1, wherein the coating on the blank or pre-shaped part remains solid during step 4 and step 5.

### Claim 6 (depends on 1)

Method according to claim 1, wherein in step 4 the blank or pre-shaped part is heated at an average heating rate of at most 50° C./s.

### Claim 7 (depends on 1)

Method according to claim 1, wherein the steel has the following composition in weight percent:
0.1<C<0.5
0.5<Mn<3.0
0.1<Si<0.5
Cr<1.0
Ti<0.2
Al<0.1
P<0.1
S<0.05
0.0005<B<0.08
optionally:
Nb<0.1
V<0.1
unavoidable impurities
the remainder being iron.

### Claim 8 (depends on 1)

Method according to claim 1, wherein the metal alloy is a zinc alloy having the following composition in weight percent:
1.0<Al<5.0,
1.0<Mg<5.0,
at most 0.2 in total of one or more standard alloying elements Pb, Sb, Ti, Ca, Mn, La, Ce, Cr, Ni, Zr, and Bi
remainder zinc and inevitable impurities.

### Claim 9 (depends on 1)

Method according to claim 1 wherein step 1 is preceded by a method for manufacturing the annealed steel strip or blank or pre-shaped part that has been coated with a metal or metal alloy before the annealing, comprising the following steps:
A—providing a steel strip or blank or pre-shaped part
B—coating the steel with a layer of zinc or zinc alloy
C—heating the coated steel to a temperature between 700° C. and 1000° C. and keeping the strip or blank or pre-shaped part at that temperature during a time period of at most 30 minutes
D—cooling the coated steel.

### Claim 10 (depends on 9)

Method according to claim 9, wherein if a strip is provided the steel strip is cut to form a blank from the strip and a pre-shaped part is formed from the blank after step A, B, C or D.

### Claim 11 (depends on 9)

Coated steel strip, blank, part or pre-shaped part provided with a coating of zinc or zinc alloy as produced according to the method of claim 9, wherein the outer layer of the coating on average contains more than 5 weight % Fe over a depth of 3 μm.

### Claim 12 (depends on 11)

Coated steel strip, blank, part or pre-shaped part according to claim 11, wherein the outer layer of the coating on average contains more than 10 weight % Fe over a depth of 3 μm.

### Claim 13 (depends on 1)

Part provided by performing the method according to claim 1.

### Claim 14 (depends on 1)

Method according to claim 1, wherein the metal alloy is a zinc alloy having the following composition in weight percent:
1.5<Al<2.0
1.5<Mg<2.0
at most 0.2 in total of one or more standard alloying elements Pb, Sb, Ti, Ca, Mn, La, Ce, Cr, Ni, Zr, and Bi
remainder zinc and inevitable impurities.

### Claim 15 (depends on 10)

Coated steel strip, blank, part or pre-shaped part provided with a coating of zinc or zinc alloy as produced according to the method of claim 10, wherein the outer layer of the coating on average contains more than 5 weight % Fe over a depth of 3 μm.

### Claim 16 (depends on 11)

Coated steel strip, blank, part or pre-shaped part according to claim 11, wherein the outer layer of the coating on average contains more than 20 weight % Fe over a depth of 3 μm.

### Claim 17 (depends on 11)

Coated steel strip, blank, part or pre-shaped part according to claim 11, wherein the outer layer of the coating on average contains more than 30 weight % Fe over a depth of 3 μm.

### Claim 18 (depends on 11)

Coated steel strip, blank, part or pre-shaped part according to claim 11, wherein the outer layer of the coating on average contains more than 40 weight % Fe over a depth of 3 μm.
