# US 2013/0152995 A1 · Solar cell module and method for producing the same

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 2013/0152995 A1
- Document ID: US20130152995A1
- Status: Published application
- Kind: A1
- Application number: 13/713,105
- Filed: 2012-12-13
- Published: 2013-06-20
- Earliest claimed: 2011-12-14
- Assignees: Panasonic Corporarion
- Inventors: MICHIRU KUROMIYA; TOMOHIRO OKUMURA
- Web page: https://patentgrep.com/patent/US20130152995A1

## CPC

- H10F 77/315: {the coatings being antireflective or having enhancing optical properties}
- C03C 17/34: with at least two coatings having different compositions (C03C17/44 takes precedence)
- H10F 19/80: Encapsulations or containers for integrated devices, or assemblies of multiple devices, having photovoltaic cells
- C03C 2217/445: Organic continuous phases
- C03C 2217/478: Silica
- C03C 2217/734: comprising an alternation of high and low refractive indexes
- Y02E 10/50: Photovoltaic [PV] energy
- H10F: INORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
- C03C: CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A solar cell module which not only can ensure that rays of light in a satisfactory amount enter the solar cells but also can suppress the deterioration of the antireflection film in reflectance to surely achieve excellent durability. By forming, on the surface of a first antireflection film, a second antireflection film having a void ratio smaller than that of the first antireflection film, CO2 and H2O in air are prevented from permeating through the antireflection film, so that a reaction of CO2 and H2O with alkali ions on the surface of a light-transmitting member is unlikely to proceed, making it possible to cause rays of light in a satisfactory amount to surely enter the solar cells and to suppress the deterioration of the antireflection film in reflectance to surely achieve excellent durability.

## Claims

### Claim 1

A solar cell module comprising:
a plurality of solar cells, and
a connector operable to electrically connect adjacent solar cells in the plurality of solar cells to each other,
the solar cell module having:
a light-transmitting member disposed to cover a light receiving surface of the solar cell module, and containing an alkali element,
a first antireflection film formed on the light-transmitting member, and comprising silica, a siloxane, and voids of the silica, and
a second antireflection film formed on the surface of the first antireflection film, and comprising the silica and the siloxane,
wherein the silica has a particle diameter of 5 nm to 50 nm.

### Claim 2 (depends on 1)

The solar cell module according to claim 1, wherein a content ratio of the silica to the siloxane (silica:siloxane ratio) is 80:20 to 95:5.

### Claim 3 (depends on 1)

The solar cell module according to claim 1, wherein a thickness of the second antireflection film is 10% or less of a total thickness of the first antireflection film and the second antireflection film.

### Claim 4 (depends on 1)

The solar cell module according to claim 1, wherein a void ratio at an interface between the first antireflection film and the light-transmitting member is larger than a void ratio at an interface between the first antireflection film and the second antireflection film.

### Claim 5 (depends on 1)

The solar cell module according to claim 1, wherein the second antireflection film includes the voids, wherein a void ratio of the second antireflection film is smaller than a void ratio at an interface between the first antireflection film and the second antireflection film.

### Claim 6 (depends on 1)

The solar cell module according to claim 1, wherein when an average refractive index of the first antireflection film and the second antireflection film is taken as n, a total thickness of the first antireflection film and the second antireflection film is taken as d, and an average wavelength of rays of light incident on the solar cells is taken as λ, a relationship: 2nd=λ/2 is satisfied.

### Claim 7 (depends on 1)

The solar cell module according to claim 1, wherein a total thickness of the first antireflection film and the second antireflection film is 100 nm to 200 nm.

### Claim 8 (depends on 1)

The solar cell module according to claim 1, wherein the second antireflection film has a surface roughness of 2.5 nm or less.

### Claim 9 (depends on 1)

The solar cell module according to claim 1, wherein each of the first antireflection film and the second antireflection film has a siloxane bond.

### Claim 10

A method for producing a solar cell module comprising:
forming a light-transmitting member containing an alkali element on light receiving surfaces of a plurality of solar cells;
subjecting a mixture of polysiloxane, silica particles, and an organic solvent to drying and firing to form an antireflection film precursor on the light-transmitting member;
subjecting the antireflection film precursor to thermal drying to form a first antireflection film comprising silica, a siloxane, and voids of the silica; and
subjecting a surface of the first antireflection film to rapid heat treatment so that the silica particles are fused to form a second antireflection film containing the silica and the siloxane,
wherein the silica has a particle diameter of 5 nm to 50 nm.

### Claim 11 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein the rapid heat treatment is conducted by a plasma torch method or a heat treatment using a laser or a flashlamp.

### Claim 12 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein a content ratio of the silica to the siloxane (silica:siloxane ratio) is 80:20 to 95:5.

### Claim 13 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein a thickness of the second antireflection film is 10% or less of a total thickness of the first antireflection film and the second antireflection film.

### Claim 14 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein a void ratio at an interface between the first antireflection film and the light-transmitting member is larger than a void ratio at an interface between the first antireflection film and the second antireflection film.

### Claim 15 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein the voids are formed in the second antireflection film, wherein a void ratio of the second antireflection film is smaller than a void ratio at an interface between the first antireflection film and the second antireflection film.

### Claim 16 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein when an average refractive index of the first antireflection film and the second antireflection film is taken as n, a total thickness of the first antireflection film and the second antireflection film is taken as d, and an average wavelength of rays of light incident on the solar cells is taken as λ, a relationship: 2nd=λ/2 is satisfied.

### Claim 17 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein a total thickness of the first antireflection film and the second antireflection film is 100 nm to 200 nm.

### Claim 18 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein the second antireflection film has a surface roughness of 2.5 nm or less.

### Claim 19 (depends on 10)

The method for producing a solar cell module according to claim 10, wherein each of the first antireflection film and the second antireflection film has a siloxane bond.

### Claim 20

A solar cell module comprising:
a solar cell;
a light receiving surface disposed to receive incident light rays;
a light-transmitting member disposed to cover the light receiving surface and containing an alkali element;
a first antireflection film formed on the light-transmitting member, and comprising silica, a siloxane, and voids of the silica; and
a second antireflection film formed on the surface of the first antireflection film, and comprising the silica and the siloxane;
wherein the silica has a particle diameter of 5 nm to 50 nm.