# US 2013/0152607 A1 · Process and plant for the vaporization of liquefied natural gas and storage thereof

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- Number: US 2013/0152607 A1
- Document ID: US20130152607A1
- Status: Published application
- Kind: A1
- Application number: 13/675,803
- Filed: 2012-11-13
- Published: 2013-06-20
- Earliest claimed: 2006-06-14
- Inventors: Liberato CICCARELLI
- Web page: https://patentgrep.com/patent/US20130152607A1

## CPC

- F17C 9/04: Recovery of thermal energy
- F01K 23/10: with exhaust fluid of one cycle heating the fluid in another cycle (F01K17/025 takes precedence)
- F01K 25/08: using special vapours
- F17C 2221/033: Methane, e.g. natural gas, CNG, LNG, GNL, GNC, PLNG
- F17C 2223/0161: cryogenic, e.g. LNG, GNL, PLNG
- F17C 2223/033: Small pressure, e.g. for liquefied gas
- F17C 2225/0123: gaseous, e.g. CNG, GNC
- F17C 2225/036: Very high pressure, i.e. above 80 bars
- F17C 2227/0135: Pumps
- F17C 2227/0306: using the same fluid
- F17C 2227/0323: in a closed loop
- F17C 2265/05: Regasification
- F17C 2265/07: Generating electrical power as side effect
- F17C 2270/0105: Ships
- F17C 2270/0118: Offshore
- F17C 2270/0136: Terminals
- F17C: VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES (storing fluids in natural or artificial cavities or chambers in the earth B65G5/00; construction or assembling of bulk storage containers employing civil-engineering techniques E04H7/00; variable-capacity gas-holders F17B; liquefaction or refrigeration machines, plants, or systems F25)
- F01K: STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES (gas-turbine or jet-propulsion plants F02; nuclear power plants, engine arrangements therein G21D)

## Abstract

A process and plant for the vaporization of liquefied natural gas includes obtaining electric energy during the vaporization operation by way of thermal exchange by transformation of an energy source for obtaining electric power.

## Claims

### Claim 1

A process for the vaporization of liquefied natural gas (LNG) and its storage, the process comprising:
production of electric power during said vaporization operation by means of thermal exchange,
wherein said thermal exchange is carried out by means of a heating-releasing permanent gas in a closed cycle in which at least a first part of said vaporized LNG is injected for storage into a pre-existing natural gas reservoir,
wherein said natural gas reservoir is at least partially exhausted, and
wherein a remaining part of non-stored vaporized LNG is burnt and expanded in a turbine.

### Claim 2

The process according to any one of the previous claims, wherein said permanent gas takes heat from the discharge gases of at least a first gas turbine which burns a second part of the vaporized LNG not sent for storage.

### Claim 3

The process according to any one of the previous claims, wherein LNG is vaporized at a substantially constant pressure and pumped by means of thermal exchange with said heat-releasing permanent gas in a closed cycle.

### Claim 4

The process according to any one of the previous claims, wherein in said closed cycle said permanent gas, after the releasing of heat, is subjected to a subsequent thermal exchange with said heat-releasing discharge gases of said turbine and finally to expansion in at least a second turbine.

### Claim 5

The process according to any one of the previous claims, wherein said electric power is produced by both said first turbine in which the remaining vaporized part of LNG not sent for storage is burnt and expanded and also by said second turbine in which said heated compressed permanent gas is expanded.

### Claim 6

The process according to any one of the previous claims, wherein said pumping of LNG is effected at a substantially constant temperature ranging from −155 to −165° C. bringing the pressure of said LNG from about 1 bar to a value ranging from 120 to 180 bars.

### Claim 7

The process according to any one of the previous claims, wherein said substantially constant temperature ranges from −160 to −163° C. and the pressure is brought to a value ranging from 120 to 150 bars.

### Claim 8

The process according to any one of the previous claims, wherein said vaporization of LNG takes place at a substantially constant pressure ranging from 120 to 180 bars bringing the temperature to a value ranging from 10 to 25° C.

### Claim 9

The process according to any one of the previous claims, wherein said first part of vaporized LNG not sent for storage in a reservoir ranges from 3 to 8% of the whole vaporized LNG stream.

### Claim 10

The process according to any one of the previous claims, wherein said second part of non-stored vaporized LNG is burnt and expanded in a turbine up to a pressure of about 1 bar.

### Claim 11

The process according to any one of the previous claims, wherein said permanent gas is preferably selected from helium and nitrogen.

### Claim 12

The process according to any one of the previous claims, wherein when said permanent gas is nitrogen, the thermal exchange with compressed LNG takes place at a substantially constant pressure ranging from 2 to 5 bars bringing the temperature from a value ranging from 75 to 100° C. to a value ranging from −150 to −130° C. and the thermal exchange with the discharge gases takes place at a substantially constant pressure ranging from 50 to 60 bars bringing the temperature from a value ranging from 20 to 40° C. to a value ranging from 400 to 450° C.

### Claim 13

The process according to any one of the previous claims, wherein said electric power obtained from said first and second turbine is produced in current generators coupled with the turbines themselves effected with the super

### Claim 14

The process according to any one of the previous claims, wherein said LNG is transported by means of methane-tankers and before being subjected to said pumping and subsequent vaporization, it is subjected to temporary storage in suitable tanks.

### Claim 15

The process according to any one of the previous claims, wherein the CO2 contained in said discharge gases is sequestered.

### Claim 16

The process according to any one of the previous claims, wherein said sequestered CO2 is injected into said reservoir.

### Claim 17

A plant for the vaporization of liquefied natural gas (LNG), comprising:
transformation means of an energy source for obtaining electric power during said vaporization operation by means of thermal exchange,
wherein said transformation means includes at least a first turbine in which a remaining vaporized part of LNG not sent for storage is burnt and expanded and at least a second turbine in which a heated compressed permanent gas is expanded.

### Claim 18 (depends on 17)

The plant according to claim 17, wherein said electric power obtained from said first and second turbine is produced in current generators coupled with the turbines themselves effected with the superconductor technology.

### Claim 19 (depends on 18)

The plant according to claim 18, further comprising a supplementary marine platform for supporting at least said turbines and reintroduction means of said vaporized gas into an at least partially exhausted natural reservoir.
