# US 2013/0152553 A1 · Selective Catalytic Reduction (SCR) System For NOx Storage

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- Number: US 2013/0152553 A1
- Document ID: US20130152553A1
- Status: Published application
- Kind: A1
- Application number: 13/327,291
- Filed: 2011-12-15
- Published: 2013-06-20
- Earliest claimed: 2011-12-15
- Assignees: GM Global Technology Operations LLC
- Inventors: Eugene V. Gonze; Michael J. Paratore, JR.; Chang H. Kim; Steven J. Schmieg
- Web page: https://patentgrep.com/patent/US20130152553A1

## CPC

- F01N 3/2013: {using electric or magnetic heating means}
- F01N 3/2066: {Selective catalytic reduction [SCR]}
- F01N 3/208: {Control of selective catalytic reduction [SCR], e.g. by adjusting the dosing of reducing agent}
- F01N 3/2892: {Exhaust flow directors or the like, e.g. upstream of catalytic device}
- F01N 9/00: Electrical control of exhaust gas treating apparatus (monitoring or diagnostic devices for exhaust-gas treatment apparatus F01N11/00; conjoint electrical control of two or more combustion engine functions F02D43/00)
- F01N 13/0097: {the purifying devices are arranged in a single housing}
- F01N 11/00: Monitoring or diagnostic devices for exhaust-gas treatment apparatus
- F01N 2240/16: an electric heater, i.e. a resistance heater
- Y02T 10/12: Improving ICE efficiencies
- Y02T 10/40: Engine management systems
- F01N: GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES (arrangements in connection with gas exhaust of propulsion units in vehicles B60K13/00; combustion-air intake silencers specially adapted for, or arranged on, internal-combustion engines F02M35/00; protecting against, or damping, noise in general G10K11/16)
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

An exhaust gas treatment system for an internal combustion engine is provided, including an exhaust gas conduit, a flow-through container of absorbent particles, an electrically heated catalyst (“EHC”) device, a selective catalytic reduction (“SCR”) device, and a control module. The exhaust gas conduit is in fluid communication with, and is configured to receive an exhaust gas from the internal combustion engine. The exhaust gas contains oxides of nitrogen (“NOx”) and water. The flow-through container of absorbent particles is in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas. The flow-through container substantially adsorbs the water from the exhaust gas below a threshold temperature. The EHC device is in fluid communication with the exhaust gas conduit and is configured to receive the exhaust gas. The EHC device is located downstream of the flow through container, and is selectively activated to produce heat.

## Claims

### Claim 1

An exhaust gas treatment system for an internal combustion engine, comprising:
an exhaust gas conduit in fluid communication with, and configured to receive an exhaust gas from the internal combustion engine, the exhaust gas containing oxides of nitrogen (“NOx”) and water;
a flow-through container of absorbent particles in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas, wherein the flow-through container substantially adsorbs water from the exhaust gas below a threshold temperature;
an electrically heated catalyst (“EHC”) device in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas, wherein the EHC device is located downstream of the flow through container of absorbent particles, and wherein the EHC device is selectively activated to produce heat;
a selective catalytic reduction (“SCR”) device in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas, wherein the SCR device is located downstream of the flow through container, and wherein the SCR device is selectively heated by the EHC device to a SCR light-off temperature, and wherein the overall temperature of the SCR device is represented by a SCR temperature profile; and
a control module in communication with the EHC device, comprising:
a control logic for determining the SCR temperature profile; and
a control logic for activating the EHC device if the SCR temperature profile is below the SCR light-off temperature, wherein the EHC device is selectively activated to heat the SCR device to the SCR light-off temperature before the flow-through container of absorbent particles reaches the threshold temperature.

### Claim 2 (depends on 1)

The exhaust treatment system of claim 1, further comprising:
a first temperature sensor situated upstream of the SCR device; and
a second temperature sensor situated downstream of the SCR device.

### Claim 3 (depends on 2)

The exhaust treatment system of claim 2, wherein the control module includes control logic for monitoring the first temperature sensor and the second temperature sensor.

### Claim 4 (depends on 3)

The exhaust treatment system of claim 3, wherein the control module includes a control logic for determining an EHC temperature of the EHC device based on the first temperature sensor, and wherein the control module includes control logic for deactivating the EHC device if the EHC temperature is above an EHC light-off temperature.

### Claim 5 (depends on 3)

The exhaust treatment system of claim 3, wherein the control module includes a control logic for calculating the SCR temperature profile based on signals from the first temperature sensor and the second temperature sensor, wherein the temperatures of the first temperature sensor and the second temperature sensor are averaged together to create the SCR temperature profile.

### Claim 6 (depends on 5)

The exhaust treatment system of claim 5, wherein a reductant injector is in fluid communication with the exhaust gas conduit and is in signal communication with the control module, and wherein the reductant injector is configured for dosing a reductant.

### Claim 7 (depends on 6)

The exhaust treatment system of claim 6, further comprising a first NOx sensor and a second NOx sensor that are in fluid communication with the exhaust gas conduit, the first NOx sensor located downstream of the internal combustion engine and upstream of the SCR device and the second NOx sensor located downstream of the SCR device, and wherein the control module includes control logic for determining an amount of NOx in the exhaust gas reduced by the SCR device based on the first NOx sensor, the second NOx sensor, and the SCR temperature profile temperature.

### Claim 8 (depends on 7)

The exhaust treatment system of claim 7, wherein the control module includes control logic for determining an amount of the reductant the SCR device has stored therein during a previous cold start of the internal combustion engine.

### Claim 9 (depends on 8)

The exhaust treatment system of claim 8, wherein the control module includes control logic for determining an amount of the reductant that has been consumed by the SCR device to convert the amount of NOx in the exhaust gas reduced by the SCR device.

### Claim 10 (depends on 9)

The exhaust treatment system of claim 9, wherein the control module includes control logic for activating the reductant injector to replace the reductant consumed by the SCR device to the amount of the reductant the SCR device has stored therein during the previous cold start of the internal combustion engine.

### Claim 11 (depends on 1)

The exhaust treatment system of claim 1, wherein the threshold temperature is about 100° C.

### Claim 12 (depends on 1)

The exhaust treatment system of claim 1, wherein the flow-through container of absorbent particles includes one of alumina particles, activated carbon particles, water absorbent zeolite materials, and water absorbent molecular sieve materials.

### Claim 13 (depends on 1)

The exhaust treatment system of claim 1, wherein the flow-through container of absorbent particles includes a selective catalyst composition applied as a washcoat on surfaces of a flow-through support.

### Claim 14 (depends on 1)

The exhaust treatment system of claim 1, wherein a portion of the flow-through container of absorbent particles includes a selective catalyst composition applied as a washcoat on surfaces of a flow-through support, and a remaining portion of the flow-through container of absorbent particles does not include the selective catalyst composition.

### Claim 15 (depends on 1)

The exhaust treatment system of claim 1, wherein the control module includes control logic for monitoring a water holding capacity of the flow-through container of absorbent particles.

### Claim 16

An exhaust gas treatment system for an internal combustion engine, comprising:
an exhaust gas conduit in fluid communication with, and configured to receive an exhaust gas from the internal combustion engine, the exhaust gas containing oxides of nitrogen (“NOx”) and water;
a flow-through container of absorbent particles in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas, wherein the flow-through container substantially adsorbs water from the exhaust gas below a threshold temperature;
an electrically heated catalyst (“EHC”) device in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas, wherein the EHC device is located downstream of the flow through container, and wherein the EHC device is selectively activated to produce heat;
a selective catalytic reduction (“SCR”) device in fluid communication with the exhaust gas conduit and configured to receive the exhaust gas, wherein the SCR device is located downstream of the flow through container, and wherein the SCR device is selectively heated by the EHC device to a SCR light-off temperature, and wherein the overall temperature of the SCR device is represented by a SCR temperature profile;
a first temperature sensor and a second temperature sensor, the first temperature sensor situated upstream of the SCR device and the second temperature sensor situated downstream of the SCR device; and
a control module in communication with the EHC device, the first temperature sensor, and the second temperature sensor, comprising:
a control logic for monitoring the first temperature sensor and the second temperature sensor;
a control logic for calculating the SCR temperature profile based on signals from the first temperature sensor and the second temperature sensor, wherein the temperatures of the first temperature sensor and the second temperature sensor are averaged together to create the SCR temperature profile; and
a control logic for activating the EHC device if the SCR temperature profile is below the SCR light-off temperature, wherein the EHC device is selectively activated to heat the SCR device to the SCR light-off temperature before the flow-through container of absorbent particles reaches the threshold temperature.

### Claim 17 (depends on 16)

The exhaust treatment system of claim 16, wherein a reductant injector is in fluid communication with the exhaust gas conduit and is in signal communication with the control module, and wherein the reductant injector is configured for dosing a reductant.

### Claim 18 (depends on 17)

The exhaust treatment system of claim 17, further comprising a first NOx sensor and a second NOx sensor that are in fluid communication with the exhaust gas conduit, the first NOx sensor located downstream of the internal combustion engine and upstream of the SCR device and the second NOx sensor located downstream of the SCR device, and wherein the control module includes control logic for determining an amount of NOx in the exhaust gas reduced by the SCR device based on the first NOx sensor, the second NOx sensor, and the SCR temperature profile temperature.

### Claim 19 (depends on 18)

The exhaust treatment system of claim 18, wherein the control module includes control logic for determining an amount of the reductant the SCR device has stored therein during a previous cold start of the internal combustion engine.

### Claim 20 (depends on 19)

The exhaust treatment system of claim 19, wherein the control module includes control logic for determining an amount of the reductant that has been consumed by the SCR device to convert the amount of NOx in the exhaust gas reduced by the SCR device, and wherein the control module includes control logic for activating the reductant injector to replace the reductant consumed by the SCR device to the amount of the reductant the SCR device has stored therein during the previous cold start of the internal combustion engine.
