Process for hydroconversion of petroleum feedstocks via a slurry technology allowing the recovery of metals from the catalyst and from the feedstock using a coking step
AssigneeIfp Energies Nouvelles
InventorsJean Philippe Heraud, Frederic Morel, Alain Quignard
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Abstract
A process for hydroconversion of heavy petroleum feedstocks comprising a hydroconversion step of the feedstock in at least one reactor containing a slurry catalyst and allowing the recovery of metals in the unconverted residual fraction, in particular those used as catalysts, The process comprises a hydroconversion step, a gas/liquid separation step, a coking step, a combustion step, a metals extraction step and a step of preparing catalytic solutions which are recycled to the hydroconversion step.
Claims13
Process for hydroconversion of heavy petroleum feedstocks containing metals comprising:
- a) a step of hydroconversion of the feedstock in at least one reactor containing a slurry catalyst containing at least one metal, and optionally a solid additive,
- b) a step of separation of the hydroconversion effluent without decompression into a so-called light fraction containing the compounds boiling at a maximum temperature of 500° C. and a residual fraction,
- b′) optionally a fractionation step comprising a separation under vacuum of said residual fraction as obtained in step b), and a vacuum residue with a high concentration of metals is obtained,
- c) a step of coking of said residual fraction as obtained in step b) and/or of said vacuum residue as obtained in step b′) making it possible to obtain a solid effluent containing coke,
- d) a step of combustion of said solid effluent containing coke at a temperature comprised between 200 and 700° C. making it possible to obtain ashes with a high concentration of metals,
- e) a step of extraction of the metals from the ashes obtained in the combustion step,
- f) a step of preparation of metallic solution(s) containing at least the metal of the catalyst which is/are recycled(s) as catalyst in the hydroconversion step.
Dependencies are inferred from the claim text.