Novel Co-Modified Organopolysiloxane
AssigneeDow Corning Toray Co., Ltd.
InventorsSeiki Tamura, Tomohiro Iimura, Akito Hayashi, Tatsuo Souda, Haruhiko Furukawa
Life of this patent
Estimating the term…
Abstract
A novel organopolysiloxane having a hydrophilic group, which can be produced easily and is not susceptible to two-phase separation, sedimentation of unreacted materials or the like after production, while being chemically stable and excellently practical, is disclosed. A method for producing the organopolysiloxane; and uses of the organopolysiloxane are also disclosed. The organopolysiloxane is a co-modified organopolysiloxane which has a group having a siloxane dendron structure and a hydrophilic group.
Claims32
A co-modified organopolysiloxane having a group with a siloxane dendron structure and a hydrophilic group, expressed by the following general formula (1)2
- General Formula (1):
- R1aL1bQcSiO(4-a-b-c)/2 (1)
- wherein,
- R1 is a monovalent organic group with the exception of groups corresponding to L1 or Q, or a hydrogen atom;
- L1 is a silylalkyl group having a siloxane dendron structure expressed by the following general formula (2) when i=1;
- wherein, R1 is synonymous with the group described above, R2 is a phenyl group or an alkyl group having from 1 to 6 carbons, and Z is a divalent organic group;
- i represents a generation of the silylalkyl group represented by Li, and is an integer of 1 to c when c is a number of generations that is a number of repetitions of the silylalkyl group, the number of generations c is an integer from 1 to 10, and Li+1 is the silylalkyl group when i is less than c and is a methyl group or a phenyl group when i=c;
- ai is a number in a range of 0 to 3;
- Q is a hydrophilic group bonded to the silicon atom via a linking group that is at least divalent, and comprises at least one hydrophilic unit selected from hydrophilic units expressed by the following structural formulae (3-1) to (3-4):
- —CrH2r—O— (3-1)
- wherein r is a number in a range of 1 to 6;
- wherein W is a hydrogen atom or an alkyl group having from 1 to 20 carbons;
- wherein W is synonymous with the group described above;
- and
- wherein a, b, and c are in a range so that 1.0≦a≦2.5, 0.001≦b≦1.5, and 0.001≦c≦1.5.
(canceled)
(canceled)
(canceled)
(canceled)
29-30. (canceled)
Dependencies are inferred from the claim text.