Catalyst preparation using h2
AssigneeBorealis Technology Oy
InventorsTimo Leinonen, Peter Denifl, Anssi Haikarainen
Life of this patent
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Abstract
The invention refers to a process for preparing a Group 2 metal/transition metal olefin polymerization catalyst component in particulate form having improved polymerization properties due to the use of H2 during catalyst component preparation and the use of such catalyst components in a process for polymerizing olefins.
Claims26
1-18. (canceled)
A process for producing homo- or copolymers by polymerizing C2 to C10 α-olefins or combinations thereof using an olefin polymerization catalyst, said catalyst comprises an alkylaluminium cocatalyst;
- and
- particles of a catalyst component prepared by steps comprising
- a) preparing a solution of a complex of a Group 2 metal and an electron donor by reacting a compound of said metal with said electron donor or a precursor thereof in an organic liquid reaction medium,
- b) adding said solution of said complex to at least one compound of a transition metal to produce an emulsion, wherein the dispersed phase of which is in the form of droplets and contains more than 50 mol % of the Group 2 metal in said complex,
- c) agitating the emulsion in order to maintain the droplets of said dispersed phase within said predetermined average size range,
- d) solidifying said droplets of the dispersed phase,
- e) washing the solidified particles at least once,
- f) drying the solidified particles or slurring the solidified particles to an oily liquid without drying and optionally
- g) recovering the dried or slurried solidified particles of the catalyst component,
- wherein H2-gas is added to at least one of the production steps a) to g).
Particles of an olefin polymerization catalyst component having a predetermined average size range of 5 to 200 μm, said catalyst component prepared by steps comprising
- a) preparing a solution of a complex of a Group 2 metal and an electron donor by reacting a compound of said metal with said electron donor or a precursor thereof in an organic liquid reaction medium,
- b) adding said solution of said complex to at least one compound of a transition metal to produce an emulsion, wherein the dispersed phase of which is in the form of droplets and contains more than 50 mol % of the Group 2 metal in said complex,
- c) agitating the emulsion in order to maintain the droplets of said dispersed phase within said predetermined average size range,
- d) solidifying said droplets of the dispersed phase,
- e) washing the solidified particles at least once,
- f) drying the solidified particles or slurring the solidified particles to an oily liquid without drying and optionally
- g) recovering the dried or slurried solidified particles of the olefin polymerization catalyst component,
- wherein H2-gas is added to at least one of the production steps a) to g).
Dependencies are inferred from the claim text.