A metallic conductive ink for ink-jet printing, comprising a metal precursor material, in particular an organometallic decomposition compound, and a thermally decomposable polymer dissolved in an organic solvent, characterized in that a polymer having a decomposition temperature Tc<150° C. is contained as the thermally decomposable polymer, the polymer is selected from a cyclic polyacetal having blocked terminal groups, a cyclic polyaldehyde comprising bifunctional monomers, such as polyphthalaldehyde, polyglutaraldehyde, polysuccinaldehyde, or a polymeric glyoxylic acid, or a glyoxylic acid derivative, such as poly(methyl glyoxylate), and monomeric depolymerization products of the thermally decomposable polymer are used as reductants for the metal precursor material.