Process to manufacture grain-oriented electrical steel strip and grain-oriented electrical steel produced thereby

A process to manufacture grain-oriented electrical steel (GOES) strip wherein a molten silicon-alloyed steel is continuously cast in a strand having a thickness in the range of from 50 to 100 mm, wherein the molten steel alloy comprises:

• Silicon 2.1% to 4.5%;
• Carbon up to 0.1%;
• Manganese 0.02% to 0.5%;
• Copper 0.01% to 0.3%;
• Sulphur and/or Selenium up to 0.04%;
• Aluminium up to 0.07%;
• Nitrogen up to 0.015%;
• optionally one or more elements selected from one or more of the groups a-c:
• a. Titanium, Vanadium, Boron, Tungsten, Zirconium, Niobium to a maximum total amount of 0.05%, and
• b. Tin, Antimony, Arsenic to a maximum total amount of 0.15%, and
• c. Phosphorous, Bismuth to a maximum total amount of 0.03%;
• the remainder being iron and unavoidable impurities;
• wherein the solidified strand is hot-rolled in a plurality of uni-directional rolling stands to produce final hot-rolled strip coils having a thickness in the range of from 0.7 to 4.0 mm by a sequence comprising the subsequent steps of:
• cooling the solidified strand to a core temperature not lower than 900° C.;
• homogenisation of the strand at a temperature in the range of from 1000 to 1300° C.;
• a first rolling reduction of the strand of at least 60% in two or more rolling steps in a roughing stage to obtain a transfer bar wherein the roughing stage consists of at least two uni-directional and consecutive rolling stands and wherein the reduction in the first rolling stand is lower than 40% and wherein the time between consecutive rolling passes in the roughing stage is less than 20 seconds;
• transfer of the transfer bar having a temperature in the range of from 950 to 1250° C. to a finishing stage wherein the transfer time between exiting the roughing stage and entering the finishing stage is at least 15 seconds and at most 60 seconds to activate the recrystallisation process in the deformed material;
• reducing the transfer bar down to final hot-rolled strip thickness in a second rolling reduction in a finishing stage in one or more uni-directional rolling steps;
• cooling the final hot-rolled strip between the finishing stage and the coiling station;
• coiling the final hot-rolled strip at a coiling temperature in the range of from 500 to 780° C.;
• followed by a sequence comprising the subsequent steps of:
• continuous annealing the hot-rolled strip at a maximum temperature of 1150° C.
• cold rolling the annealed strip to the final cold-rolled thickness in the range of from 0.15 to 0.5 mm by single cold rolling or by double cold rolling with an intermediate continuous annealing;
• continuous annealing the cold-rolled strip to induce primary recrystallisation and, optionally, decarburization and/or nitriding at a temperature in the range of 750 to 850° C. by regulating the chemical composition of the annealing atmosphere;
• coating the annealed strip with an annealing separator and coiling the annealed strip;
• annealing the coiled strip to induce secondary recrystallisation;
• continuous thermal flattening annealing of the annealed strip;
• coating the annealed strip for electric insulation.