Back to results
US 2012/0208989 A1Published application
Fluorinated aromatic materials and their use in optoelectronics
AssigneeThe University of South Dakota
InventorHaoran Sun
Life of this patent
Estimating the term…
Abstract
Fluorinated aromatic materials, their synthesis and their use in optoelectronics. In some cases, the fluorinated aromatic materials are perfluoroalkylated aromatic materials that may include perfluoropolyether substituents.
Claims18
A fluorinated aromatic compound of the formula:
- Ar—(R)x-(Q)y-(G)z,
- where Ar is an aromatic core including 3 to about 120 sp2 hybridized carbon atoms or a total of about 3 to about 120 sp2 hybridized carbon atoms, nitrogen atoms, oxygen atoms and sulfur atoms;
- R is a perfluoroalkyl group of the formula CnF2n+1, n is an integer ranging from 1 to about 30;
- Q is a perfluoropolyether group of the formula CkF2k+1Oh, k is an integer ranging from 1 to about 1000, h is an integer less than or equal to k−1;
- G is an organic functional group selected from the group consisting of hydrogen, C1-30 alkyl, C3-30 aryl, halogen, nitro, cyano, ester, ether, hydroxyl, aryl group bearing substituents including one or more of carbon, fluorine, chlorine, bromine, nitro or methoxy, or an aryl group including a heteroatom such as N, O and S;
- x, y and z are integers such that x+y+z is less than or equal to a total number of sp2 hybridized carbon atoms, nitrogen atoms, oxygen atoms and sulfur atoms in the aromatic core, and y and z may independently be zero.
3 more elements
A method of making a fluorinated aromatic compound, comprising:
- combining a brominated aromatic and a perfluoroalkyl halide in a solvent including a fluorinated solvent;
- and
- reacting the brominated aromatic and the perfluoroalkyl halide in a copper mediated cross-coupling reaction.
Dependencies are inferred from the claim text.