A method of preparing a laser-ablatable element comprising applying to a substrate, multiple formulations each comprising a coating solvent, a laser-ablatable polymeric binder, and an infrared radiation absorbing compound, to provide multiple sub-layers on the substrate, such that the infrared radiation absorbing compound concentration is different in each adjacent pair of sub-layers so that the concentration is always greater in each pair sub-layer that is closer to the substrate, and the concentration is progressively greater in the sub-layers as they are closer to the substrate after the coating solvent is removed, wherein the multiple sub-layers provide a relief-forming layer so that the sub-layer farthest from the substrate provides a relief-image forming surface.