# US 2012/0074070 A1 · System and method for reducing at least an amount of disinfection by-products in water

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- Number: US 2012/0074070 A1
- Document ID: US20120074070A1
- Status: Published application
- Kind: A1
- Application number: 13/242,838
- Filed: 2011-09-23
- Published: 2012-03-29
- Earliest claimed: 2010-09-23
- Inventors: Cosima Sichel
- Web page: https://patentgrep.com/patent/US20120074070A1

## CPC

- C02F 1/32: with ultraviolet light
- C02F 1/725: {by catalytic oxidation}
- C02F 2103/42: from bathing facilities, e.g. swimming pools
- C02F 2209/005: Processes using a programmable logic controller [PLC]
- C02F 2305/10: Photocatalysts
- C02F: TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE (separation in general B01D; special arrangements on waterborne vessels of installations for treating water, waste water or sewage, e.g. for producing fresh water, B63J; adding materials to water to prevent corrosion C23F; treating radioactively-contaminated liquids G21F9/04; regeneration of reactants for recirculation into processes, see the relevant places for the processes)

## Abstract

In a method and a system for reducing at least an amount of disinfection by-products in water, the system has a dosing pump (15) for adding a photocatalyst (36) into a stream (17) of the water to obtain a mixed stream (17′), and a photo reactor (20) adapted to receive the mixed stream (17′) and to irradiate the mixed stream (17′) with photons, the photocatalyst (36) in the mixed stream (17′) producing free radicals on being irradiated with the photons, wherein the dosing pump (15) is controllable responsive to an amount of absorption of the photons by the mixed stream (17′).

## Claims

### Claim 1

A system for reducing at least an amount of disinfection by-products in water, comprising:
at least one dosing pump for adding a photocatalyst into a stream of the water to obtain a mixed stream, and
a photo reactor adapted to receive the mixed stream and to irradiate the mixed stream with photons, the photocatalyst in the mixed stream being adapted to produce free radicals on being irradiated with the photons, wherein the at least one dosing pump is controllable responsive to an amount of absorption of the photons by the mixed stream.

### Claim 2 (depends on 1)

The system according to claim 1, further comprising one or more sensors arranged close to or inside the photo reactor to detect an amount of irradiance of the photons after the photons passed through the mixed stream, the one or more sensors being configured to output respective signals indicative of the amount of irradiance of the photons.

### Claim 3 (depends on 2)

The system according to claim 2, further comprising at least one controller operably coupled to the one or more sensors to receive the respective signals, the at least one controller being configured to provide a control signal to the dosing at least one dosing pump responsive to the respective signals, wherein the at least one dosing pump is operable responsive to the control signal.

### Claim 4 (depends on 3)

The system according to claim 3, wherein the at least one controller is configured to generate the control signal based on an average amount of the amounts of irradiance indicated by the respective signals provided by two or more sensors at the same time.

### Claim 5 (depends on 2)

The system according to claim 2, wherein the at least one dosing pump is operable to control the addition of the photocatalyst such that a concentration of the photocatalyst in the mixed stream is settable in that the amount of irradiance of the photons detected is constant.

### Claim 6 (depends on 1)

The system according to claim 1, wherein the photocatalyst is a chalcogenide.

### Claim 7 (depends on 6)

The system according to claim 6, wherein the chalcogenide is an oxide or a sulphide.

### Claim 8 (depends on 7)

The system according to claim 7, wherein the oxide is selected from the group consisting of a TiO2, ZnO, ZrO2, CeO2, SnO2, and SbrO2 and the sulphide is CdS or ZnS.

### Claim 9 (depends on 1)

The system according to claim 1, wherein the photocatalyst is in the form of a slurry.

### Claim 10 (depends on 1)

The system according to claim 1, further comprising a filter unit adapted to remove the photocatalyst at least in part from an irradiated mixed stream downstream of a place of irradiation of the mixed stream with the photons.

### Claim 11 (depends on 10)

The system according to claim 10, wherein the system comprises a filter backwashing system which is adapted to backwash the photocatalyst removed from the irradiated mixed stream by the filter unit responsive to the amount of absorption of the photons by the mixed stream.

### Claim 12

A method of reducing at least an amount of disinfection by-products in water comprising:
adding a photocatalyst into a stream of water to obtain a mixed stream, and
irradiating the mixed stream with photons, the photocatalyst in the mixed stream producing free radicals on being irradiated with the photons, and
controlling the addition of the amount of photocatalyst into the stream responsive to an amount of absorption of the photons by the mixed stream.

### Claim 13 (depends on 12)

The method according to claim 12, wherein the controlling of the addition of the amount of photocatalyst comprises:
detecting an amount of irradiance of the photons after the photons passed through the mixed stream, and
controlling the addition of the amount of photocatalyst responsive to the amount of irradiance detected.

### Claim 14 (depends on 12)

The method according to claim 12, wherein the photocatalyst is a chalcogenide.

### Claim 15 (depends on 12)

The method according to claim 12, wherein the photocatalyst is an oxide or a sulphide.

### Claim 16 (depends on 15)

The method according to claim 15, wherein the oxide is selected from the group consisting of a TiO2, ZnO, ZrO2, CeO2, SnO2, and SbrO2 and the sulphide is CdS or ZnS.

### Claim 17 (depends on 12)

The method according to claim 12, wherein the photocatalyst is dosed to the stream in form of a photocatalyst powder.

### Claim 18 (depends on 12)

The method according to claim 12, wherein the photocatalyst is dosed to the stream in form of a slurry containing a photocatalyst powder.

### Claim 19

A method for reducing at least an amount of disinfection by-products in water, comprising:
adding a photocatalyst into a stream of water by at least one dosing pump to obtain a mixed stream, and
receiving the mixed stream by a photo reactor and irradiating the mixed stream with photons, wherein the photocatalyst in the mixed stream is adapted to produce free radicals on being irradiated with the photons, and wherein the at least one dosing pump is controllable responsive to an amount of absorption of the photons by the mixed stream.

### Claim 20 (depends on 19)

The method according to claim 19, further detecting an amount of irradiance of the photons after the photons passed through the mixed stream by one or more sensors arranged close to or inside the photo reactor, wherein the one or more sensors are configured to output respective signals indicative of the amount of irradiance of the photons.
