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US 2012/0071686 A1Published application
Production of diesters from dinitrile compounds
AssigneeRhodia Operations
InventorsRoland Jacquot, Philippe Leconte
Life of this patent
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Abstract
Diesters are prepared by first hydrolyzing dinitrile compounds into imide compounds and then reacting such imide compounds with at least one alcohol.
Claims19
-18. (canceled)
A process for the preparation of at least one diester compound comprising the following stages:
- a) first preparing an imide compound of the following general formula (I):
- wherein A is a linear or branched divalent hydrocarbon radical having from 2 to 12 carbon atoms,
- by hydrolysis, in the presence of water, of at least one dinitrile compound of following general formula (III):
- NC-A-CN (III)
- and b) then reacting said imide compound with at least one alcohol of the following general formula (II):
- R—OH (II)
- wherein R is a linear or branched aliphatic, cycloaliphatic, aromatic or arylalkyl hydrocarbon radical having from 1 to 20 carbon atoms and optionally containing heteroatoms,
- to obtain a reaction product comprising at least one diester compound of the following general formula (IV) and optionally by-products of different formula (e):
- R—OOC-A-COO—R (IV)
- wherein:
- at least one of the stages a) and/or b) is carried out in the presence of a catalyst, with the proviso that if both stages are carried out in the presence of a catalyst, then stage b) is carried out in the presence of at least one catalyst other than that employed during stage a).
8 more elements
Dependencies are inferred from the claim text.