Crosslinkable dielectrics and methods of preparation and use thereof

An electronic device comprising at least one dielectric layer,

• wherein the at least one dielectric layer comprises a crosslinked organic compound based on at least one radically crosslinkable compound,
• the at least one radically crosslinkable compound comprises:
• (i) at least one acrylate group, wherein the at least one radically crosslinkable compound is selected from the group consisting of a polyether acrylate, a polyester acrylate, and a homopolymer or copolymer acrylate,
• (ii) an olefinic double bond, a triple bond, or both in at least one side chain, wherein the at least one radically crosslinkable compound is at least one alkyd resin;
• or
• (iii) both (i) and (ii),
• the copolymer acrylate is a random copolymer or a block copolymer of one of formulae
• wherein
• R7 is independently H;
• OR8—;
• alkyl;
• alkenyl;
• alkynyl;
• —C(O)—OR8;
• —C(O)—R8—;
• —OH;
• alkyl substituted with —OH, —C(O)—OR8—, or —C(O)—R8—;
• alkyl wherein the alkyl chain is interrupted by one or more oxygen atoms;
• aryl;
• heteroaryl;
• cycloalkyl;
• and heterocycloalkyl,
• X is CR82, O, NR8, SiO or SiR82;
• R8 is H, alkyl, aryl, heteroaryl, cycloalkyl, heterocycloalkyl, vinyl, alkenyl, alkynyl, cycloalkenyl, or cycloalkynyl,
• R9 is H or a methyl group,
• R10 is CpH2p+1, wherein p is from 1 to 6
• n is from 1 to 20, and
• o+m is from 1 to 500.