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US 2012/0059182 A1Published application
Catalysts, Methods of Makting Catalysts, and Methods of Use
AssigneeUniversity of Florida Research Foundation, Inc.
InventorsSukwon Hong, Hwimin Seo
Life of this patent
Estimating the term…
Abstract
Embodiments of the present disclosure provide for acyclic diaminocarbenes (ADCs) catalysts such as those shown in FIG. 1.1 and in the Examples, methods of making catalysts, methods of using catalysts, and the like. Catalyst of the present disclosure can be useful in various catalytic transformations. Embodiments of the catalyst can be used in hydroamination, cycloisomerization, allylic rearrangement reactions, alkyne hydration reactions, Meyer-Schuster rearrangement reactions, and the like.
Claims15
A compound, comprising a formula of compound A:
- wherein R1 and R2 are independently selected from a secondary alkyl group, unsubstituted or substituted, or a tertiary alkyl group, unsubstituted or substituted, R3 and R4 are independently selected from an aryl group, and MG is a metal group.
A compound, comprising a formula of compound A:
- wherein R1 and R2 are independently selected from a secondary alkyl group, unsubstituted or substituted, or a tertiary alkyl group, unsubstituted or substituted, R3 and R4 are independently an aryl group, Y is selected from the group consisting of:
- Cl, Br, I, BF4, PF6, BAr4, ClO4, OAc, OTf, Ts, Ms, NTf2, and PO2Cl2.
Dependencies are inferred from the claim text.