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US 2012/0059096 A1Published application
Stable Solution of the Polymer Prepared from N,O-Heterocycles and its Preparation Method and Use
AssigneeTaiwan Union Technology Corporation
InventorsShih-Hao Liao, Chih-Wei Liao, Hsuan-Hao Hsu, Hsien-Te Chen, Tsung-Hsien Lin
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Abstract
A stable solution of the polymer prepared from N,O-heterocyclic compound and its preparing method are provided, wherein the stable solution is prepared by making the N,O-heterocyclic compound of formulae I or II carry out a ring-opening polymerization: wherein R1 to R3, W1, W2, m, n, p and q are as defined in the specification. The stable solution can be used as a hardener for curing epoxy resin.
Claims15
A method for providing a stable solution of polymer prepared from an N,O-heterocyclic compound, comprising:
- (a) dissolving an N,O-heterocyclic compound of formula I or formula II into a first solvent to form a first reaction solution:
- wherein,
- R1 to R3 are independently selected from the group consisting of H, a halogen, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C1-C10 cycloalkyl group, and a substituted or unsubstituted C6-C20 aryl group;
- W1 and W2 are independently selected from the group consisting of H, a halogen, an ether group, a thioether group, a sulfonyl group, a sulfinyl group, a carbonyl group, a substituted or unsubstituted C1-C10 alkyl group, a substituted or unsubstituted C1-C10 cycloalkyl group and a substituted or unsubstituted C6-C20 aryl group;
- m and n are independently an integer ranging from 1 to 4;
- p is an integer ranging from 1 to 3;
- and
- q is an integer ranging from 1 to 4;
- (b) heating the first reaction solution to a first temperature to carry out a ring-opening polymerization;
- and
- (c) cooling the first reaction solution to a second temperature to substantially terminate the ring-opening polymerization,
- wherein, the first solvent is unreactive to the N,O-heterocyclic compound;
- the first temperature is higher than the softening point of the N,O-heterocyclic compound and lower than the boiling point of the first solvent;
- and the second temperature is lower than the first temperature.
11 more elements
Dependencies are inferred from the claim text.