Method for manufacture of noble metal alloy catalysts and catalysts prepared therewith
AssigneeUmicore AG & Co. KG
InventorsDan V. GOIA, Marco LOPEZ, Tapan Kumar SAU, Mihaela-Ortansa JITIANU
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AssigneeUmicore AG & Co. KG
InventorsDan V. GOIA, Marco LOPEZ, Tapan Kumar SAU, Mihaela-Ortansa JITIANU
Estimating the term…
The invention provides a method for manufacturing supported noble metal based alloy catalysts with a high degree of alloying and a small crystallite size. The method involves using polyol solvents as reaction medium and comprises a two-step reduction process in the presence of a support material. In the first step, the first metal (transition metal; e.g. Co, Cr, Ru) is activated by increasing the reaction temperature to 80 to 160° C. In the second step, the second metal (noble metal; e.g. Pt, Pd, Au) is added and the slurry is heated to the boiling point of the polyol solvent in a range of 160 to 300° C. The catalysts manufactured according to the method are used as electrocatalysts for polymer electrolyte membrane fuel cells (PEMFC), direct-methanol fuel cells (DMFC) or as gas phase catalysts for CO oxidation or exhaust gas purification.
1-18. (canceled)
A supported ternary platinum-cobalt-gold alloy catalyst with the atomic ratio Pt:Co=3:1,
A supported ternary platinum-cobalt-palladium alloy catalyst with the atomic ratio Pt:Co=3:1,
A supported ternary platinum-cobalt-gold alloy catalyst according to claim 1, wherein the concentration of platinum, cobalt and gold on the support is in the range of 1 to 90 wt.-% based on the total weight of the catalyst.
A supported ternary platinum-cobalt-gold alloy catalyst according to claim 1, wherein the concentration of platinum, cobalt and gold on the support is in the range of 20 to 80 wt.-% based on the total weight of the catalyst.
A supported ternary platinum-cobalt-palladium alloy catalyst according to claim 2, wherein the concentration of platinum, cobalt and palladium on the support is in the range of 1 to 90 wt.-% based on the total weight of the catalyst.
A supported ternary platinum-cobalt-palladium alloy catalyst according to claim 2, wherein the concentration of platinum, cobalt and palladium on the support is in the range of 20 to 80 wt.-% based on the total weight of the catalyst.
Dependencies are inferred from the claim text.