Polyoxyalkylene polyol or monool and polyurethane resin
AssigneeSanyo Chemical Industries, Ltd.
InventorsHiromichi Nakaminami, Shogo Sugahara, Shu Yasuhara, Kouichi Murata
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AssigneeSanyo Chemical Industries, Ltd.
InventorsHiromichi Nakaminami, Shogo Sugahara, Shu Yasuhara, Kouichi Murata
Estimating the term…
An object of the present invention is to provide a polyoxyalkylene polyol and a polyoxyalkylene monool, capable of producing a urethane elastomer and a urethane foam which are sufficiently excellent in mechanical properties and moisture resistance. The present invention is directed to a polyoxyalkylene polyol or monool (S), which is an alkylene oxide adduct of an active hydrogen-containing compound (H), wherein 40% or more of hydroxyl groups located at the terminal are primary hydroxyl group-containing groups represented by the general formula (1) shown below, and a hydroxyl value x, the total degree of unsaturation y and the content of ethylene oxide z satisfy a relationship of the mathematical expression (1). [In the general formula (1), R1 represents a hydrogen atom, an alkyl group having 1 to 12 carbon atoms, a cycloalkyl group or a phenyl group, each of which may be substituted with a halogen atom or an aryl group.] y≦28.3×x−2×(100−z)/100 (1) [In the mathematical expression (1), x represents a hydroxyl value, y represents the total degree of unsaturation, and z is the content of ethylene oxide based on the weight of (S) and is from 0 to 50% by weight.
A polyoxyalkylene polyol or monool (S), which is an alkylene oxide adduct of an active hydrogen-containing compound (H), wherein 40% or more of hydroxyl groups located at the terminal are primary hydroxyl group-containing groups represented by the general formula (1) shown below, and a hydroxyl value x, the total degree of unsaturation y and the content of ethylene oxide z satisfy a relationship of the mathematical expression (1).
A method for producing a polyoxyalkylene polyol or monool, comprising the step of addition polymerization of an active hydrogen compound (H) with an alkylene oxide in the presence of the aforementioned catalyst (C) in a reaction vessel (1) while removing a low boiling point compound (t) as a by-product having a boiling point of 150° C. or lower under a pressure of 0.1 MPa, continuously or intermittently, out of the system.
Dependencies are inferred from the claim text.