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US 2011/0257310 A1Published application
Flame-retardant composition comprising a phosphonic acid derivative
AssigneeThor GmbH
InventorVolker Butz
Life of this patent
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Abstract
The present invention relates to a flame-retardant composition that comprises a synergistic flame-retardant mixture, and a method for flame-retarding a polymer by adding the flame-retardant composition. The invention further relates to polymers that contain said flame-retardant composition.
Claims14
A blend containing a synergistic mixture of (A) and (B), which denote the following:
- (A) is a compound or a mixture of 2 or more chemical compounds selected from the group consisting of
- a) one or more phosphonate compound(s) of the Formula
- where A1 and A2 independently denote a substituted or unsubstituted, straight or branched chain alkyl group having to 4 carbon atoms, substituted or unsubstituted benzyl, substituted or unsubstituted phenyl, or substituted or unsubstituted naphthyl, and
- b) one or more phosphonate compound(s) of the following Formula
- where A3 and A4 independently denote methyl or ethyl and A5 denotes a straight or branched chain alkyl group having 1 to carbon atoms or a phenyl or benzyl group having up to 3 methyl groups respectively, and
- c) alkyl or arylphosphonic acids, where alkyl denotes a straight or branched chain alkyl group having 1 to 4 carbon atoms, and aryl denotes a substituted or unsubstituted benzyl, substituted or unsubstituted phenyl, substituted or unsubstituted naphthyl, or a salt or ester of the aforementioned phosphonic acid, and
- (B) a 1,3,5-triazine compound or a mixture of two or more 1,3,5-triazine compound(s) selected from tris-2-hydroxyethyl isocyanurate, melamine, melamine cyanurate, melamine phosphate, poly-[2,4-(piperazin-1,4-yl)-6-(morpholin-4-yl)-1,3,5-triazine], dimelamine phosphate, melamine pyrophosphate, and hindered amine compounds of Formula I, II, IIA, and III:
- R1NH—CH2CH2CH2NR2CH2CH2NR3CH2CH2CH2NHR4 (I)
- T-E1-T1 (II)
- T-E1 (IIA)
- G-E1-G1-E1-G2 (III),
- where in the tetraamine of Formula I
- R1 and R2 denote the s-triazine moiety E, and one of R3 and R4 denotes the s-triazine moiety E, with the other of R3 or R4 denoting a hydrogen,
- E denotes
- R denotes methyl, cyclohexyl or octyl,
- R5 denotes an alkyl having 1 to 12 carbon atoms,
- where in the compound of Formula II or IIA, if R denotes cyclohexyl or octyl, each of T and T1 denotes a tetraamine substituted by R1-R4 as defined in Formula I, where
- (1) one of the s-triazine moieties E in each tetraamine is replaced by the group E1, which forms a bridge between two tetraamines T and T1, or
- (2) the group E1 can have both terminals in the same tetraamine T as in Formula IIA, where two of the E moieties of the tetraamine are replaced by one E1 group, or
- (3) all three s-triazine substituents of tetraamine T can denote E1, such that one E1 residue comprises the bond between T and T1 and a second E1 residue has both terminals in tetraamine T,
- and
- E1 denotes
19 more elements
Dependencies are inferred from the claim text.