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US 2011/0257055 A1Published application
Composite Particles and Method of Forming
Assignee3M Innovative Properties Company
InventorsJimmie R. Baran, Haeen Sykora, Madeline P. Shinbach, Roxanne A. Boehmer, Daniel W. Wuerch
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Abstract
Composite particles and a method of forming composite particles are described. The composite particles comprise at least one inorganic nanoparticle covalently bound to at least one inorganic microparticle with a linking compound. Lubricant compositions and sprayable dispersion compositions comprising composite particles are also described.
Claims24
A composite particle comprising:
- at least one inorganic microparticle;
- at least one inorganic nanoparticle;
- and
- at least one linking compound comprising a metal atom M selected from the group consisting of Si and Ti, wherein the at least one linking compound is covalently bound to at least one inorganic nanoparticle through M and covalently bound to at least one inorganic microparticle through M, wherein the at least one inorganic nanoparticle has an average particle size in a range from about 1 nanometer to about 100 nanometers, and wherein the at least one inorganic microparticle has an average particle size in a range of greater than about 0.1 micrometer to about 500 micrometers.
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A method of forming a composite particle comprising:
- providing a mixture comprising at least one inorganic nanoparticle, a solvent, and at least one linking compound of the formula
- M(Z)n(R)m
- wherein each metal atom M is independently selected from the group consisting of Si and Ti;
- each Z is independently selected from the group consisting of —OR′ and —X;
- wherein R′ is C1-C6 selected from linear, branched, and cyclic groups, or combinations thereof or which may be substituted, and each X is a halide;
- each R is C1-C18 selected from linear, branched, and cyclic groups, or combinations thereof, or which may be substituted;
- n is 2 or 3;
- and m is 1 or 2;
- agitating the mixture to provide at least one inorganic nanoparticle precursor in which the at least one linking compound is covalently bound to at least one inorganic nanoparticle through metal atom M;
- adding at least one inorganic microparticle to the mixture;
- and
- reacting the at least one inorganic microparticle and the mixture to covalently bind at least one inorganic nanoparticle precursor to at least one inorganic microparticle through metal atom M.
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Dependencies are inferred from the claim text.