Fungicide heretocyclyl-triazinyl-amino derivatives

A compound of formula (II)

• wherein
• W represents a leaving group such as a halogen atom, a C1-C6 alkylsulfonate, a C1-C6 haloalkylsulfonate;
• a substituted or non-substituted phenylsulfonate;
• Het represents a saturated or unsaturated, aromatic or non-aromatic 4-, 5-, 6- or 7-membered heterocycle comprising up to four heteroatoms which may be the same or different;
• Y independently represents a halogen atom, a nitro group, a hydroxy group, an oxo group, a cyano group, an amino group, a sulphenyl group, a pentafluoro-λ6-sulphenyl group, a formyl group, a formyloxy group, a formylamino group, a carbamoyl group, a N-hydroxycarbamoyl group, a carbamate group, a (hydroxyimino)-C1-C6-alkyl group, a C1-C8-alkyl, a tri(C1-C8-alkyl)silyl, a tri(C1-C8-alkyl)silyl-C1-C8-alkyl, C1-C8-cycloalkyl, tri(C1-C8-alkyl)silyl-C1-C8-cycloalkyl, a C1-C8-halogenoalkyl having 1 to 5 halogen atoms, a C1-C8-halogenocycloalkyl having 1 to 5 halogen atoms, a C1-C8-alkenyl, a C2-C8-alkynyl, a C2-C8-alkenyloxy, a C1-C8-alkynyloxy, a C1-C8-alkylamino, a di-C1-C8-alkylamino, a C1-C8-alkoxy, a C1-C8-halogenoalkoxy having 1 to 5 halogen atoms, a C1-C8-alkylsulphenyl, a C1-C8-halogenoalkylsulphenyl having 1 to 5 halogen atoms, a 2-C8-alkenyloxy, a C2-C8-halogenoalkenyloxy having 1 to 5 halogen atoms, a C3-C8-alkynyloxy, a C3-C8-halogenoalkynyloxy having 1 to 5 halogen atoms, a C1-C8-alkylcarbonyl, a C1-C8-halogenoalkylcarbonyl having 1 to 5 halogen atoms, a C1-C8-alkylcarbamoyl, a di-C1-C8-alkylcarbamoyl, a N—C1-C8-alkyloxycarbamoyl, a C1-C8-alkoxycarbamoyl, a N—C1-C8-alkyl-C1-C8-alkoxycarbamoyl, a C1-C8-alkoxycarbonyl, a C1-C8-halogenoalkoxycarbonyl having 1 to 5 halogen atoms, a C1-C8-alkylcarbonyloxy, a C1-C8-halogenoalkylcarbonyloxy having 1 to 5 halogen atoms, a C1-C8-alkylcarbonylamino, a C1-C8-halogenoalkylcarbonylamino having 1 to 5 halogen atoms, a C1-C8-alkylaminocarbonyloxy, a di-C1-C8-alkylaminocarbonyloxy, a C1-C8-alkyloxycarbonyloxy, a C1-C8-alkylsulphenyl, a C1-C8-halogenoalkylsulphenyl having 1 to 5 halogen atoms, a C1-C8-alkylsulphinyl, a C1-C8-halogenoalkylsulphinyl having 1 to 5 halogen atoms, a C1-C8-alkylsulphonyl, a C1-C8-halogenoalkylsulphonyl having 1 to 5 halogen atoms, a C1-C8-alkylaminosulfamoyl, a di-C1-C8-alkylaminosulfamoyl, a (C1-C6-alkoxyimino)-C1-C6-alkyl, a (C1-C6-alkenyloxyimino)-C1-C6-alkyl, a (C1-C6-alkynyloxyimino)-C1-C6-alkyl, a 2-oxopyrrolidin-1-yl, (benzyloxyimino)-C1-C6-alkyl, C1-C8-alkoxyalkyl, C1-C8-halogenoalkoxyalkyl haying 1 to 5 halogen atoms, benzyloxy, benzylsulphenyl, benzylamino, phenoxy, phenylsulphenyl, or phenylamino;
• it being possible for each of these groups or substituents to be substituted when chemically possible;
• p represents 0, 1, 2, 3, 4, 5 or 6;
• Ra represents a hydrogen atom, a cyano group, a formyl group, a formyloxy group, a C1-C8-alkoxycarbonyl, a C1-C8-halogenoalkoxycarbonyl having 1 to 5 halogen atoms, C1-C8-alkylcarbonyl, a C1-C8-halogenoalkylcarbonyl having 1 to 5 halogen atoms, C1-C8-alkyl-sulphonyl, a C1-C8-halogenoalkylsulphonyl having 1 to 5 halogen atoms, C1-C8-alkyl, C1-C8-cycloalkyl, a C1-C8-halogenoalkyl having 1 to 5 halogen atoms, a C1-C8-halogenocycloalkyl having 1 to 5 halogen atoms, C2-C8-alkenyl, C2-C8-alkynyl, C1-C8-alkoxyalkyl, a C1-C8-halogenoalkoxyalkyl having 1 to 5 halogen atoms;
• it being possible for each of these groups or substituents to be substituted when chemically possible;
• Rb represents a hydrogen atom, a halogen atom, a cyano, a C1-C8-alkyl, a C1-C8-cycloalkyl, a C1-C8-halogenoalkyl having 1 to 5 halogen atoms, a C1-C8-halogenocycloalkyl having 1 to 5 halogen atoms;
• it being possible for each of these groups or substituents to be substituted when chemically possible;
• X independently represents a substituted or non-substituted C1-C10-alkyl, a substituted or non-substituted C1-C10-halogenoalkyl, a halogen atom or a cyano;
• n represents 0, 1, 2 or 3;
• and
• L1 and L2 independently represent a hydrogen atom, a cyano group, a hydroxy group, an amino group, a formyl group, a formyloxy group, a formylamino group, a carbamoyl group, a N-hydroxycarbamoyl group, a carbamate group, substituted or non-substituted (hydroxyimino)-C1-C6-alkyl group, substituted or non-substituted C1-C8-alkyl, a substituted or non-substituted tri(C1-C8-alkyl)silyl, substituted or non-substituted tri(C1-C8-alkyl)silyl-C1-C8-alkyl, substituted or non-substituted C1-C8-cycloalkyl, substituted or non-substituted tri(C1-C8-alkyl)silyl-C1-C8-cycloalkyl, C1-C8-halogenoalkyl having 1 to 5 halogen atoms, C1-C8-halogenocycloalkyl having 1 to 5 halogen atoms, a substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C1-C8-alkynyl, substituted or non-substituted C1-C8-alkylamino, substituted or non-substituted di-C1-C8-alkylamino, substituted or non-substituted C1-C8-alkoxy, C1-C8-halogenoalkoxy having 1 to 5 halogen atoms, substituted or non-substituted C2-C8-alkenyloxy, substituted or non-substituted C2-C8-alkynyloxy, substituted or non-substituted C2-C8-alkenyloxy, C2-C8-halogenoalkenyloxy having 1 to 5 halogen atoms, substituted or non-substituted C3-C8-alkynyloxy, C3-C8-halogenoalkynyloxy having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylcarbonyl, C1-C8-halogenoalkylcarbonyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylcarbamoyl, substituted or non-substituted di-C1-C8-alkylcarbamoyl, substituted or non-substituted N—C1-C8-alkyloxycarbamoyl, substituted or non-substituted C1-C8-alkoxycarbamoyl, substituted or non-substituted N—C1-C8-alkyl-C1-C8-alkoxycarbamoyl, substituted or non-substituted C1-C8-alkoxycarbonyl, C1-C8-halogenoalkoxycarbonyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylcarbonyloxy, C1-C8-halogenoalkylcarbonyloxy having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylcarbonylamino, C1-C8-halogenoalkylcarbonylamino having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylaminocarbonyloxy, substituted or non-substituted di-C1-C8-alkylaminocarbonyloxy, substituted or non-substituted C1-C8-alkyloxycarbonyloxy, substituted or non-substituted C1-C8-alkylsulphenyl, C1-C8-halogenoalkylsulphenyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylsulphinyl, C1-C8-halogenoalkylsulphinyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylsulphonyl, C1-C8-halogenoalkylsulphonyl having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylaminosulfamoyl, substituted or non-substituted di-C1-C8-alkylaminosulfamoyl, substituted or non-substituted (C1-C6-alkoxyimino)-C1-C6-alkyl, substituted or non-substituted (C1-C6-alkenyloxyimino)-C1-C6-alkyl, substituted or non-substituted (C1-C6-alkynyloxyimino)-C1-C6-alkyl, substituted or non-substituted (2-oxopyrrolidin-1-yl) (2-oxopyrrolidin-1-yl) C1-C8-halogenoalkyl having 1 to 5 halogen atoms, substituted or non-substituted (2-oxopiperidin-1-yl) C1-C8-alkyl, (2-oxopiperidin-1-yl) C1-C8-halogenoalkyl having 1 to 5 halogen atoms, substituted or non-substituted (2-oxoazepan-1-yl) (2-oxoazepan-1-yl) C1-C8-halogenoalkyl having 1 to 5 halogen atoms, substituted or non-substituted (benzyloxyimino)-C1-C6-alkyl;
• or
• L1 and L2 can form together a saturated or unsaturated, aromatic or non-aromatic, substituted or non-substituted 4-, 5-, 6- or 7-membered, N-including heterocycle
• comprising up to 4 heteroatoms independently selected in the list consisting of N, O, S;
• unless indicated otherwise, a group or a substituent that is substituted is substituted by one or more of the following groups or atoms:
• a halogen atom, a nitro group, a hydroxy group, a cyano group, an amino group, a sulphenyl group, a pentafluoro-λ6-sulphenyl group, a formyl group, a formyloxy group, a formylamino group, a carbamoyl group, a N-hydroxycarbamoyl group, a carbamate group, a (hydroxyimino)-C1-C6-alkyl group, a C1-C8-alkyl, a tri(C1-C8-alkyl)silyl-C1-C8-alkyl, tri(C1-C8-alkyl)silyl-C1-C8-cycloalkyl, a C1-C8-halogenoalkyl having 1 to 5 halogen atoms, a C1-C8-halogenocycloalkyl having 1 to 5 halogen atoms, a C1-C8-alkenyl, a C1-C8-alkynyl, a C2-C8-alkenyloxy, a C1-C8-alkynyloxy, a C1-C8-alkylamino, a di-C1-C8:
• alkylamino, a C1-C8-alkoxy, a C1-C8-halogenoalkoxy having 1 to 5 halogen atoms, a C1-C8-alkylsulphenyl, a C1-C8-halogenoalkylsulphenyl having 1 to 5 halogen atoms, a C2-C8-alkenyloxy, a C2-C8-halogenoalkenyloxy having 1 to 5 halogen atoms, a C3-C8-alkynyloxy, a C3-C8-halogenoalkynyloxy having 1 to 5 halogen atoms, a C1-C8-alkylcarbonyl, a C1-C8-halogenoalkylcarbonyl having 1 to 5 halogen atoms, a C1-C8-alkylcarbamoyl, a di-C1-C8-alkylcarbamoyl, a N—C1-C8-alkyloxycarbamoyl, a C1-C8-alkoxycarbamoyl, a N—C1-C8-alkyl-C1-C8-alkoxycarbamoyl, a C1-C8-alkoxycarbonyl, a C1-C8-halogenoalkoxycarbonyl having 1 to 5 halogen atoms, a C1-C8-alkylcarbonyloxy, a C1-C8-halogenoalkylcarbonyloxy having 1 to 5 halogen atoms, a C1-C8-alkylcarbonylamino, a C1-C8-halogenoalkylcarbonylamino having 1 to 5 halogen atoms, a C1-C8-alkylaminocarbonyloxy, a di-C1-C8-alkylaminocarbonyloxy, a C1-C8-alkyloxycarbonyloxy, a C1-C8-alkylsulphenyl, a C1-C8-halogenoalkylsulphenyl having 1 to 5 halogen atoms, a C1-C8-alkylsulphinyl, a C1-C8-halogenoalkylsulphinyl having 1 to 5 halogen atoms, a C1-C8-alkylsulphonyl, a C1-C8-halogenoalkylsulphonyl having 1 to 5 halogen atoms, a C1-C8-alkylaminosulfamoyl, a di-C1-C8-alkylaminosulfamoyl, a (C1-C6-alkoxyimino)-C1-C6-alkyl, a (C1-C6-alkenyloxyimino)-C1-C6-alkyl, a (C1-C6-alkynyloxyimino)-C1-C6-alkyl, a 2-oxopyrrolidin-1-yl, (benzyloxyimino)-C1-C6-alkyl, C1-C8-alkoxyalkyl, C1-C8-halogenoalkoxyalkyl having 1 to 5 halogen atoms, benzyloxy, benzylsulphenyl, benzylamino, phenoxy, phenylsulphenyl, or phenylamino.