Hydrate and anhydrous crystal form of the sodium salt of 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzenesulfonamide, process for preparation thereof and use thereof as herbicides and plant growth regulators
AssigneeBayer CropScience AG
InventorsBritta OLENIK, Christian WALDRAFF, Arno RATSCHINSKI, Martin-Holger HINZ, Hans-Joachim RESSEL
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Abstract
A hydrate and an anhydrous crystal form of the sodium salt of 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzenesulfonamide are described. These thermodynamically stable crystal forms have particular advantages in the stability of suspension formulations.
Claims12
A sodium salt of 2-iodo-N-[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)carbamoyl]benzenesulfonamide, wherein the salt is present as crystal form I or hydrate (crystal form II), the respective x-ray powder diffractograms of which at 25° C. have at least three of the following 20 (2 theta) values:
- 2 θ
- D [Å ± 0.2]
- crystal form I
- 6.0
- 14.7
- 8.9
- 9.9
- 9.9
- 9.0
- 11.1
- 8.0
- 12.8
- 6.9
- 16.7
- 5.3
- 24.0
- 3.7
- 24.3
- 3.7
- 26.6
- 3.4
- 26.9
- 3.3
- hydrate (crystal form II)
- 6.8
- 13.0
- 7.2
- 12.3
- 9.8
- 9.0
- 11.8
- 7.5
- 13.6
- 6.5
- 14.4
- 6.2
- 16.6
- 5.3
- 22.1
- 4.0
- 25.1
- 3.5
- 26.4
- 3.4
Dependencies are inferred from the claim text.