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US 2011/0218137 A1Published application
Antifoaming compositions
AssigneeWacker Chemie AG
InventorsHolger Rautschek, Elisabeth Brehm, Christian Herzig
Life of this patent
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Abstract
Mixtures of silicone resin with an organopolysiloxane copolymer prepared by hydrosilylating a substantially linear polymer containing an isocyanate reactive group with an Si—H containing organopolysiloxane, and reacting this intermediate with a diisocyanate, are useful as long lasting defoamers which are compatible with numerous media.
Claims13
-10. (canceled)
A composition comprising
- (A) polysiloxane copolymers prepared by
- in a 1st step
- reacting organopolysiloxanes (1) which have per molecule at least one Si-bonded hydrogen atom, with substantially linear oligomeric or polymeric compounds (2) of the formula
- R1-(A-CnH2n)m-A1-H (I),
- where R1 is a monovalent, optionally substituted hydrocarbon radical, which is hydrosilylatable by Si-H groups in a hydrosilylation reaction,
- A is a divalent, polar organic radical selected from the group consisting of —O—, —C(O)-O—, —O—C(O)—, —O—C(O)-O—, —C(O)-NH-, -NH-C(O)-, urethane radicals and urea radicals, and mixtures thereof,
- A1 is a divalent, polar organic radical selected from the group consisting of —O—, -NH, -NR′-, and mixtures thereof where R′ is a monovalent hydrocarbon radical having 1 to 18 carbon atoms,
- n is an integer from 1 to 20, and
- m is an integer,
- with the proviso that the m units (A-CnH2n) are identical or different, to form intermediates (4) containing H-A′ groups, and
- in a 2nd step
- reacting the resultant intermediates (4) containing H-A′ groups, with organic compounds (5) which have per molecule at least two isocyanate groups, and also, optionally, with further compounds (7) which are reactive with isocyanate groups,
- (B) organopolysiloxane resins comprising units of the formula
- R8g(R9O)hSiO(4-g-h)/2 (VI),
- in which
- R8 are identical or different, and are hydrogen or a monovalent, optionally substituted, SiC-bonded hydrocarbon radical,
- R9 are identical or different and are hydrogen or a monovalent, optionally substituted hydrocarbon radical,
- g is 0, 1, 2 or 3, and
- h is 0, 1,2 or 3,
- with the proviso that the sum g+h≦3 and in less than 50% of all of the units of the formula (VI) in the organopolysiloxane resin the sum g+h is 2,
- with the proviso that the composition does not contain polyorganosiloxanes in which more than 90% of the units are difunctional units of the formula SiR″2O2/2 where R′ is a hydrocarbon radical.
18 more elements
Dependencies are inferred from the claim text.